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Volume 38
Main Index

Issue 1


Spectroscopy and Electrochemistry of mer-[RuCl3(dmso)(tmen)]. Dimethylsulfoxide Is Sulfur-Bonded to Ru(II), Ru(III), and Ru(IV)
Jeffrey J. Rack and Harry B. Gray
pp 2 - 3; DOI:
10.1021/ic981029v
PDF
Experimental and Theoretical Investigations of Condensation and Disproportionation of Mn(bpy)Cl3(H2O) in Aqueous Solution
Christian Philouze, Marc Henry, Nathalie Auger, Daniel Vignier, Monique Lance, Martine Nierlich, and Jean-Jacques Girerd
pp 4 - 11; DOI:
10.1021/ic971518f
PDF
Internal Reorganization Energies for Copper Redox Couples: The Slow Electron-Transfer Reactions of the [CuII/I(bib)2]2+/+ Couple
Boping Xie, Thomas Elder, Lon J. Wilson, and David M. Stanbury
pp 12 - 19; DOI:
10.1021/ic980926w
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Theoretical Study of the Intercalation of Li into TiO2 Structures
ubomír Benco, Jean-Luc Barras, Claude Auguste Daul, and Erich Deiss
pp 20 - 28; DOI:
10.1021/ic9803558
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Bonding Properties of Amidinate Complexes of the Group 14 Elements Silicon, Germanium, Tin, and Lead in Their Divalent and Tetravalent Oxidation States
Wolfgang W. Schoeller, Andreas Sundermann, and Markus Reiher
pp 29 - 37; DOI:
10.1021/ic9808201
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Conformational Influence of Dithiocarbazinic Acid Bishydrazone Ligands on the Structure of Zinc(II) Complexes: A Comparative XANES Study
Christoph Hennig, Karl-Heinz Hallmeier, Gernot Zahn, Frank Tschwatschal, and Horst Hennig
pp 38 - 43; DOI:
10.1021/ic9804059
PDF
Protonated Borane-Lewis Base Complexes BH4X+ (X = NH3, PH3, H2O, H2S, CO)
Golam Rasul, G. K. Surya Prakash, and George A. Olah
pp 44 - 47; DOI:
10.1021/ic9811502
PDF
Axial Ligation Equilibria and Dynamics in a Redox Polyether Hybrid: An Fe Tetraphenylporphyrin Melt
Jeffrey W. Long and Royce W. Murray
pp 48 - 54; DOI:
10.1021/ic980163c
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Increasing the Nuclearity of Magnetic Polyoxometalates. Syntheses, Structures, and Magnetic Properties of Salts of the Heteropoly Complexes [Ni3(H2O)3(PW10O39)H2O]7-, [Ni4(H2O)2(PW9O34)2]10-, and [Ni9(OH)3(H2O)6(HPO4)2(PW9O34)3]16-
Juan M. Clemente-Juan, Eugenio Coronado, José R. Galán-Mascarós, and Carlos J. Gómez-García
pp 55 - 63; DOI:
10.1021/ic9807902
PDF
Syntheses and Structures of Mixed-Metal Sulfido Clusters Containing Incomplete Cubane-Type M2M'S4 and Cubane-Type M2M'2S4 Cores (M = Mo, W; M' = Rh, Ir)
Tomotake Ikada, Shigeki Kuwata, Yasushi Mizobe, and Masanobu Hidai
pp 64 - 69; DOI:
10.1021/ic981035r
PDF
Six-Membered Cyanuric-Thiazyl and Cyanuric-Sulfanuric Ring Systems: Thermal Isomerization of (CF3CH2O)3C2N3S(O) to (CF3CH2O)2(CF3CH2)C2N3S(O)2
Tristram Chivers, Derek Gates, Xiaorong Li, Ian Manners, and Masood Parvez
pp 70 - 76; DOI:
10.1021/ic9808652
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Electronic Structure of the Electron-Poor Dinuclear Organometallic Compounds [(CpM)(CpM')]-Cot (M, M' = V, Cr, Fe, Co)
Uwe Richter, Jürgen Heck, and Joachim Reinhold
pp 77 - 83; DOI:
10.1021/ic9805776
PDF
Characterization of Na5P3O10 Polymorphs by 23Na MAS, 23Na MQMAS, and 31P MAS NMR Spectroscopy
Colin A. Fyfe, Holger Meyer zu Altenschildesche, and Jrgen Skibsted
pp 84 - 92; DOI:
10.1021/ic980524o
PDF
A Delocalized Analogue of the Bicobaltocene Cation Derived from Reduction of a d6d6 (Fulvalenediyl)bis(cobaltacarborane) Complex: Electrochemistry, ESR, Optical Spectroscopy, and IR Spectroscopy of the Carborane Group
Teen T. Chin, Russell N. Grimes, and William E. Geiger
pp 93 - 99; DOI:
10.1021/ic980382y
PDF
Syntheses, Characterization, and Structural Studies of Several (Nitro)(nitrosyl)iron(III) Porphyrinates: [Fe(Porph)(NO2)(NO)]
Mary K. Ellison, Charles E. Schulz, and W. Robert Scheidt
pp 100 - 108; DOI:
10.1021/ic981162n
PDF
Structural Studies of the Hydrazine and Ammine Complexes of the Dinuclear Ruthenium Polysulfide Complexes
Takashi Furuhashi, Masaki Kawano, Yoshihiro Koide, Ryosuke Somazawa, and Kazuko Matsumoto
pp 109 - 114; DOI:
10.1021/ic9804115
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Rhenium Complexes with Weakly Coordinating Solvent Ligands, cis-[Re(PR3)(CO)4(L)][BArF], L = CH2Cl2, Et2O, NC5F5: Decomposition to Chloride-Bridged Dimers in CH2Cl2 Solution
Jean Huhmann-Vincent, Brian L. Scott, and Gregory J. Kubas
pp 115 - 124; DOI:
10.1021/ic980912q
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Volatile Zirconium Bis(acetylacetonato)bis(alcoholato) Complexes Containing Heterosubstituted Alcoholato Ligands
M. Morstein
pp 125 - 131; DOI:
10.1021/ic980652c
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Product of a DMF Aminalization, Bis[bis(3,5-dimethylpyrazol-1-yl)(dimethylamino)methane]copper(II) Perchlorate-Bis(dichloromethane)
Robert T. Stibrany, Spencer Knapp, Joseph A. Potenza, and Harvey J. Schugar
pp 132 - 135; DOI:
10.1021/ic980903h
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Synthesis and Electrochemistry of Ruthenium Complexes with an Oxygen Tripod Ligand
Wa-Hung Leung, Eddie Y. Y. Chan, and Wing-Tak Wong
pp 136 - 143; DOI:
10.1021/ic980196s
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New Insight into the Nature of Cu(TCNQ): Solution Routes to Two Distinct Polymorphs and Their Relationship to Crystalline Films That Display Bistable Switching Behavior
Robert A. Heintz, Hanhua Zhao, Xiang Ouyang, Giulio Grandinetti, Jerry Cowen, and Kim R. Dunbar
pp 144 - 156; DOI:
10.1021/ic9812095
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Theoretical Studies of NMR Chemical Shifts and Vibrational Frequencies in 3-Phosphaalkynes PC-R
Klaus Hübler and Peter Schwerdtfeger
pp 157 - 164; DOI:
10.1021/ic9811291
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Actinide Gas-Phase Chemistry: Reactions of An+ and AnO+ [An = Th, U, Np, Pu, Am] with Nitriles and Butylamine
John K. Gibson
pp 165 - 173; DOI:
10.1021/ic980908e
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Dipyridophenazine Complexes of Os(II) as Red-Emitting DNA Probes: Synthesis, Characterization, and Photophysical Properties
R. Erik Holmlin, Johanna A. Yao, and Jacqueline K. Barton
pp 174 - 189; DOI:
10.1021/ic9808955
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Carboxylate/Diphenylphosphate Exchanges in Asymmetric Diiron Complexes Modeling the Purple Acid Phosphatases Enzymes: Associated Redox Processes
Elisabeth Bernard, Sylvie Chardon-Noblat, Alain Deronzier, and Jean-Marc Latour
pp 190 - 193; DOI:
10.1021/ic980122g
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An Extended Solid from the Solvothermal Decomposition of Co(Acac)3: Structure and Characterization of Co5(OH)2(O2CCH3)8·2H2O
Roger Kuhlman, George L. Schimek, and Joseph W. Kolis
pp 194 - 196; DOI:
10.1021/ic9802855
PDF
Molecular Structure of 1-Isothiocyanatosilatrane: Ab Initio and DFT Calculations
Gyusung Chung, Ohyun Kwon, and Younghi Kwon
pp 197 - 200; DOI:
10.1021/ic980667a
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Two-Coordinate Tribenzylphosphine (PBz3) Complexes of Copper(I): Solid State 31P NMR Studies and the Crystal Structure of [Cu(PBz3)2]PF6
Eric W. Ainscough, Andrew M. Brodie, Anthony K. Burrell, John V. Hanna, Peter C. Healy, and Joyce M. Waters
pp 201 - 203; DOI:
10.1021/ic980842n
PDF
Rapid Cage Degradation of 1-Formyl- and 1-Alkyloxycarbonyl-Substituted 1,2-Dicarba-closo-dodecaboranes by Water or Methanol in Polar Organic Solvents
John J. Schaeck and Stephen B. Kahl
pp 204 - 206; DOI:
10.1021/ic980995a
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Issue 2


One-Dimensional Coordination Polymers Based upon Bridging Terephthalate Ions
Ryan H. Groeneman, Leonard R. MacGillivray, and Jerry L. Atwood
pp 208 - 209; DOI:
10.1021/ic9807137
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Silsesquioxane Chemistry: Synthesis and Structure of the Novel Anionic Aluminosilsesquioxane [HNEt3][{Cy7Si7O9(OSiMe3)O2}2Al]·C6H14 (Cy = c-C6H11)
Frank T. Edelmann, Yurii K. Gun'ko, Stephan Giessmann, Falk Olbrich, and Klaus Jacob
pp 210 - 211; DOI:
10.1021/ic9808100
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Vanadium Oxide Clusters as Building Blocks for the Synthesis of Metal Oxide Surfaces and Framework Materials: Synthesis and X-ray Crystal Structure of [H6Mn3VIV15VV4O46(H2O)12]·30H2O
M. Ishaque Khan, Elizabeth Yohannes, and Douglas Powell
pp 212 - 213; DOI:
10.1021/ic981077f
PDF
Study of NaF-AlF3 Melts by High-Temperature 27Al NMR Spectroscopy: Comparison with Results from Raman Spectroscopy
E. Robert, V. Lacassagne, C. Bessada, D. Massiot, B. Gilbert, and J.-P. Coutures
pp 214 - 217; DOI:
10.1021/ic980677b
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Anion-Controlled Nuclearity and Metal-Metal Distances in Copper(I)-dppm Complexes (dppm = Bis(diphenylphosphino)methane)
Jitendra K. Bera, Munirathnam Nethaji, and Ashoka G. Samuelson
pp 218 - 228; DOI:
10.1021/ic980515f
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A Chromium-Vanadyl Ferrimagnetic Molecule-Based Magnet: Structure, Magnetism, and Orbital Interpretation
S. Ferlay, T. Mallah, R. Ouahès, P. Veillet, and M. Verdaguer
pp 229 - 234; DOI:
10.1021/ic980109w
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Synthesis and Structures of New Layered Ternary Manganese Tellurides: AMnTe2 (A = K, Rb, Cs), Na3Mn4Te6, and NaMn1.56Te2
Joonyeong Kim, Chwanchin Wang, and Timothy Hughbanks
pp 235 - 242; DOI:
10.1021/ic980805w
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Heterobimetallic Dinitrogen Complexes That Contain the {[N3N]Mo-N=N}- Ligand
Myra B. O'Donoghue, William M. Davis, Richard R. Schrock, and William M. Reiff
pp 243 - 252; DOI:
10.1021/ic9811188
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Dinuclear Phosphido-Bridged Derivatives of Platinum(I). Synthesis and Characterization of [Pt2(-PBut2)2(PBut2H)(L)] [L = PBut2R (R = H, Li, n-Heptyl), CO, 2-CS2]
Piero Leoni, Giuseppina Chiaradonna, Marco Pasquali, and Fabio Marchetti
pp 253 - 259; DOI:
10.1021/ic9811392
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Sulfur Allocation and Vanadium-Sulfate Interactions in Whole Blood Cells from the Tunicate Ascidia ceratodes, Investigated Using X-ray Absorption Spectroscopy
Patrick Frank, Britt Hedman, and Keith O. Hodgson
pp 260 - 270; DOI:
10.1021/ic980792m
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New Layered Uranium(VI) Molybdates: Syntheses and Structures of (NH3(CH2)3NH3)(H3O)2(UO2)3(MoO4)5, C(NH2)3(UO2)(OH)(MoO4), (C4H12N2)(UO2)(MoO4)2, and (C5H14N2)(UO2)(MoO4)2·H2O
P. Shiv Halasyamani, Robin J. Francis, Susan M. Walker, and Dermot O'Hare
pp 271 - 279; DOI:
10.1021/ic980836r
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A New Route to the Phosphazene Polymerization Precursors, Cl3P=NSiMe3 and (NPCl2)3
Harry R. Allcock, Chester A. Crane, Christopher T. Morrissey, and Michael A. Olshavsky
pp 280 - 283; DOI:
10.1021/ic980534p
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Synthesis and EPR Characterization of "Phosphaverdazyl" Radicals
Robin G. Hicks and Richard Hooper
pp 284 - 286; DOI:
10.1021/ic980985+
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On the Second-Order Nonlinear Optical Structure-Property Relationships of Metal Chromophores
Karel Base, Mark T. Tierney, Alain Fort, Jacques Muller, and Mark W. Grinstaff
pp 287 - 289; DOI:
10.1021/ic980872q
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{Li[P(NtBu)2]}4·0.25P4(NtBu)6: Solvent and Substituent Effects on the Structures and Reactivity of 1,3-Diaza-2-phosphaallyllithium Complexes
Justin K. Brask, Tristram Chivers, Mark L. Krahn, and Masood Parvez
pp 290 - 295; DOI:
10.1021/ic980117c
PDF
Synthesis and Structural Characterization of Some Monomeric Group 13 Amides
Joel S. Silverman, Claire J. Carmalt, Alan H. Cowley, Robert D. Culp, Richard A. Jones, and Brian G. McBurnett
pp 296 - 300; DOI:
10.1021/ic980619q
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Cation Catalysis of Anion-Anion Electron Transfer in Aqueous Solution: Self-Exchange Reaction Kinetics of Some Hexa- and Octacyanometalate Couples at Variable Pressure
Peter D. Metelski and Thomas W. Swaddle
pp 301 - 307; DOI:
10.1021/ic980887o
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Uranyl Sequestering Agents: Correlation of Properties and Efficacy with Structure for UO22+ Complexes of Linear Tetradentate 1-Methyl-3-hydroxy-2(1H)-pyridinone Ligands
Jide Xu and Kenneth N. Raymond
pp 308 - 315; DOI:
10.1021/ic980993q
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Na9K16Tl18Cd3: A Novel Phase Containing Tl8Cd310- and Tl57- Clusters
DaPing Huang and John D. Corbett
pp 316 - 320; DOI:
10.1021/ic9807792
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Ab Initio Study of BnHn and Bn(NH2)n (n = 3-6) Species. A Comparison of Classical and Nonclassical Structures
Michael L. McKee
pp 321 - 330; DOI:
10.1021/ic981034z
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A Spectroscopic Study of the Homogeneous Catalytic Conversion of Ethylene to Vinyl Acetate by Palladium Acetate
David D. Kragten, Rutger A. van Santen, Michael K. Crawford, William D. Provine, and Jan J. Lerou
pp 331 - 339; DOI:
10.1021/ic980399g
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Electron Counting Scheme Relevant for Late Transition Metal Compounds with Weakly Electronegative Ligands. Electronic Band Structure Study of Phosphosilicides PtSi3P2 and NiSi2P3
K.-S. Lee, H.-J. Koo, D. Dai, J. Ren, and M.-H. Whangbo
pp 340 - 345; DOI:
10.1021/ic980761r
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Interaction of Dimethyltin(IV)2+ Cation with Gly-Gly, Gly-His, and Some Related Ligands. A New Case of a Metal Ion Able To Promote Peptide Nitrogen Deprotonation in Aqueous Solution
Péter Surdy, Patrice Rubini, Norbert Buzás, Bernard Henry, Lorenzo Pellerito, and Tamás Gajda
pp 346 - 352; DOI:
10.1021/ic980398o
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The First Thiolate-Bridged Dinuclear Indacarboranes with -Coordination
Jae-Hak Kim, Jeong-Wook Hwang, Young-Whan Park, and Youngkyu Do
pp 353 - 357; DOI:
10.1021/ic980904+
PDF
Intramolecular and Environmental Contributions to Electrode Half-Reaction Entropies of M(tacn)23+/2+ (M = Fe, Co, Ni, Ru; tacn = 1,4,7-Triazacyclononane) Redox Couples
Jeffrey W. Turner and Franklin A. Schultz
pp 358 - 364; DOI:
10.1021/ic980977t
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Electrochemical and Magnetic Exchange Interactions in Trinuclear Chain Complexes Containing Oxo-Mo(V) Fragments as a Function of the Topology of the Bridging Ligand
Van Ân Ung, Samantha M. Couchman, John C. Jeffery, Jon A. McCleverty, Michael D. Ward, Federico Totti, and Dante Gatteschi
pp 365 - 369; DOI:
10.1021/ic980934c
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Mechanisms of the Nucleophilic Substitution of the Allyl Carbons of (-Allyl)platinum and (-Allyl)palladium Complexes
Tomohiro Suzuki and Hiroshi Fujimoto
pp 370 - 382; DOI:
10.1021/ic9805877
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Use of 13C-1H NMR Coupling Constants To Assess the Binding of Imidazole Ring Ligands to Metals
Scott J. Moore, Rene J. Lachicotte, Sharon T. Sullivan, and Luigi G. Marzilli
pp 383 - 390; DOI:
10.1021/ic980519k
PDF
Syntheses and Superoxide Dismuting Activities of Partially (1-4) -Chlorinated Derivatives of Manganese(III) meso-Tetrakis(N-ethylpyridinium-2-yl)porphyrin
Remy Kachadourian, Ines Batini-Haberle, and Irwin Fridovich
pp 391 - 396; DOI:
10.1021/ic9808854
PDF
Activation of Carbon Dioxide: Gas-Phase Reactions of Y+, YO+, and YO2+ with CO and CO2
M. R. Sievers and P. B. Armentrout
pp 397 - 402; DOI:
10.1021/ic981117f
PDF
Solvent Cage Effects on the Ligand Field Photochemistry of the Cyanoferrate(II) Complexes
Jailson Farias de Lima, Adelino Kaoru Nakano, and Neyde Yukie Murakami Iha
pp 403 - 405; DOI:
10.1021/ic980363o
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Comment on "Direct Observation of a Metastable Solid Phase of Mg/Al/CO3-Layered Double Hydroxide by Means of High-Temperature in Situ Powder XRD and DTA/TG"
Vicente Rives
pp 406 - 407; DOI:
10.1021/ic980739y
PDF
Molecular Structure, Conformational Analysis, and Electronic Spectra of 1-Phenyl-1-aza-closo-dodecaborane(12)
Wolfgang Fendrich, James E. Harvey, and Piotr Kaszynski
pp 408 - 410; DOI:
10.1021/ic980737d
PDF
4,4'-Dipyridylamine-Bridged Binuclear Complexes of Pentacyanoferrate and Pentaammineruthenium
Ching-Lung Lin, Kenneth Hung, Andrew Yeh, Hsiu-Tun Tsen, and Chan-Cheng Su
pp 411 - 414; DOI:
10.1021/ic980087d
PDF
Diborane(4)yl Complexes of Molybdenum and Ruthenium
Holger Braunschweig, Margot Koster, and Ruimin Wang
pp 415 - 416; DOI:
10.1021/ic980947q
PDF

Issue 3


Automated Solid-Phase Synthesis of Site-Specifically Labeled Ruthenium-Oligonucleotides
Shoeb I. Khan, Amy E. Beilstein, and Mark W. Grinstaff
pp 418 - 419; DOI:
10.1021/ic9806636
PDF
Nucleobase Stacking Evidenced on Ternary Metal (Palladium(II), Copper(II)) Complexes with Nucleobase Amino Acids and Aromatic Diimines
Mamoru Mizutani, Ichiro Kubo, Koichiro Jitsukawa, Hideki Masuda, and Hisahiko Einaga
pp 420 - 421; DOI:
10.1021/ic980438o
PDF
Modeling the Catalytic Cycle of Liver Alcohol Dehydrogenase: Synthesis and Structural Characterization of a Four-Coordinate Zinc Ethoxide Complex and Determination of Relative Zn-OR versus Zn-OH Bond Energies
Catherine Bergquist and Gerard Parkin
pp 422 - 423; DOI:
10.1021/ic981267q
PDF
The First Structurally Characterized Discrete Dinuclear -Cyano Hexacyanoferrate Complex
Paul V. Bernhardt and Manuel Martinez
pp 424 - 425; DOI:
10.1021/ic981019u
PDF
[(Ethylenediamine)Pt(uracilate)]4, a Metal Analogue of Calix[4]arene. Coordination and Anion Host-Guest Chemistry Related to Its Conformational Dynamics
Jorge A. R. Navarro, Matthias B. L. Janik, Eva Freisinger, and Bernhard Lippert
pp 426 - 432; DOI:
10.1021/ic9808394
PDF
X-ray Absorption Spectra of the Oxidized and Reduced Forms of C112D Azurin from Pseudomonas aeruginosa
Serena DeBeer, Cynthia N. Kiser, Gary A. Mines, John H. Richards, Harry B. Gray, Edward I. Solomon, Britt Hedman, and Keith O. Hodgson
pp 433 - 438; DOI:
10.1021/ic9804622
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Acid-Base and Metal Ion-Coordinating Properties of Pyrimidine-Nucleoside 5'-Diphosphates (CDP, UDP, dTDP) and of Several Simple Diphosphate Monoesters. Establishment of Relations between Complex Stability and Diphosphate Basicity
S. Ali A. Sajadi, Bin Song, Fridrich Gregá, and Helmut Sigel
pp 439 - 448; DOI:
10.1021/ic9809862
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Electrochemical Behavior of the Fe(III) Complexes of the Cyclic Hydroxamate Siderophores Alcaligin and Desferrioxamine E
Ivan Spasojevi, Sandra K. Armstrong, Timothy J. Brickman, and Alvin L. Crumbliss
pp 449 - 454; DOI:
10.1021/ic980635n
PDF
Synthesis and Structure of NaZnSiO3OH, a New Chiral Zincosilicate Framework Material
A. M. Healey, M. T. Weller, and A. R. Genge
pp 455 - 458; DOI:
10.1021/ic9810135
PDF
Transition-Metal Complexes with Sulfur Ligands. 132.1 Electron-Rich Fe and Ru Complexes with [MN2S3] Cores Containing the New Pentadentate Ligand 'N2H2S3'2- (= 2,2'-Bis(2-mercaptophenylamino)diethyl Sulfide(2-))
Dieter Sellmann, Jürgen Utz, and Frank W. Heinemann
pp 459 - 466; DOI:
10.1021/ic980383q
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Ruthenium Complexes of Quinone Related Ligands: A Study of the Electrochemical Properties of 2-Aminothiophenolatobis(2,2'-Bipyridine)Ruthenium(II)
Mehrdad Ebadi and A. B. P. Lever
pp 467 - 474; DOI:
10.1021/ic980838b
PDF
Dinuclear Calcium Complexes with Intramolecularly NH···O Hydrogen-Bonded Dicarboxylate Ligands
Norikazu Ueyama, Jiro Takeda, Yusuke Yamada, Akira Onoda, Taka-aki Okamura, and Akira Nakamura
pp 475 - 478; DOI:
10.1021/ic981055t
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An Adjacent Dibenzotetraazaporphyrin: A Structural Intermediate between Tetraazaporphyrin and Phthalocyanine
Nagao Kobayashi, Hideya Miwa, Hiroaki Isago, and Tatsuya Tomura
pp 479 - 485; DOI:
10.1021/ic9806535
PDF
Synthesis, Structure, and Reactivity of 1,2-(1',1',2',2'-Tetramethyldisilane-1',2')carborane
Francis M. de Rege, Jeremy D. Kassebaum, Brian L. Scott, Kent D. Abney, and Gary J. Balaich
pp 486 - 489; DOI:
10.1021/ic980992y
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Mixed Chloride/Amine Complexes of Dimolybdenum(II,II). 2. Reactions of Mo2Cl4(NHEt2)4 with Monodentate and Bidentate Phosphines. New Type of Compounds Mo2Cl4(diphosphine)4
F. Albert Cotton, Evgeny V. Dikarev, and Santiago Herrero
pp 490 - 495; DOI:
10.1021/ic980972w
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Heavy Alkali Metal Arenedithiocarboxylates: A Facile Synthesis, Dimeric Structure, and Nonbonding Interaction between the Metals and Aromatic Ring Carbons
Shinzi Kato, Nobuyuki Kitaoka, Osamu Niyomura, Yuka Kitoh, Takahiro Kanda, and Masahiro Ebihara
pp 496 - 506; DOI:
10.1021/ic9808089
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Facile Synthesis and Structure of Heavy Alkali Metal Thiocarboxylates: Structural Comparison with the Selenium and Tellurium Isologues
Osamu Niyomura, Shinzi Kato, and Takahiro Kanda
pp 507 - 518; DOI:
10.1021/ic9808091
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First Isolation and Characterization of Sodium and Potassium Tellurocarboxylates: Structural Analysis of Te-Alkyl Telluroester
Shinzi Kato, Osamu Niyomura, Shohou Nakaiida, Yasuyuki Kawahara, Takahiro Kanda, Ryo Yamada, and Shinya Hori
pp 519 - 530; DOI:
10.1021/ic980815x
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Linkage Isomerism Dependent on Solvent and Temperature. Synthesis and Structural Properties of Diamineplatinum(II) Complexes of Allyl- and Diallylmalonate Ligands
Young-A Lee, Young Keun Chung, and Youn Soo Sohn
pp 531 - 537; DOI:
10.1021/ic980873i
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Synthesis and Structural Characterization of Neutral Silver(I) Complexes with Arenephosphinothiols. Crystal Structures of [Ag4{2-(Ph2P)-6-(Me3Si)C6H6S}4] and [Ag4{2-(Ph2PO)-6-(Me3Si)C6H3S}4]
Paulo Perez-Lourido, Jose A. Garcia-Vazquez, Jaime Romero, Antonio Sousa, Eric Block, Kevin P. Maresca, and Jon Zubieta
pp 538 - 544; DOI:
10.1021/ic9808403
PDF
Layered and Hexagonal Aluminosilicate-Hexadecylamine Mesostructures: Solid State Transformation and Ionic Conductivity
Sang Kyeong Yun and Joachim Maier
pp 545 - 549; DOI:
10.1021/ic980276w
PDF
Redox-Induced Formation and Cleavage of O-O and Bonds in a Peroxo-Bridged Manganese Dimer: A Density Functional Study
John E. McGrady and Robert Stranger
pp 550 - 558; DOI:
10.1021/ic981253k
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Catechol-Pendant Terpyridine Complexes: Electrodeposition Studies and Electrocatalysis of NADH Oxidation
Gregory D. Storrier, Kazutake Takada, and Héctor D. Abruña
pp 559 - 565; DOI:
10.1021/ic980578y
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C-(Halide) Oxidative Addition Routes to Ruthenium Carbenes
Montserrat Oliván and Kenneth G. Caulton
pp 566 - 570; DOI:
10.1021/ic980070v
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Substitution Reactions of Platinum(II)-Nucleobase Complexes by Associative Mechanism Involving Pseudorotation of the Five-Coordinate Intermediate
Marjaana Mikola, Karel D. Klika, Anu Hakala, and Jorma Arpalahti
pp 571 - 578; DOI:
10.1021/ic9810945
PDF
Linking Intermetallics and Zintl Compounds: An Investigation of Ternary Trielides (Al, Ga, In) Forming the NaZn13 Structure Type
Karen J. Nordell and Gordon J. Miller
pp 579 - 590; DOI:
10.1021/ic980772k
PDF
Paramagnetic Zinc(II) Complexes of a Bis(catechol): Dependence of Product Spin State on Tautomerization of the Bis(catechol) Ligand
David A. Shultz and Scot H. Bodnar
pp 591 - 594; DOI:
10.1021/ic981092k
PDF
Synthesis and Structural Characterization of (n-Bu4N)3AuSn2Te6
Chwanchin Wang and Robert C. Haushalter
pp 595 - 597; DOI:
10.1021/ic980198c
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Synthesis and Structure of Solvent-Free Hexameric Magnesium Tri(tert-butyl)silylphosphandiide
Matthias Westerhausen, Mathias Krofta, and Arno Pfitzner
pp 598 - 599; DOI:
10.1021/ic9810485
PDF
Controlled Assembly Based on Multibridging Thiolate Ligands: New Polymeric Silver(I) Complexes with One-Dimensional Chain and Three-Dimensional Network Structures
Maochun Hong, Weiping Su, Rong Cao, Wenjian Zhang, and Jiaxi Lu
pp 600 - 602; DOI:
10.1021/ic980367t
PDF
New Reaction Path in the Dissociation of the Fe2(-OH)2(H2O)84+ Complex
Gábor Lente and István Fábián
pp 603 - 605; DOI:
10.1021/ic980813c
PDF
Synthesis, Characterization, and Intervalence Charge Transfer Properties of a Series of Rhenium(I)-Iron(III) Mixed-Valence Compounds
Brian W. Pfennig, Jamie L. Cohen, Irene Sosnowski, Nathan M. Novotny, and Douglas M. Ho
pp 606 - 612; DOI:
10.1021/ic9811751
PDF

Issue 4


Thermochromic Conformational Change of Methanobacterium thermoautotrophicum Iron Superoxide Dismutase
Jean Philippe Renault, Irène Morgenstern-Badarau, and Mario Piccioli
pp 614 - 615; DOI:
10.1021/ic981172o
PDF
Oxidation of Metal-Bound Thiolato Sulfur Centers in Fe(III) and Co(III) Complexes with Carboxamido Nitrogens and Thiolato Sulfurs as Donors: Relevance to the Active Sites of Nitrile Hydratases
Laurie A. Tyler, Juan C. Noveron, Marilyn M. Olmstead, and Pradip K. Mascharak
pp 616 - 617; DOI:
10.1021/ic980884b
PDF
Synthesis, Structural Characterization, and Solution Behavior of the First Mononuclear, Aqueous Aluminum Citrate Complex
M. Matzapetakis, C. P. Raptopoulou, A. Terzis, A. Lakatos, T. Kiss, and A. Salifoglou
pp 618 - 619; DOI:
10.1021/ic9806131
PDF
Molecular Recognition of Long Dicarboxylate/Dicarboxylic Species via Supramolecular/Coordinative Interactions with Ditopic Receptors. Crystal Structure of {[Cu2L(H2O)2]Pimelate}(ClO4)2
Carla Bazzicalupi, Andrea Bencini, Antonio Bianchi, Vieri Fusi, Enrique Garcia-España, Claudia Giorgi, José M. Llinares, José Antonio Ramirez, and Barbara Valtancoli
pp 620 - 621; DOI:
10.1021/ic9812151
PDF
Floating Bands in Nuclear Spectroscopy
Raymond K. Sheline
pp 622 - 632; DOI:
10.1021/ic981196v
PDF
Nickel(II) in an N4S Donor Environment: An Unprecedented Alcoholysis Reaction through the Activation of a Carbon-Nitrogen Single Bond
Sudeep Bhattacharyya, Timothy J. R. Weakley, and Muktimoy Chaudhury
pp 633 - 638; DOI:
10.1021/ic9703888
PDF
Phosphorus-31 Solid-State NMR Studies of Homonuclear Spin Pairs in Molybdenum Phosphine Complexes: Single-Crystal, Dipolar-Chemical Shift, Rotational-Resonance, and 2D Spin-Echo NMR Experiments
Klaus Eichele, Gabriel C. Ossenkamp, Roderick E. Wasylishen, and T. Stanley Cameron
pp 639 - 651; DOI:
10.1021/ic9806232
PDF
Solid State and Solution Structures of 9-Vertex Arachno Boron Hydride Clusters. An ab Initio/IGLO/NMR Study
Matthias Hofmann and Paul von Ragué Schleyer
pp 652 - 660; DOI:
10.1021/ic9714450
PDF
Triplet-Triplet Energy Transfer between Porphyrins Linked via a Ruthenium(II) Bisterpyridine Complex
Lucia Flamigni, Francesco Barigelletti, Nicola Armaroli, Barbara Ventura, Jean-Paul Collin, Jean-Pierre Sauvage, and J. A. Gareth Williams
pp 661 - 667; DOI:
10.1021/ic980847k
PDF
Ab Initio Configuration Interaction Calculation of the Exchange Coupling Constant in Hydroxo Doubly Bridged Cr(III) Dimers
O. Castell and R. Caballol
pp 668 - 673; DOI:
10.1021/ic980682f
PDF
Solvent-Dependent Studies of Intervalence Transfer of Mixed-Valence Complexes Containing Ferrocenylpyridine and Rutheniumammines
Tsun-Yang Liu, Yuan Jang Chen, Chih-Cheng Tai, and Keh Shin Kwan
pp 674 - 679; DOI:
10.1021/ic9713341
PDF
Synthesis and Characterization of Intermolecular Hydrogen Bond Stabilized Acyl(hydroxycarbene)platinum(II) Complexes
Dirk Steinborn, Michael Gerisch, Clemens Bruhn, and Julian A. Davies
pp 680 - 683; DOI:
10.1021/ic9805170
PDF
In Situ Monitoring of the Degradation of Iron Porphyrins by Dioxygen with Hydrazine as Sacrificial Reductant. Detection of Paramagnetic Intermediates in the Coupled Oxidation Process by 1H NMR Spectroscopy
Tamara N. St. Claire and Alan L. Balch
pp 684 - 691; DOI:
10.1021/ic981178d
PDF
Absorption Spectra, Photophysical Properties, and Redox Behavior of Stereochemically Pure Dendritic Ruthenium(II) Tetramers and Related Dinuclear and Mononuclear Complexes
Sebastiano Campagna, Scolastica Serroni, Swamy Bodige, and Frederick M. MacDonnell
pp 692 - 701; DOI:
10.1021/ic9811852
PDF
Synthesis of the Ferrocene Derivative FcCHN(CH2)2SH [Fc = (5-C5H5)Fe(5-C5H4)]: Reactivity toward (Phosphine)gold(I) Cations
Eva M. Barranco, M. Concepción Gimeno, Peter G. Jones, Antonio Laguna, and M. Dolores Villacampa
pp 702 - 706; DOI:
10.1021/ic980379e
PDF
Electronic Structure and Bonding in Tricoordinate Amido Complexes of Transition Metals
Ana A. Palacios, Pere Alemany, and Santiago Alvarez
pp 707 - 715; DOI:
10.1021/ic980634v
PDF
Structural and Electrical Characterization of Polymeric Haloplumbate(II) Systems
Anna Bonamartini Corradi, Anna Maria Ferrari, Gian Carlo Pellacani, Andrea Saccani, Franco Sandrolini, and Paolo Sgarabotto
pp 716 - 721; DOI:
10.1021/ic980893k
PDF
Spin-Dependent Delocalization in Three Isostructural Complexes [LFeNiFeL]2+/3+/4+ (L = 1,4,7-(4-tert-Butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane)
Thorsten Glaser, Frank Kesting, Thomas Beissel, Eckhard Bill, Thomas Weyhermüller, Wolfram Meyer-Klaucke, and Karl Wieghardt
pp 722 - 732; DOI:
10.1021/ic9811289
PDF
N-Nitrosohydroxylamine-N-sulfonate: A Redetermination of Its X-ray Crystal Structure and an Analysis of Its formation from NO and SO32- Using Ab Initio Molecular Orbital Calculations
John Reglinski, David R. Armstrong, Katherine Sealey, and Mark D. Spicer
pp 733 - 737; DOI:
10.1021/ic981173g
PDF
Solid State Compounds with Tin-Tin Bonding. Yb36Sn23: A Novel Compound Containing Oligomeric Tin Anions
E. Alejandro Leon-Escamilla and John D. Corbett
pp 738 - 743; DOI:
10.1021/ic980861x
PDF
Kinetics and Mechanisms of Reactions of Alkyl Hydroperoxides with Methylrhenium Oxides
Kimberly A. Brittingham and James H. Espenson
pp 744 - 750; DOI:
10.1021/ic9809052
PDF
Syntheses and Crystal Structures of a Linear-Chain Uranyl Phenylphosphinate UO2(O2PHC6H5)2 and Layered Uranyl Methylphosphonate UO2(O3PCH3)
Daniel Grohol, Franz Gingl, and Abraham Clearfield
pp 751 - 756; DOI:
10.1021/ic9809761
PDF
Synthesis and Structure of an Air-Stable, Free-Radical Cobalt(III) Semiquinone Complex
Steven Arzberger, Jake Soper, Oren P. Anderson, Agnete la Cour, and Mark Wicholas
pp 757 - 761; DOI:
10.1021/ic981052g
PDF
The Polar [WO2F4]2- Anion in the Solid State
Kevin R. Heier, Alexander J. Norquist, P. Shiv Halasyamani, Angel Duarte, Charlotte L. Stern, and Kenneth R. Poeppelmeier
pp 762 - 767; DOI:
10.1021/ic980863h
PDF
Methyl B12 Models Containing Unsubstituted Imidazole As an Axial Ligand Investigated by Structural and NMR Spectroscopic Methods. Evidence that -Imidazolato-Bridged Dimers Are Formed by Base Addition to Some Analogues with Macrocyclic Equatorial Ligands Incorporating BF2
Scott J. Moore, Alexander Kutikov, Rene J. Lachicotte, and Luigi G. Marzilli
pp 768 - 776; DOI:
10.1021/ic980944d
PDF
New Steric Hindrance Approach Employing the Hybrid Ligand 2-Aminomethylpiperidine for Diminishing Dynamic Motion Problems of Platinum Anticancer Drug Adducts Containing Guanine Derivatives
Hing C. Wong, Raymond Coogan, Francesco P. Intini, Giovanni Natile, and Luigi G. Marzilli
pp 777 - 787; DOI:
10.1021/ic980987u
PDF
Synthesis and Structural Characterization of New Polyphosphorus Ring and Cage Compounds
Danan Dou, Eileen N. Duesler, and Robert T. Paine
pp 788 - 793; DOI:
10.1021/ic980954e
PDF
Synthesis, X-ray Structure, and Physical and Photophysical Properties of the Heterobimetallic Complex Fe(5-C5H4PPh2)2Pt(bph)
Greg Y. Zheng, D. Paul Rillema, and Joseph H. Reibenspies
pp 794 - 797; DOI:
10.1021/ic980549n
PDF
Synthesis and Characterization of Chiral Platinum(II) Sulfonamides: (dppe)Pt(NN) and (dppe)Pt(NO) Complexes
Jennifer J. Becker, Peter S. White, and Michel R. Gagné
pp 798 - 801; DOI:
10.1021/ic981287s
PDF
Activation of Ligand Reactivity: Thiolate C-S and Dithiophosphate Ester C-O Heterolyses within a Dimolybdenum(V) System
Edith I. Koffi-Sokpa, D. Troy Calfee, Brian R. T. Allred, Jackie L. Davis, Elaine K. Haub, Alexis K. Rich, Richard A. Porter, Mark S. Mashuta, John F. Richardson, and Mark E. Noble
pp 802 - 813; DOI:
10.1021/ic981303l
PDF
Aqueous Phosphoester Bond Cleavage of Dimethyl Phosphate by Cp2MoCl2: First Reported Case of Hydrolytic Cleavage on an Unactivated Phosphate Diester by an Organometallic Complex
Louis Y. Kuo and Laurie A. Barnes
pp 814 - 817; DOI:
10.1021/ic970462m
PDF
Oxyanion Specificity of Aspartate--semialdehyde Dehydrogenase
Michelle M. Kish and Ronald E. Viola
pp 818 - 820; DOI:
10.1021/ic981082j
PDF
Synthesis and Crystal Structures of the Dithiolato Complexes [W(SPh)2(CO)2(PEt3)2] and [M{S(CH2)nS}(CO)2(PEt3)2] (M = Mo or W, n = 2; M = W, n = 3)
Paul K. Baker, Alec I. Clark, Michael G.B. Drew, Marcus C. Durrant, and Raymond L. Richards
pp 821 - 824; DOI:
10.1021/ic980469j
PDF
New Maze-Type Network Assembled by Copper(II) and 4,4'-Diaminodiphenylmethane: {[Cu(C13H14N2)(C3H4O4)Cl]Cl}2
Yugen Zhang, Masayoshi Nishiura, Li Jianmin, Deng Wei, and Tsuneo Imamoto
pp 825 - 827; DOI:
10.1021/ic980911y
PDF
An Improved High Yield Synthesis Procedure and Reactivity of W6S8(4-tert-butylpyridine)6
D. Venkataraman, Lori L. Rayburn, Laurie I. Hill, Song Jin, Abds-Sami Malik, Kevin J. Turneau, and Francis J. DiSalvo
pp 828 - 830; DOI:
10.1021/ic980967s
PDF
Platinum Complexes of Phospholes with Reduced Pyramidal Character from Steric Crowding
Zsolt Csók, György Keglevich, György Petocz, and László Kollár
pp 831 - 833; DOI:
10.1021/ic980963n
PDF
Binuclear Copper(II) Chelates with a 24-Membered Amide-Based Macrocycle
Michiko B. Inoue, Enrique F. Velazquez, Adriana Ruiz-Lucero, Motomichi Inoue, Arnold Raitsimring, and Quintus Fernando
pp 834 - 837; DOI:
10.1021/ic980747e
PDF
Modeling Tyrosinase Monooxygenase Activity. Spectroscopic and Magnetic Investigations of Products Due to Reactions between Copper(I) Complexes of Xylyl-Based Dinucleating Ligands and Dioxygen: A
Debalina Ghosh and Rabindranath Mukherjee
pp 838 - 838; DOI:
10.1021/ic990127t
PDF

Issue 5


Structural Characterization of a Tris-salicylate Coordination for Iron(III) with the Tripodal Ligand O-TRENSOX
Guy Serratrice, Paul Baret, Hakim Boukhalfa, Isabelle Gautier-Luneau, Dominique Luneau, and Jean-Louis Pierre
pp 840 - 841; DOI:
10.1021/ic980402w
PDF
"Electro-Photo Switch" and "Molecular Light Switch" Devices Based on Ruthenium(II) Complexes of Modified Dipyridophenazine Ligands: Modulation of the Photochemical Function through Ligand Design
S. Arounaguiri and Bhaskar G. Maiya
pp 842 - 843; DOI:
10.1021/ic981109z
PDF
Halogenated Carboxonium Salts: Preparation and Structural Analysis
Rolf Minkwitz, Stefan Reinemann, Oliver Blecher, Hans Hartl, and Irene Brüdgam
pp 844 - 847; DOI:
10.1021/ic981212o
PDF
Synthesis, Structure, and Solution NMR Studies of Cyanide-Copper(II) and Cyanide-Bridged Iron(III)-Copper(II) Complexes
Daniele M. Corsi, Narasimha N. Murthy, Victor G. Young, Jr., and Kenneth D. Karlin
pp 848 - 858; DOI:
10.1021/ic981091s
PDF
O-Alkylated Derivatives of 1,3,5-Triamino-1,3,5-trideoxy-cis-inositol: Triamine Ligands with Unexpectedly High Affinity toward Divalent Transition- and d10-Metal Ions
Michael Weber, Dirk Kuppert, Kaspar Hegetschweiler, and Volker Gramlich
pp 859 - 868; DOI:
10.1021/ic980867m
PDF
Solution and Solid State Structure of a Canted, Side-to-Face, Bis(porphyrin) Adduct
Enzo Alessio, Silvano Geremia, Stefano Mestroni, Elisabetta Iengo, Ivana Srnova, and Miroslav Slouf
pp 869 - 875; DOI:
10.1021/ic980816p
PDF
Electrochemical Kinetics of Cyanometalate Complexes in Aqueous Solution at High Pressures
Yansong Fu and Thomas W. Swaddle
pp 876 - 880; DOI:
10.1021/ic9810440
PDF
Kinetics and Mechanism of the Epoxidation of Allylic Alcohols by Hydrogen Peroxide with Methyltrioxorhenium as Catalyst
Heather Riley Tetzlaff and James H. Espenson
pp 881 - 885; DOI:
10.1021/ic981107e
PDF
Anisotropic Templating Effect in the Formation of Two-Dimensional Anionic Cadmium-Thiocyanate Coordination Solids [(12C4)2Cd][Cd2(SCN)6] and [(12C4)2Cd][Cd3(SCN)8] with Checkerboard and Herringbone Patterns, Respectively
Hong Zhang, Ximin Wang, H. Zhu, W. Xiao, Kecong Zhang, and Boon K. Teo
pp 886 - 892; DOI:
10.1021/ic980387v
PDF
Synthesis of Chiral C2-Symmetric Bisferrocenyldiamines. X-ray Crystal Structure of Ru(2)Cl2·2CHCl3 (2 = N1,N2-Bis{(R)-1-[(S)-2-(diphenylphosphino)]ferrocenylethyl}- N1,N2-dimethyl-1,2-ethanediamine)
Jeong-Ho Song, Dong-Jei Cho, Sang-Jin Jeon, Yong-Hoon Kim, Tae-Jeong Kim, and Jong Hwa Jeong
pp 893 - 896; DOI:
10.1021/ic980433r
PDF
Complexes of Multifunctional Phosphorus Ligands. Rhenium(V) Complexes of the Multidentate Phenoxyphosphine Ligands Bis(o-trimethylsilyloxyphenyl)phenylphosphine and Tris(o-trimethylsilyloxyphenyl)phosphine. Stepwise Elimination of Me3SiX (X = Cl, OEt) from the Metal-Ligand System
Ronald G. Cavell, Robert W. Hilts, Hongyan Luo, and Robert McDonald
pp 897 - 905; DOI:
10.1021/ic980304a
PDF
Synthesis and Characterization of Copper(I) Complexes with a Fairly Bulky Tris(pyrazolyl)hydroborate Ligand. Probing the Flexibility of the Metal-Containing Pocket Formed by the Ligand
Rebecca R. Conry, Guanzhen Ji, and A. Alex Tipton
pp 906 - 913; DOI:
10.1021/ic980851w
PDF
Significant Electronic Effect of Porphyrin Ligand on the Reactivities of High-Valent Iron(IV) Oxo Porphyrin Cation Radical Complexes
Yeong Mee Goh and Wonwoo Nam
pp 914 - 920; DOI:
10.1021/ic980989e
PDF
Metal Complexes of Pyridylphenylisocyanides and Pyridylethynylphenylisocyanides as Building Blocks for Coordination Polymers and Supramolecular Assemblies
Andreas Mayr and Jianhua Guo
pp 921 - 928; DOI:
10.1021/ic9803053
PDF
Density Functional and Electrostatic Calculations of Manganese Superoxide Dismutase Active Site Complexes in Protein Environments
Jian Li, Cindy L. Fisher, Robert Konecny, Donald Bashford, and Louis Noodleman
pp 929 - 939; DOI:
10.1021/ic980731o
PDF
CuZn Superoxide Dismutase Geometry Optimization, Energetics, and Redox Potential Calculations by Density Functional and Electrostatic Methods
Robert Konecny, Jian Li, Cindy L. Fisher, Valerie Dillet, Donald Bashford, and Louis Noodleman
pp 940 - 950; DOI:
10.1021/ic980730w
PDF
Excited-State Electronic Structure in Polypyridyl Complexes Containing Unsymmetrical Ligands
Kristin M. Omberg, Gregory D. Smith, Darius A. Kavaliunas, Pingyun Chen, Joseph A. Treadway, Jon R. Schoonover, Richard A. Palmer, and Thomas J. Meyer
pp 951 - 956; DOI:
10.1021/ic981338l
PDF
Preparation, Characterization, and Luminescence Properties of a 58-Electron Linear Pt4 Cluster, [Pt4(dmb)4(PPh3)2]2+ (dmb = 1,8-Diisocyano-p-menthane), and Its Diphosphine Polymers
Tianle Zhang, Marc Drouin, and Pierre D. Harvey
pp 957 - 963; DOI:
10.1021/ic9807947
PDF
Ligand and Tetrathiometalate Effects in Induced Internal Electron Transfer Reactions
C. A. McConnachie and E. I. Stiefel
pp 964 - 972; DOI:
10.1021/ic980674z
PDF
15N NMR and Electrochemical Studies of [RuII(hedta)]- Complexes of NO, NO+, NO2-, and NO-
Ya Chen, Fu-Tyan Lin, and Rex E. Shepherd
pp 973 - 983; DOI:
10.1021/ic980868e
PDF
Crystal Structures of a Series of Complexes Produced by Reaction of Copper(I) Cyanide with Diamines
Fred B. Stocker, Teodora P. Staeva, Chad M. Rienstra, and Doyle Britton
pp 984 - 991; DOI:
10.1021/ic970226b
PDF
Electrochemistry of Centered Hexanuclear Zirconium Halide Clusters in Ambient-Temperature Chloroaluminate Molten Salts
Dong Sun and Timothy Hughbanks
pp 992 - 997; DOI:
10.1021/ic981182p
PDF
Insertion Routes to Tetrasubstituted Guanidinate Complexes of Ta(V) and Nb(V)
Ma Khin Tan Tin, Glenn P. A. Yap, and Darrin S. Richeson
pp 998 - 1001; DOI:
10.1021/ic980709v
PDF
Test of Electron Delocalization Effects on Water-Proton Spin-Lattice Relaxation by Bromination of [Tetrakis(4-sulfonatopheny)porphine]manganese
L. Henry Bryant, Jr., Melinda Whaley Hodges, and Robert G. Bryant
pp 1002 - 1005; DOI:
10.1021/ic981197n
PDF
Diminishing Dynamic Motion Problems of Platinum Anticancer Drug Adducts of Guanine Derivatives with the Hybrid Ligand Approach: Evidence for Cis Interligand Interactions Especially between 3'-GMP's
Hing C. Wong, Francesco P. Intini, Giovanni Natile, and Luigi G. Marzilli
pp 1006 - 1014; DOI:
10.1021/ic981198f
PDF
Computer Modeling of the Oxygen-atom Transfer Reaction between Hydrogen Sulfite and a Molybdenum(VI) Dioxo Complex
Anders Thapper, Robert J. Deeth, and Ebbe Nordlander
pp 1015 - 1018; DOI:
10.1021/ic980646g
PDF
Protein Engineering: Design of Single-Residue-Anchored Metal-Uptake Systems
Subramania Ranganathan and Natarajan Tamilarasu
pp 1019 - 1023; DOI:
10.1021/ic980263i
PDF
The Synthesis, X-ray Crystal Structure, and Molecular Structure of Rhenium Tetra- carbonylbromidetrimethylamineisocyanoborane
Wendy C. Andersen, Daniel R. Mitchell, Kenneth J. H. Young, Xianhui Bu, Vincent M. Lynch, Hermann A. Mayer, and William C. Kaska
pp 1024 - 1027; DOI:
10.1021/ic980697d
PDF
Aminoguanidinium Fluorozirconates: Improved Synthesis and Thermal Decomposition of CN4H8ZrF6, CN4H8ZrF6·1/2H2O, CN4H8ZrF6·H2O, (CN4H7)2ZrF6, and CN4H7ZrF5
M. R. Bauer, C. R. Ross, II, R. M. Nielson, and S. C. Abrahams
pp 1028 - 1030; DOI:
10.1021/ic981216t
PDF
Bond Valence Sums in Coordination Chemistry Using New R0 Values. Potassium-Oxygen Complexes
Richard M. Wood and Gus J. Palenik
pp 1031 - 1034; DOI:
10.1021/ic981057d
PDF

Issue 6


Protonation and Dehydration Reactions of the Mn4O4L6 Cubane and Synthesis and Crystal Structure of the Oxidized Cubane [Mn4O4L6]+: A Model for the Photosynthetic Water Oxidizing Complex
Wolfgang F. Ruettinger, Douglas M. Ho, and G. Charles Dismukes
pp 1036 - 1037; DOI:
10.1021/ic981145y
PDF
Metal-Metal versus Metal-Arene Interactions in Polyfunctional Thallium(I) Amides
Christian H. Galka and Lutz H. Gade
pp 1038 - 1039; DOI:
10.1021/ic9813157
PDF
Synthesis, Structure, and Reactivity of Novel Dithiolato(oxo)rhenium(V) Complexes
Josemon Jacob, Ilia A. Guzei, and James H. Espenson
pp 1040 - 1041; DOI:
10.1021/ic981367w
PDF
Lanthanide Complexes of the -1 Isomer of the [P2W17O61]10- Heteropolytungstate: Preparation, Stoichiometry, and Structural Characterization by 183W and 31P NMR Spectroscopy and Europium(III) Luminescence Spectroscopy
Judit Bartis, Michaela Dankova, Jeremy J. Lessmann, Qun-Hui Luo, William DeW. Horrocks, Jr., and Lynn C. Francesconi
pp 1042 - 1053; DOI:
10.1021/ic980384i
PDF
NMR Spectra and Magnetic Exchange Interactions in Nickel(II) Complexes with a Chelated Nitronyl Nitroxide Radical
Takafumi Yoshida and Sumio Kaizaki
pp 1054 - 1058; DOI:
10.1021/ic9805426
PDF
Synthesis, Magnetic Properties, and Electronic Spectra of Octahedral Mixed-Ligand (-Diketonato)nickel(II) Complexes with a Chelated Nitronyl Nitroxide Radical
Takafumi Yoshida, Takayoshi Suzuki, Kan Kanamori, and Sumio Kaizaki
pp 1059 - 1068; DOI:
10.1021/ic981283n
PDF
Reversible Displacement of Polyagostic Interactions in 16e [Mn(CO)(R2PC2H4PR2)2]+ by H2, N2, and SO2. Binding and Activation of 2-H2 trans to CO Is Nearly Invariant to Changes in Charge and cis Ligands
Wayne A. King, Brian L. Scott, Juergen Eckert, and Gregory J. Kubas
pp 1069 - 1084; DOI:
10.1021/ic981263l
PDF
Structures of Fe(II) Complexes with N,N,N'-Tris(2-pyridylmethyl)ethane-1,2-diamine Type Ligands. Bleomycin-like DNA Cleavage and Enhancement by an Alkylammonium Substituent on the N' Atom of the Ligand
Pierre Mialane, Alexander Nivorojkine, Geneviève Pratviel, Laurent Azéma, Michaela Slany, Frédéric Godde, Ariane Simaan, Frédéric Banse, Taraneh Kargar-Grisel, Guy Bouchoux, Joelle Sainton, Olivier Horner, Jean Guilhem, Lyuba Tchertanova, Bernard Meunier, and Jean-Jacques Girerd
pp 1085 - 1092; DOI:
10.1021/ic971059i
PDF
Oxidative Addition of Tetrachloro-1,2-benzoquinone to 3-Cyclotriphosphazanes. An Unusual Ring Contraction-Rearrangement
Natesan Thirupathi, Setharampattu S. Krishnamurthy, and Munirathinam Nethaji
pp 1093 - 1098; DOI:
10.1021/ic980459i
PDF
Element-Element Bonds. IX.1 Structures of Tetrakis(trifluoromethyl)diphosphane and -diarsane: Experimental and Theoretical Investigations
Gerd Becker, Winfried Golla, Joseph Grobe, Karl Wilhelm Klinkhammer, Duc Le Van, Andreas H. Maulitz, Otto Mundt, Heinz Oberhammer, and Martin Sachs
pp 1099 - 1107; DOI:
10.1021/ic981218d
PDF
Oxidative-Addition Reactions of Diiodine to Dinuclear Rhodium Pyrazolate Complexes
Cristina Tejel, Marta Bordonaba, Miguel A. Ciriano, Andrew J. Edwards, William Clegg, Fernando J. Lahoz, and Luis A. Oro
pp 1108 - 1117; DOI:
10.1021/ic980650s
PDF
Molecular Structure of a Monomeric, Base-Free Metal(I) Amide, TlN[Si(CH3)3]2, by Gas Electron Diffraction and by Density Functional Theory and ab Initio MP2 Calculations
Arne Haaland, Dmitry J. Shorokhov, Hans Vidar Volden, and Karl Wilhelm Klinkhammer
pp 1118 - 1120; DOI:
10.1021/ic981217l
PDF
Tantalum-Gold and Tantalum-Copper Trihydride Complexes [Cp'2TaH3MPPh3][PF6] (Cp' = C5H4C(CH3)3). Structure Determination from 1H T1 Relaxation Studies
Vladimir I. Bakhmutov, Evgenii V. Vorontsov, Ekaterina V. Bakhmutova, Gilles Boni, and Claude Moise
pp 1121 - 1125; DOI:
10.1021/ic980765w
PDF
Comparison of Heteronuclear Coupling Constants for Isostructural Nitrogen Coordination Compounds of 111/113Cd and 199Hg
Deborah C. Bebout, Sarah W. Stokes, and Raymond J. Butcher
pp 1126 - 1133; DOI:
10.1021/ic980825y
PDF
Synthesis and Physicochemical Characterization of a New Gadolinium Chelate: The Liver-Specific Magnetic Resonance Imaging Contrast Agent Gd-EOB-DTPA
H. Schmitt-Willich, M. Brehm, Ch. L. J. Ewers, G. Michl, A. Müller-Fahrnow, O. Petrov, J. Platzek, B. Radüchel, and D. Sülzle
pp 1134 - 1144; DOI:
10.1021/ic981072i
PDF
Experimental and Theoretical Investigation of the Molecular and Electronic Structure of [Zn4(4-S){-S2As(CH3)2}6] and [Cd4(4-S){-S2As(CH3)2}6]: Two Possible Molecular Models of Extended Metal Chalcogenide Semiconductors
Alberto Albinati, Maurizio Casarin, Chiara Maccato, Luciano Pandolfo, and Andrea Vittadini
pp 1145 - 1152; DOI:
10.1021/ic980914a
PDF
Study of the Molecular Geometry, Electronic Structure, and Thermal Stability of Phosphazene and Heterophosphazene Rings with ab Initio Molecular Orbital Calculations
R. Jaeger, M. Debowski, I. Manners, and G. J. Vancso
pp 1153 - 1159; DOI:
10.1021/ic980877n
PDF
Synthesis of Zirconium Aryloxide Complexes Containing Pendent Vinyl Groups
William J. Evans, Mohammad A. Ansari, and Joseph W. Ziller
pp 1160 - 1164; DOI:
10.1021/ic981201v
PDF
pH-Dependent Monomer Oligomer Interconversion of Copper(II) Complexes with N-(2-R-imidazol-4-ylmethylidene)-2-aminoethylpyridine (R = Methyl, Phenyl)
Naohide Matsumoto, Yuri Motoda, Toshihiro Matsuo, Toshio Nakashima, Nazzareno Re, Francoise Dahan, and Jean-Pierre Tuchagues
pp 1165 - 1173; DOI:
10.1021/ic981158b
PDF
Synthesis, Crystal Structure, and Magnetic Properties of Oxalato-Copper(II) Complexes with 3,3-Bis(2-imidazolyl)propionic Acid, an Imidazole-Carboxylate Polyfunctional Ligand: From Mononuclear Entities to Ladder-Like Chains
Y. Akhriff, J. Server-Carrió, A. Sancho, J. García-Lozano, E. Escrivá, J. V. Folgado, and L. Soto
pp 1174 - 1185; DOI:
10.1021/ic980982x
PDF
Metal Complexes of New, Chiral N2O2 Tetradentate Ligands
Ronald J. Cross, Louis J. Farrugia, Paul D. Newman, Robert D. Peacock, and Diane Stirling
pp 1186 - 1192; DOI:
10.1021/ic980172l
PDF
A New Electron-Transfer Donor for Photoinduced Electron Transfer in Polypyridyl Molecular Assemblies
Colleen M. Partigianoni, Sandrine Chodorowski-Kimmes, Joseph A. Treadway, Durwin Striplin, Scott A. Trammell, and Thomas J. Meyer
pp 1193 - 1198; DOI:
10.1021/ic980544q
PDF
Role of the Invariant Peptide Fragment Forming NH···S Hydrogen Bonds in the Active Site of Cytochrome P-450 and Chloroperoxidase: Synthesis and Properties of Cys-Containing Peptide Fe(III) and Ga(III) (Octaethylporphinato) Complexes as Models
Takafumi Ueno, Nami Nishikawa, Shino Moriyama, Seiji Adachi, Keonil Lee, Taka-aki Okamura, Norikazu Ueyama, and Akira Nakamura
pp 1199 - 1210; DOI:
10.1021/ic980710u
PDF
Unusual Me-O Bond Cleavage in a Metalated Crown-Ether: X-ray Molecular Structure of (5-Methoxy-4,6-dimethyl-1,3-xylylene-2-one)-15 Crown-4 Complex of Pentamethylcyclopentadienyl Iridium
H. Amouri, J. Vaissermann, M. N. Rager, and Y. Besace
pp 1211 - 1215; DOI:
10.1021/ic980811s
PDF
Crystallization in Nonaqueous Media of Co- and Mn-Substituted Microporous Aluminophosphates Investigated by in Situ Synchrotron X-ray Powder Diffraction
P. Norby, A. Nrlund Christensen, and J. C. Hanson
pp 1216 - 1221; DOI:
10.1021/ic980749z
PDF
A New Manganese Dinuclear Complex with Phenolate Ligands and a Single Unsupported Oxo Bridge. Storage of Two Positive Charges within Less than 500 mV. Relevance to Photosynthesis
Olivier Horner, Elodie Anxolabéhère-Mallart, Marie-France Charlot, Lyuba Tchertanov, Jean Guilhem, Tony A. Mattioli, Alain Boussac, and Jean-Jacques Girerd
pp 1222 - 1232; DOI:
10.1021/ic980832m
PDF
Reaction Mechanism for Olefin Exchange at Chloro Ethene Complexes of Platinum(II)
Maria Rosaria Plutino, Stefanus Otto, Andreas Roodt, and Lars I. Elding
pp 1233 - 1238; DOI:
10.1021/ic981020t
PDF
Formation of Dinuclear Copper(II) Complexes from a Macrocycle with Built-in Pyrazole Groups
Richard H. Bode, Johan E. Bol, Willem L. Driessen, Frans B. Hulsbergen, Jan Reedijk, and Anthony L. Spek
pp 1239 - 1243; DOI:
10.1021/ic9811704
PDF
Interaction of M3+ Lanthanide Cations with Amide, Pyridine, and Phosphoryl O=PPh3 Ligands: A Quantum Mechanics Study
F. Berny, N. Muzet, L. Troxler, A. Dedieu, and G. Wipff
pp 1244 - 1252; DOI:
10.1021/ic980788a
PDF
Chemistry of the Ag2(dmb)22+ Template (dmb = 1,8-Diisocyano-p-menthane). Preparation, Characterization, and X-ray Structures of the Ag2(dmb)2Y2 Dimers (Y = NO3-, ClO4-, CH3CO2-) and the Paramagnetic [Ag4(dmb)4(TCNQ)3]TCNQ Complex (TCNQ = 7,7,8,8-Tetracyanoquinodimethane)
Daniel Fortin, Marc Drouin, Pierre D. Harvey, F. Geoffrey Herring, David A. Summers, and Robert C. Thompson
pp 1253 - 1260; DOI:
10.1021/ic980974g
PDF
Enantioselective Sulfoxidation as a Probe for a Metal-Based Mechanism in H2O2-Dependent Oxidations Catalyzed by a Diiron Complex
Carole Duboc-Toia, Stéphane Ménage, Raymond Y. N. Ho, Lawrence Que, Jr., Claude Lambeaux, and Marc Fontecave
pp 1261 - 1268; DOI:
10.1021/ic980958j
PDF
Synthesis, Characterization, and Reactivity of Urea Derivatives Coordinated to Cobalt(III). Possible Relevance to Urease
Lee Roecker, Janet Akande, L. Nelson Elam, Irina Gauga, Billy W. Helton, Miranda C. Prewitt, Alan M. Sargeson, Jason H. Swango, Anthony C. Willis, Tianpei Xin, and Jun Xu
pp 1269 - 1275; DOI:
10.1021/ic980287p
PDF
High-Spin (meso-Tetraalkylporphyrinato)iron(III) Complexes As Studied by X-ray Crystallography, EPR, and Dynamic NMR Spectroscopies
Takahisa Ikeue, Yoshiki Ohgo, Akira Uchida, Mikio Nakamura, Hiroshi Fujii, and Masataka Yokoyama
pp 1276 - 1281; DOI:
10.1021/ic981184+
PDF
New SO2 Iron-Containing Cluster Compounds [PPN]2[Fe3(CO)9(3,2-SO2)], [PPN]2[Fe3(CO)8(-SO2)3-S], [PPN]2[Fe3(CO)8(-SO2)(3-CCO)], and [PPN]2[Fe2(CO)6(-SO2)2] from Heterometal Precursors
R. W. Eveland, C. C. Raymond, T. E. Albrecht-Schmitt, and D. F. Shriver
pp 1282 - 1287; DOI:
10.1021/ic980762j
PDF
Investigations of the Copper Bromide-2,2'-Dipyridyl System: Hydrothermal Synthesis and Structural Characterization of Molecular Cu3Br4(C10H8N2)2, One-Dimensional CuBr2(C10H8N2), and Two-Dimensional [Cu2(OH)2(C10H8N2)2][Cu4Br6]
Robert P. Hammond, Michael Cavaluzzi, Robert C. Haushalter, and Jon A. Zubieta
pp 1288 - 1292; DOI:
10.1021/ic980997v
PDF
Synthesis and Characterization of Indium Compounds with Phosphinothiol Ligands. The Crystal and Molecular Structures of [In{2-(Ph2P)C6H4S}3], [In{2-(Ph2P)-6-(Me3Si)C6H3S}2{2-(Ph2PO)-6-(Me3Si)C6H3S}], and [NMe4][In{PhP(C6H4S-2)2}2]·CH3CN
Paulo Pérez-Lourido, Jaime Romero, José Arturo García-Vázquez, Antonio Sousa, Kevin Maresca, and Jon Zubieta
pp 1293 - 1298; DOI:
10.1021/ic980282s
PDF
Hypochlorite Ion Decomposition: Effects of Temperature, Ionic Strength, and Chloride Ion
Luke C. Adam and Gilbert Gordon
pp 1299 - 1304; DOI:
10.1021/ic980020q
PDF
Preparation, Spectroscopic Characterization, and Theoretical Study of the [Pd4(dmb)4(PPh3)2]Cl2 Complex (dmb = 1,8-Diisocyano-p-menthane) and Its Organometallic Polymer {[Pd4(dmb)5](CH3CO2)2}n: The First Examples of 58-Electron Linear Pd4 Clusters
Tianle Zhang, Marc Drouin, and Pierre D. Harvey
pp 1305 - 1315; DOI:
10.1021/ic9811594
PDF
Structure and Apparent Reactivity of the -Cation Radical Derivatives of Zinc and Copper 5,10,15,20-Tetra(2,6-dichlorophenyl)porphyrinate
Noëlle Ehlinger and W. Robert Scheidt
pp 1316 - 1321; DOI:
10.1021/ic981041n
PDF
Investigation of Zinc Chelation in Zinc-Finger Arrays by Electrospray Mass Spectrometry
D. Fabris, Y. Hathout, and C. Fenselau
pp 1322 - 1325; DOI:
10.1021/ic9809963
PDF
Technetium Complexes of a Hydrazinonicotinamide-Conjugated Cyclic Peptide and 2-Hydrazinopyridine: Synthesis and Characterization
Shuang Liu, D. Scott Edwards, Anthony R. Harris, Stuart J. Heminway, and John A. Barrett
pp 1326 - 1335; DOI:
10.1021/ic980973o
PDF
Evidence for Nondissociative Ligand Exchange within [4+2]-Coordinate Phosphorus Species in Solution
Moni Chauhan, Claude Chuit, Alain Fruchier, and Catherine Reyé
pp 1336 - 1339; DOI:
10.1021/ic9811749
PDF
Crystal Structure and Energy Transfer in Double-Complex Salts Composed of Tris(2,2'-bipyridine)ruthenium(II) or Tris(2,2'-bipyridine)osmium(II) and Hexacyanochromate(III)
Takuhiro Otsuka, Naoto Takahashi, Naoki Fujigasaki, Akiko Sekine, Yuji Ohashi, and Youkoh Kaizu
pp 1340 - 1347; DOI:
10.1021/ic9810541
PDF
Synthesis and Structures of [In4(4,4'-bipy)3(HPO4)4(H2PO4)4]·4H2O and In4(4,4'-bipy)3(HPO4)4(H2PO4)4, Indium Phosphates with a Pillared Layer Structure
Kwang-Hwa Lii and Yuh-Feng Huang
pp 1348 - 1350; DOI:
10.1021/ic9715106
PDF
Heterodinuclear Macrocyclic Complexes Containing Both Nickel(II) and Lanthanide(III) Ions
Jerzy Lisowski and Przemysaw Starynowicz
pp 1351 - 1355; DOI:
10.1021/ic971416p
PDF
Trigonal-Planar Zinc(II) and Cadmium(II) Tris(phenoxide) Complexes
Donald J. Darensbourg, Sharon A. Niezgoda, Jennifer D. Draper, and Joseph H. Reibenspies
pp 1356 - 1359; DOI:
10.1021/ic9805325
PDF
Crystal Structure and Magnetic Properties of Polybis(formamide)bis(-formato)cobalt(II): An Extended Two-Dimensional Square Lattice Material Which Exhibits Spontaneous Magnetization below 9 K
Steven J. Rettig, Robert C. Thompson, James Trotter, and Shihua Xia
pp 1360 - 1363; DOI:
10.1021/ic980742h
PDF
Aggregation of the Half-Sandwich Trisulfido Complex of Tungsten with Silver Ions: Synthesis of a Cyanide-Bridged Helical Polymer {[(5-C5Me5)WS3]2Ag3(CN)} and a Cyclic Cluster [(5-C5Me5)WS3Ag]4
Jian-Ping Lang and Kazuyuki Tatsumi
pp 1364 - 1367; DOI:
10.1021/ic980883j
PDF
Metal-Dependent Intramolecular Chiral Induction: The Zn2+ Complex of an Ethidium-Peptide Conjugate
Robert P. Houser, Marilena P. Fitzsimons, and Jacqueline K. Barton
pp 1368 - 1370; DOI:
10.1021/ic981012c
PDF

Issue 7


Monitoring Cysteine and Histidine Ligands in Zinc-Finger Peptides via Ultraviolet Resonance Raman Spectroscopy
Mária Vargek, Xiaojie Zhao, Zhihong Lai, George L. McLendon, and Thomas G. Spiro
pp 1372 - 1373; DOI:
10.1021/ic980871y
PDF
Luminescent Lanthanide Complexes with Encapsulating Polybenzimidazole Tripodal Ligands
Cheng-Yong Su, Bei-Sheng Kang, Han-Qin Liu, Qi-Guang Wang, Zhong-Ning Chen, Zhong-Ling Lu, Ye-Xiang Tong, and Thomas C. W. Mak
pp 1374 - 1375; DOI:
10.1021/ic980899+
PDF
Cationic Tetrasilver Complex of Hexaphenylbenzene
Gui Ling Ning, Megumu Munakata, Liang Ping Wu, Masahiko Maekawa, Takayoshi Kuroda-Sowa, Yusaku Suenaga, and Kunihisa Sugimoto
pp 1376 - 1377; DOI:
10.1021/ic981133c
PDF
Diamond-Shaped Heterometallic Complexes of Iron(II) and Copper(I) Bridged by Cyanide Groups
Donald J. Darensbourg, Way-Zen Lee, M. Jason Adams, David L. Larkins, and Joseph H. Reibenspies
pp 1378 - 1379; DOI:
10.1021/ic981419h
PDF
Homoleptic Bismuth and Antimony Complexes of the Tripodal [Te(NtBu)3]2- Anion
Tristram Chivers, Masood Parvez, Gabriele Schatte, and Glenn P. A. Yap
pp 1380 - 1381; DOI:
10.1021/ic9814322
PDF
Solvothermal Elemental Direct Reaction to CdE (E = S, Se, Te) Semiconductor Nanorod
Yadong Li, Hongwei Liao, Yi Ding, Yue Fan, Yue Zhang, and Yitai Qian
pp 1382 - 1387; DOI:
10.1021/ic980878f
PDF
Bivalent, Trivalent, and Tetravalent Nickel Complexes with a Common Tridentate Deprotonated Pyridine Bis-Amide Ligand. Molecular Structures of Nickel(II) and Nickel(IV) and Redox Activity
Apurba Kumar Patra and Rabindranath Mukherjee
pp 1388 - 1393; DOI:
10.1021/ic980672e
PDF
Hydrothermal Synthesis and Characterization of Novel One-Dimensional Tellurites of Molybdenum(VI), A4Mo6TeO22·2H2O (A = NH4, Rb)
Vidyavathy Balraj and K. Vidyasagar
pp 1394 - 1400; DOI:
10.1021/ic980957r
PDF
Spectroscopic Evidence for a Unique Bonding Interaction in Oxo-Molybdenum Dithiolate Complexes: Implications for Electron Transfer Pathways in the Pyranopterin Dithiolate Centers of Enzymes
Frank E. Inscore, Rebecca McNaughton, Barry L. Westcott, Matthew E. Helton, Robert Jones, Ish K. Dhawan, John H. Enemark, and Martin L. Kirk
pp 1401 - 1410; DOI:
10.1021/ic981126o
PDF
High-Pressure, Low-Temperature Emission Studies of a Metal-Organic Platinum(II) Compound in a Shpol'skii Matrix
Hartmut Yersin, Dietrich Trümbach, and Harald Wiedenhofer
pp 1411 - 1415; DOI:
10.1021/ic9807846
PDF
Structural Variation of Dinuclear Transition Metal Compounds with a Common Type of Ligand: Solid State and Solution Structures and Model Studies
Peter Comba, Sergey P. Gavrish, Robert W. Hay, Peter Hilfenhaus, Yaroslaw D. Lampeka, Philip Lightfoot, and Alexander Peters
pp 1416 - 1421; DOI:
10.1021/ic9807184
PDF
Synthesis, Structure, and Physicochemical Properties of ((Ethylsulfanyl)porphyrazinato)cobalt(II). Metal-Ligand Bonds in Co(OESPz) and in Related Cobalt(II) Tetrapyrroles: Insights from a Density Functional Study
Giampaolo Ricciardi, Angela Rosa, Ilaria Ciofini, and Alessandro Bencini
pp 1422 - 1431; DOI:
10.1021/ic9811547
PDF
Studies on Mixed -Diketonate/Isopropoxide Compounds of Zirconium and Hafnium, the X-ray Single-Crystal Structures of [M2(OPri)6(tmhd)2] (M = Zr, Hf): Some Chemistry Important in the MOCVD of Oxides
Kirsty A. Fleeting, Paul O'Brien, David J. Otway, Andrew J. P. White, David J. Williams, and Anthony C. Jones
pp 1432 - 1437; DOI:
10.1021/ic980690w
PDF
Tungsten-Tungsten Multiple-Bond Functionalities Supported by a Polyoxo Surface Modeled by Calix[4]arene
Luca Giannini, Euro Solari, Carlo Floriani, Nazzareno Re, Angiola Chiesi-Villa, and Corrado Rizzoli
pp 1438 - 1445; DOI:
10.1021/ic9811796
PDF
Dual Role of Pyridine N-Oxides in Ruthenium Porphyrin-Catalyzed Asymmetric Epoxidation of Olefins
Zeev Gross and Santiago Ini
pp 1446 - 1449; DOI:
10.1021/ic981021l
PDF
Platinum-Thioether Bonds Can Be Reverted by Guanine-N7 Bonds in Pt(dien)2+ Model Adducts
Stella S. G. E. van Boom, Bao Wei Chen, Jan Maarten Teuben, and Jan Reedijk
pp 1450 - 1455; DOI:
10.1021/ic981086o
PDF
Chemical Speciation of the Uranyl Ion under Highly Alkaline Conditions. Synthesis, Structures, and Oxo Ligand Exchange Dynamics
David L. Clark, Steven D. Conradson, Robert J. Donohoe, D. Webster Keogh, David E. Morris, Phillip D. Palmer, Robin D. Rogers, and C. Drew Tait
pp 1456 - 1466; DOI:
10.1021/ic981137h
PDF
Kinetics and Mechanism of Nitric Oxide Disproportionation upon Reaction with Ruthenium(II) Porphyrin Carbonyls: Evidence for Dinitrosyl Intermediates
Ivan M. Lorkovi and Peter C. Ford
pp 1467 - 1473; DOI:
10.1021/ic981121r
PDF
Interaction of Palladium(II) Complexes with Sulfur-Containing Peptides Studied by Electrospray Mass Spectrometry
Xuemei Luo, Wei Huang, Yuhua Mei, Shaozhen Zhou, and Longgen Zhu
pp 1474 - 1480; DOI:
10.1021/ic9805473
PDF
Metal-Modified Base Pairs Involving Different Donor Sites of Purine Nucleobases: trans-[a2Pt(7,9-DimeG-N1)(9-EtGH-N7)]2+ and trans-[a2Pt(7,9-DimeG-N1)(9-EtG-N7)]+ (a = NH3 or CH3NH2; 9-EtGH = 9-Ethylguanine; 7,9-DimeG = 7,9-Dimethylguanine). Possible Relevance to Metalated DNA Triplex Structures
Roland K. O. Sigel, Michal Sabat, Eva Freisinger, Amanda Mower, and Bernhard Lippert
pp 1481 - 1490; DOI:
10.1021/ic981005o
PDF
Alkaline Transition of Pseudoazurin from Achromobacter cycloclastes Studied by Paramagnetic NMR and Its Effect on Electron Transfer
Christopher Dennison and Takamitsu Kohzuma
pp 1491 - 1497; DOI:
10.1021/ic981242r
PDF
Reaction of Photoluminescent Porous Silicon Surfaces with Lithium Reagents To Form Silicon-Carbon Bound Surface Species
Jae Hee Song and Michael J. Sailor
pp 1498 - 1503; DOI:
10.1021/ic980303i
PDF
Synthesis, Mass Spectrometry, and Spectroscopic Properties of a Dinuclear Ruthenium Complex Comprising a 20 Å Long Fully Aromatic Bridging Ligand
Eléna Ishow, André Gourdon, Jean-Pierre Launay, Claudio Chiorboli, and Franco Scandola
pp 1504 - 1510; DOI:
10.1021/ic9812196
PDF
Synthesis and Characterization of Rhenium(III) Organohydrazide Compounds. Crystal and Molecular Structures of [ReCl(PPh3)2(NHNC5H4N)(HNNC5H4N)]Cl2, [Re{2-(Ph2P)C6H4S}{2-(Ph2PO)C6H4S}(NNC5H4N)(HNNC5H4N)], and [Re{2-(Ph2P)C6H4S}2(NNC5H4N)]
Paulo Pérez-Lourido, Jaime Romero, J. A. García-Vázquez, Antonio Sousa, Kevin P. Maresca, and Jon Zubieta
pp 1511 - 1519; DOI:
10.1021/ic980953m
PDF
Use of Norbornadiene in Solar Energy Storage: Theoretical Study of a Copper(I) Photosensitizer for the Norbornadiene-Quadricyclane Transformation
Marzio Rosi, Antonio Sgamellotti, Federico Franceschi, and Carlo Floriani
pp 1520 - 1522; DOI:
10.1021/ic9813314
PDF
Two- and Three-Dimensional Cadmium Coordination Polymers Based on N,N-(2-Pyridyl)-(4-pyridylmethyl)amine
Zhiyong Wang, Ren-Gen Xiong, Bruce M. Foxman, Scott R. Wilson, and Wenbin Lin
pp 1523 - 1528; DOI:
10.1021/ic981123b
PDF
Synthesis and Reactivity of Dinuclear Complexes Containing 2-Phenyl-Metal Interactions. Crystal Structures of [NBu4][(C6F5)3Pt{-Ph2PCH2PPh(2-Ph)}Pt(C6F5)2] and [NBu4][(C6F5)3Pt(-dppm)Pt(C6F5)2(CO)]
José M. Casas, Juan Forniés, Francisco Martínez, Angel J. Rueda, Milagros Tomás, and Alan J. Welch
pp 1529 - 1534; DOI:
10.1021/ic9808753
PDF
Synthesis and Characterization of Nanoscale Molybdenum Sulfide Catalysts by Controlled Gas Phase Decomposition of Mo(CO)6 and H2S
Michael R. Close, Jeffrey L. Petersen, and Edwin L. Kugler
pp 1535 - 1542; DOI:
10.1021/ic980700t
PDF
Insensitivity of Vanadyl-Oxygen Bond Strengths to Radical Type (2A1u vs 2A2u) in Vanadyl Porphyrin Cation Radicals
Kazimierz Czarnecki, Leonard M. Proniewicz, Hiroshi Fujii, David Ji, Roman S. Czernuszewicz, and James R. Kincaid
pp 1543 - 1547; DOI:
10.1021/ic981369g
PDF
Reactions of the Eight-Coordinate Rhenium Complex ReH4(hq)(PPh3)2 (hq = 2-Hydroxyquinoline Monoanion) with Monodentate Tertiary Phosphines: Formation of Pentagonal Bipyramidal Dihydridorhenium(III) Complexes of the Type ReH2(hq)(PPh3)2(PR3)
Talia M. McKinney, Phillip E. Fanwick, and Richard A. Walton
pp 1548 - 1554; DOI:
10.1021/ic981155z
PDF
Stereoselectivity in the Formation of Metallomacrocycles from [Mo(NO){HB(3,5-Me2C3HN2)3}I2] and Ditopic Proligands: The X-ray Crystal Structures of anti-[[Mo(NO){HB(3,5-Me2C3HN2)3}{1,4-(OCH2)2C6H4}]2·4CHCl3, syn-[Mo(NO){HB(3,5-Me2C3HN2)3}{1,4-(OCH2)2C6H4}]2·2CH2Cl2, and anti-[Mo(NO){HB(3,5-Me2C3HN2)3}{(4-OC6H4)2CH2}]2·2CHCl3·CH2Cl2
Ferida S. McQuillan, Hongli Chen, Thomas A. Hamor, Christopher J. Jones, Helen A. Jones, and R. Peter Sidebotham
pp 1555 - 1562; DOI:
10.1021/ic981010s
PDF
Phosphine-Based Dinuclear Platinum(II) Diamido, Amido-Hydroxo, Oxo-Amido, Oxo-Imido, Diimido, and Dihydrazido Complexes
Jian Jun Li, Wei Li, Alan J. James, Todd Holbert, Tristan P. Sharp, and Paul R. Sharp
pp 1563 - 1572; DOI:
10.1021/ic981246w
PDF
Electron Redistribution in Pt2(dta)4I: From Building Blocks to the Infinite Chain. A Theoretical Investigation of Possible Peierls Distortions
Vincent Robert, Sébastien Petit, and Serguei A. Borshch
pp 1573 - 1578; DOI:
10.1021/ic9812353
PDF
Mechanism of CO2 and H+ Reduction by Ni(cyclam)+ in Aqueous Solution. A Pulse and Continuous Radiolysis Study
Craig A. Kelly, Elliott L. Blinn, Nadia Camaioni, Mila D'Angelantonio, and Quinto G. Mulazzani
pp 1579 - 1584; DOI:
10.1021/ic980902p
PDF
Calix[4]arene Ligands with Phosphorus-Containing Groups Tethered at the Upper Rim
Izilda A. Bagatin, Dominique Matt, Holger Thönnessen, and Peter G. Jones
pp 1585 - 1591; DOI:
10.1021/ic980964f
PDF
Electron Transfer. 139. Reductions with Trioxodinitrate, [N2O3]2-
Ahmad M. Al-Ajlouni and Edwin S. Gould
pp 1592 - 1595; DOI:
10.1021/ic981194a
PDF
Binuclear Gd3+ Complex of a 34-Membered Macrocycle with Six Carboxymethyl Arms: X-ray Structures, Formation Constants, NMR, EPR, and 1H NMR Relaxivities
Michiko B. Inoue, Hisila Santacruz, Motomichi Inoue, and Quintus Fernando
pp 1596 - 1602; DOI:
10.1021/ic981015p
PDF
Syntheses and Stuctures of Alkyl Peroxo Adducts of -Diketonate Cobalt(III) Complexes and Their Role in Oxidation of Hydrocarbons and Olefin Epoxidation
Ferman A. Chavez, Jorge A. Briones, Marilyn M. Olmstead, and Pradip K. Mascharak
pp 1603 - 1608; DOI:
10.1021/ic980970b
PDF
Chemical Bonding in the Ternary Transition Metal Bismuthides Ti4TBi2 with T = Cr, Mn, Fe, Co, and Ni
Ruedi Rytz and Roald Hoffmann
pp 1609 - 1617; DOI:
10.1021/ic981075v
PDF
Density Functional Theory Studies of the Binding of Molecular Oxygen with Schiff's Base Complexes of Cobalt
Neil J. Henson, P. Jeffrey Hay, and Antonio Redondo
pp 1618 - 1626; DOI:
10.1021/ic9813056
PDF
Synthesis and Structures of Gallium Alkylthiolate Compounds
Seigi Suh, Jon H. Hardesty, Thomas A. Albright, and David M. Hoffman
pp 1627 - 1633; DOI:
10.1021/ic981318j
PDF
C-S Bond Cleavage by Chloride in a Thioether N2S2 Complex of Platinum
Lyall R. Hanton and Kitty Lee
pp 1634 - 1637; DOI:
10.1021/ic980781t
PDF
Luminescence Properties and Crystal Structures of Dicyano(diimine)platinum(II) Complexes Controlled by Pt···Pt and - Interactions
Masako Kato, Chizuko Kosuge, Katsuyuki Morii, Jeung Sun Ahn, Hiroshi Kitagawa, Tadaoki Mitani, Michio Matsushita, Tatsuhisa Kato, Shigenobu Yano, and Masaru Kimura
pp 1638 - 1641; DOI:
10.1021/ic981027a
PDF
Asymmetric Benzothiophene Condensation Facilitated by Platinum(II). The Distinct Roles of Platinum(II) and Palladium(II)
F. Teixidor, P. Anglès, C. Viñas, R. Kivekäs, and R. Sillanpää
pp 1642 - 1644; DOI:
10.1021/ic971425y
PDF

Issue 8


Back-bonding Manifestation on the Stability of a Pyridinethiolate Surface Modifier at a Gold Electrode
Izaura C. N. Diógenes, Francisco C. Nart, and Icaro S. Moreira
pp 1646 - 1647; DOI:
10.1021/ic981207k
PDF
[Cd2(H2O)4][Re6S8(CN)6]·14H2O: A Cyano-Bridged Cluster-Cluster Framework Solid with Accessible Cubelike Cavities
Matthew P. Shores, Laurance G. Beauvais, and Jeffrey R. Long
pp 1648 - 1649; DOI:
10.1021/ic9900408
PDF
Structural Analysis of All the Nickel 14-Membered Tetraaza Macrocycles in the Cambridge Structural Database
Maria A. Donnelly and Marc Zimmer
pp 1650 - 1658; DOI:
10.1021/ic980918f
PDF
The Reduction Pathway of End-on Coordinated Dinitrogen. I. Vibrational Spectra of Mo/W-N2, -NNH, and -NNH2 Complexes and Quantum Chemistry Assisted Normal Coordinate Analysis
Nicolai Lehnert and Felix Tuczek
pp 1659 - 1670; DOI:
10.1021/ic980939+
PDF
The Reduction Pathway of End-on Coordinated Dinitrogen. II. Electronic Structure and Reactivity of Mo/W-N2, -NNH, and -NNH2 Complexes
Nicolai Lehnert and Felix Tuczek
pp 1671 - 1682; DOI:
10.1021/ic9809409
PDF
Synthesis and Physicochemical Characterization of Protonated and Deprotonated Forms in Heteroleptic Lanthanide(III) Porphyrinate Double-Deckers. X-ray Structure of GdIIIH(oep)(tpp) at 298 and 21 K
Georgios A. Spyroulias, Catherine P. Raptopoulou, Dominique de Montauzon, Alain Mari, René Poilblanc, Aris Terzis, and Athanassios G. Coutsolelos
pp 1683 - 1696; DOI:
10.1021/ic970879s
PDF
Coenzyme B12 Axial-Base Chemical Precedent Studies. Adenosylcobinamide Plus Sterically Hindered Axial-Base Co-C Bond Cleavage Product and Kinetic Studies: Evidence for the Dominance of Axial-Base Transition-State Effects and for Co-N(Axial-Base) Distance-Dependent, Competing and Effects
Jeanne M. Sirovatka and Richard G. Finke
pp 1697 - 1707; DOI:
10.1021/ic980608x
PDF
Kinetic Studies of the Alkylation of Metal Cyanide Complexes: M(CO)x(L)5-xCN (M = Mn, Re) and CpM'(CO)x(L)2-xCN (M' = Fe, Ru)
Laurie A. Cardoza and Robert J. Angelici
pp 1708 - 1712; DOI:
10.1021/ic981014x
PDF
Aggregation of Fe(III)TPPS4 on Biological Structures Is pH-Dependent, Suggesting Oxo-Bridging in the Aggregates
Victor E. Yushmanov
pp 1713 - 1718; DOI:
10.1021/ic980377u
PDF
Design, Synthesis, and Crystal Structure of a cis-Configuration N2S2-Coordinated Palladium(II) Complex: Role of the Intra- and Intermolecular Aromatic-Ring Stacking Interaction
Ze-Hua Liu, Chun-Ying Duan, Jun Hu, and Xiao-Zeng You
pp 1719 - 1724; DOI:
10.1021/ic9711731
PDF
Synthesis and Structures of Oxyanion Encapsulated Copper(I)-dppm Complexes (dppm = Bis(diphenylphosphino)methane)
Jitendra K. Bera, Munirathnam Nethaji, and Ashoka G. Samuelson
pp 1725 - 1735; DOI:
10.1021/ic9801589
PDF
Anti-Inflammatory Dinuclear Copper(II) Complexes with Indomethacin. Synthesis, Magnetism and EPR Spectroscopy. Crystal Structure of the N,N-Dimethylformamide Adduct
Jane E. Weder, Trevor W. Hambley, Brendan J. Kennedy, Peter A. Lay, Dugald MacLachlan, Richard Bramley, Christopher D. Delfs, Keith S. Murray, Boujemaa Moubaraki, Barry Warwick, John R. Biffin, and Hubertus L. Regtop
pp 1736 - 1744; DOI:
10.1021/ic981100x
PDF
One-Pot Synthesis, Structure, and Unusual Luminescence of Novel One-Dimensional Lanthanide(III) Tetramethoxyborates
Alison S. Gajadhar-Plummer, Ishenkumba A. Kahwa, Andrew J. P. White, and David J. Williams
pp 1745 - 1753; DOI:
10.1021/ic9810788
PDF
Stacking Surface Effect in the DNA Intercalation of Some Polypyridine Platinum(II) Complexes
Matteo Cusumano, Maria Letizia Di Pietro, and Antonino Giannetto
pp 1754 - 1758; DOI:
10.1021/ic9809759
PDF
Mono- and Trinuclear Nickel(II) Complexes with Sulfur-Containing Oxime Ligands: Uncommon Templated Coupling of Oxime with Nitrile
Vitaly V. Pavlishchuk, Sergey V. Kolotilov, Anthony W. Addison, Michael J. Prushan, Raymond J. Butcher, and Laurence K. Thompson
pp 1759 - 1766; DOI:
10.1021/ic981277r
PDF
Y21I18C14B7: Synthesis, Average Structure, and Structural Misfit
Oliver Oeckler, Viola Duppel, Hansjürgen Mattausch, and Arndt Simon
pp 1767 - 1771; DOI:
10.1021/ic981377x
PDF
Nickel(II) and Zinc(II) meso-Tetracyclohexylporphyrins. Structural and Electronic Effects Induced by meso-Cyclohexyl Substitution in Metalloporphyrins
Marc Veyrat, René Ramasseul, Ilona Turowska-Tyrk, W. Robert Scheidt, Marie Autret, Karl M. Kadish, and Jean-Claude Marchon
pp 1772 - 1779; DOI:
10.1021/ic981233i
PDF
Estimation of Electron Transfer Rate Constant from Static (Optical and Thermodynamic) Measurements: A Study of Ru(NH3)5pz2+ + Fe(CN)63- Ru(NH3)5pz3+ + Fe(CN)64- Electron Transfer Reactions
F. Sánchez, P. Pérez-Tejeda, and M. López-López
pp 1780 - 1784; DOI:
10.1021/ic9807893
PDF
Difluoromethylcobalamin: Structural Aspects of an Old Tree with a New Branch
Trixie Wagner, Carol E. Afshar, H. L. Carrell, Jenny P. Glusker, Ulli Englert, and Harry P. C. Hogenkamp
pp 1785 - 1794; DOI:
10.1021/ic980751q
PDF
Structure of the Aqua Ions and Fluoride Complexes of Uranium(IV) and Thorium(IV) in Aqueous Solution an EXAFS Study
H. Moll, M. A. Denecke, F. Jalilehvand, M. Sandström, and I. Grenthe
pp 1795 - 1799; DOI:
10.1021/ic981362z
PDF
Substitution and Reduction of Platinum(IV) Complexes by a Nucleotide, Guanosine 5'-Monophosphate
Sunhee Choi, Shruthi Mahalingaiah, Sarah Delaney, Nathan R. Neale, and Syed Masood
pp 1800 - 1805; DOI:
10.1021/ic9809815
PDF
35Cl and 37Cl Magic-Angle Spinning NMR Spectroscopy in the Characterization of Inorganic Perchlorates
Jrgen Skibsted and Hans J. Jakobsen
pp 1806 - 1813; DOI:
10.1021/ic9811650
PDF
Thermally Activated Site Exchange and Quantum Exchange Coupling Processes in Unsymmetrical Trihydride Osmium Compounds
Amaya Castillo, Guada Barea, Miguel A. Esteruelas, Fernando J. Lahoz, Agustí LLedós, Feliu Maseras, Javier Modrego, Enrique Oñate, Luis A. Oro, Natividad Ruiz, and Eduardo Sola
pp 1814 - 1824; DOI:
10.1021/ic9804061
PDF
Tetracopper Assembly Complexes Comprised of One Dimetallic Core and Two Monometallic Auxiliaries: Intramolecular Electron-Transfer Relevant to Multicopper Oxidases
Sayaka Yamanaka, Hisashi kawa, Ken-ichiro Motoda, Masami Yonemura, David E. Fenton, Mehrdad Ebadi, and A. B. P. Lever
pp 1825 - 1830; DOI:
10.1021/ic981327s
PDF
Synthesis and X-ray Powder Structure of a New Pillared Layered Cadmium Phosphonate, Giving Evidence that the Intercalation of Alkylamines into Cd(O3PR)·H2O Is Topotactic
Florence Fredoueil, Dominique Massiot, Pascal Janvier, Franz Gingl, Martine Bujoli-Doeuff, Michel Evain, Abraham Clearfield, and Bruno Bujoli
pp 1831 - 1833; DOI:
10.1021/ic981248g
PDF
[Co4O4]4+ Cubane Core as a Brnsted Base: Preparation and Properties of [Co4O3(OH)(O2CR)2(bpy)2]3+ and [Co4O2(OH)2(O2CR)2(bpy)2]4+ Salts
Katerina Dimitrou, Angelica D. Brown, Kirsten Folting, and George Christou
pp 1834 - 1841; DOI:
10.1021/ic981237n
PDF
Electrochemical Detection of Single-Stranded DNA Using Polymer-Modified Electrodes
Allyn C. Ontko, Paul M. Armistead, Sandra R. Kircus, and H. Holden Thorp
pp 1842 - 1846; DOI:
10.1021/ic981211w
PDF
MCD C-Term Signs, Saturation Behavior, and Determination of Band Polarizations in Randomly Oriented Systems with Spin S 1/2. Applications to S = 1/2 and S = 5/2
Frank Neese and Edward I. Solomon
pp 1847 - 1865; DOI:
10.1021/ic981264d
PDF
Conformation Isomerism of Nonagermanide Ions. Crystal Structures of Brown and Red [K-([2.2.2]crypt)]6Ge9Ge9·(ethylenediamine)x (x = 0.5, 1.5)
Thomas F. Fässler and Uwe Schütz
pp 1866 - 1870; DOI:
10.1021/ic981157j
PDF
Synthesis, Structure, and Properties of Group 4 and 5 Metal Pyrazolato Chloride Complexes
Carlos Yélamos, Mary Jane Heeg, and Charles H. Winter
pp 1871 - 1878; DOI:
10.1021/ic981096p
PDF
X-ray Absorption Spectroscopy of Tricarbonatodioxouranate(V), [UO2(CO3)3]5-, in Aqueous Solution
T. I. Docrat, J. F. W. Mosselmans, J. M. Charnock, M. W. Whiteley, D. Collison, F. R. Livens, C. Jones, and M. J. Edmiston
pp 1879 - 1882; DOI:
10.1021/ic9814423
PDF
New Linear Coordination Polymers Based on Copper(I) and 4,7-Phenanthroline: Structure Dependence on Solvent and Counteranion
Susan Lopez and Steven W. Keller
pp 1883 - 1888; DOI:
10.1021/ic980800z
PDF
Synthesis and Structural Analysis of BaCrS2
Omar Fuentes, Chong Zheng, Catherine E. Check, Jianhua Zhang, and Gerardo Chacon
pp 1889 - 1893; DOI:
10.1021/ic980609p
PDF
Tuning of Spin Density Wave Strengths in Quasi-One-Dimensional Halogen-Bridged NiIII Complexes with Strong Electron Correlations, [NiIII(chxn)2X]Y2
Masahiro Yamashita, Toshio Manabe, Kazuo Inoue, Takuya Kawashima, Hiroshi Okamoto, Hiroshi Kitagawa, Tadaoki Mitani, Koshiro Toriumi, Hiroshi Miyamae, and Ryuichi Ikeda
pp 1894 - 1899; DOI:
10.1021/ic9812499
PDF
Alcohol and Aldehyde Adducts of Zinc Thiolates: Structural Modeling of Alcoholdehydrogenase
Bodo Müller, Astrid Schneider, Markus Tesmer, and Heinrich Vahrenkamp
pp 1900 - 1907; DOI:
10.1021/ic981227m
PDF
Computer-Aided Design (CAD) of Synzymes: Use of Molecular Mechanics (MM) for the Rational Design of Superoxide Dismutase Mimics
Dennis P. Riley, Susan L. Henke, Patrick J. Lennon, and Karl Aston
pp 1908 - 1917; DOI:
10.1021/ic981319b
PDF
Reactions of the Dirhenium(II) Complexes Re2X4(-dppm)2 (X = Cl, Br; dppm = Ph2PCH2PPh2) with Isocyanides. 18.1 The Isolation and Characterization of Isomers of the [Re2Cl2(-dppm)2(CO)(CNXyl)3]2+ Cation and Its Monocationic and Neutral Congeners
Yan Ding, Wengan Wu, Phillip E. Fanwick, and Richard A. Walton
pp 1918 - 1928; DOI:
10.1021/ic981192q
PDF
Iron Chemistry of a Pentadentate Ligand That Generates a Metastable FeIII-OOH Intermediate
Gerard Roelfes, Marcel Lubben, Kui Chen, Raymond Y. N. Ho, Auke Meetsma, Susan Genseberger, Roel M. Hermant, Ronald Hage, Sanjay K. Mandal, Victor G. Young, Jr., Yan Zang, Huub Kooijman, Anthony L. Spek, Lawrence Que, Jr., and Ben L. Feringa
pp 1929 - 1936; DOI:
10.1021/ic980983p
PDF
Barium Templating Schiff-Base Lateral Macrobicycles
David Esteban, Daniel Bañobre, Rufina Bastida, Andrés de Blas, Alejandro Macías, Adolfo Rodríguez, Teresa Rodríguez-Blas, David E. Fenton, Harry Adams, and José Mahía
pp 1937 - 1944; DOI:
10.1021/ic9811190
PDF
Sc5Ni2Te2: Synthesis, Structure, and Bonding of a Metal-Metal-Bonded Chain Phase, a Relative of Gd3MnI3
Paul A. Maggard and John D. Corbett
pp 1945 - 1950; DOI:
10.1021/ic981073a
PDF

Issue 9


Formation of a Five-Coordinate Hydroxide-Bound Heme in the His93Gly Mutant of Sperm Whale Myoglobin
Tapan Kanti Das, Stefan Franzen, Alycen Pond, John H. Dawson, and Denis L. Rousseau
pp 1952 - 1953; DOI:
10.1021/ic990049+
PDF
Electrochemical Reduction of Nitrogenous Ligands at a Conserved Dinuclear Metal-Sulfur Site: Cleavage of the N=N Bond of Phenyldiazene and Reduction of an Imide to NH3
François Y. Pétillon, Philippe Schollhammer, Jean Talarmin, and Kenneth W. Muir
pp 1954 - 1955; DOI:
10.1021/ic9813359
PDF
Synthesis, Structure, and Properties of Molybdenum and Tungsten Cyano Complexes with Cuboidal M4(3-E)4 (M = Mo, W; E = S, Se, Te) Cores
V. P. Fedin, I. V. Kalinina, D. G. Samsonenko, Y. V. Mironov, M. N. Sokolov, S. V. Tkachev, A. V. Virovets, N. V. Podberezskaya, M. R. J. Elsegood, W. Clegg, and A. G. Sykes
pp 1956 - 1965; DOI:
10.1021/ic980956z
PDF
Precursors to New Molecular Tube Ligands. 1. Double-Capped Trinuclear Cobalt Complexes of Aminoethanethiol
Alan P. Arnold, Rajumati Bhula, Xiangna Chen, Rodney J. Geue, and W. Gregory Jackson
pp 1966 - 1970; DOI:
10.1021/ic980691o
PDF
Chemistry of Diazaphospholephosphines. 1. Preparation of Substituted 4-(Phosphino)-2,5-dimethyl-2H-1,2,32-diazaphospholes, Bifunctional Phosphines with Dicoordinate and Tricoordinate Phosphorus(III) Centers. Chromium(0) and Molybdenum(0) Difluorophosphine Complexes
Michael D. Mikoluk and Ronald G. Cavell
pp 1971 - 1981; DOI:
10.1021/ic9802092
PDF
Mixed-Oxidation Divanadium(IV,V) Compound with Ligand Asymmetry: Electronic and Molecular Structure in Solution and in the Solid State
Subodh Kanti Dutta, Satyabrata Samanta, Sujit Baran Kumar, Oc Hee Han, Pannee Burckel, A. Alan Pinkerton, and Muktimoy Chaudhury
pp 1982 - 1988; DOI:
10.1021/ic980743+
PDF
Intramolecular Ligand Hydroxylation: Mechanistic High-Pressure Studies on the Reaction of a Dinuclear Copper(I) Complex with Dioxygen
Michael Becker, Siegfried Schindler, Kenneth D. Karlin, Thomas A. Kaden, Susan Kaderli, Tania Palanché, and Andreas D. Zuberbühler
pp 1989 - 1995; DOI:
10.1021/ic981066m
PDF
On the Calculation and Modeling of Magnetic Exchange Interactions in Weakly Bonded Systems: The Case of the Ferromagnetic Copper(II) 2-Azido Bridged Complexes
Carlo Adamo, Vincenzo Barone, Alessandro Bencini, Federico Totti, and Ilaria Ciofini
pp 1996 - 2004; DOI:
10.1021/ic9812306
PDF
Elucidation of the Wide Range of Reaction Pathways That Accompany the Electrochemical Oxidation of cis,mer-[Mn(CO)2(1-dpm)(2-dpm)X] (dpm = Ph2PCH2PPh2; X = Cl, Br)
John C. Eklund, Alan M. Bond, Ray Colton, David G. Humphrey, Peter J. Mahon, and Jacky N. Walter
pp 2005 - 2011; DOI:
10.1021/ic980796r
PDF
Synthesis, Structure, and Solution Studies of Cyclohexantriol Complexes of Europium(III)
Ch. Husson, P. Delangle, J. Pécaut, and Ph. J. A. Vottéro
pp 2012 - 2019; DOI:
10.1021/ic980924b
PDF
Ruthenium(II) -Diimine Complexes with One, Two, and Three 4,4'-Bis(hydroxymethyl)-2,2'-bipyridine and 4,4'-Bis(chloromethyl)-2,2'-bipyridine Ligands: Useful Starting Materials for Further Derivatization
James E. Collins, Jaydeep J. S. Lamba, J. Christopher Love, John E. McAlvin, Christina Ng, Benjamin P. Peters, Xufeng Wu, and Cassandra L. Fraser
pp 2020 - 2024; DOI:
10.1021/ic981102h
PDF
Coupling of Amino Carboranes to Carboxylic Acid Containing Substrates
Ye Wu and William Quintana
pp 2025 - 2029; DOI:
10.1021/ic981223h
PDF
pH-Dependent Excited-State Dynamics of [Ru(bpy)3]2+-Modified Amino Acids: Effects of an Amide Linkage and Remote Functional Groups
Bernd Geisser, Adrian Ponce, and Ralf Alsfasser
pp 2030 - 2037; DOI:
10.1021/ic980896x
PDF
A Cubane-Substituted Polyoxoanion: Structure and Magnetic Properties of Cs2[H2PW9Ni4O34(OH)3(H2O)6]·5H2O
Ulrich Kortz, André Tézé, and Gilbert Hervé
pp 2038 - 2042; DOI:
10.1021/ic981138+
PDF
Mixed-Valence, Disordered Structures and Characterization of Iodine-Doped Phthalocyanines: [YbPc2]I2 and [(AsPc)(Pc)]I2
Jan Janczak, Ryszard Kubiak, and Adam Jezierski
pp 2043 - 2049; DOI:
10.1021/ic981168c
PDF
Thermodynamic Calculations for Reactions Involving Hydrogen Halide Polymers, Ions, and Lewis Acid Adducts. 3. Systems Constituted from Al3+, H+, and Cl-
W. David Chandler and Keith E. Johnson
pp 2050 - 2056; DOI:
10.1021/ic980640r
PDF
Formation of Polymeric Network Arrays by Complexes of Manganese(II) or Cobalt(II) with Alkane Chain Linked Bis(amide) Ligands of Biological Relevance
David M. L. Goodgame, David A. Grachvogel, Izhar Hussain, Andrew J. P. White, and David J. Williams
pp 2057 - 2063; DOI:
10.1021/ic9812609
PDF
Palladium(II) Complexation by p-Cyclophane Receptors. A Solution and Solid State Study
Andrea Bencini, Antonio Bianchi, Vieri Fusi, Claudia Giorgi, Piero Paoletti, Jose' Antonio Ramirez, and Barbara Valtancoli
pp 2064 - 2070; DOI:
10.1021/ic9810891
PDF
Monoprotic Tetradentate N3O-Donor Ligands and Their Cu(II) and Ni(II) Complexes
Hongyan Luo, Jem-Mau Lo, Phillip E. Fanwick, Joseph G. Stowell, and Mark A. Green
pp 2071 - 2078; DOI:
10.1021/ic981324f
PDF
Synthesis of Some P-Trifluoromethyl-Substituted (Silylamino)phosphines, N-Silylphosphoranimines, and Phosphazenes
Sakthivel Karthikeyan and Robert H. Neilson
pp 2079 - 2084; DOI:
10.1021/ic980707a
PDF
Resonance Raman, X-ray Crystallographic, and Magnetic Susceptibility Studies of Metal-Metal-Bonded MoRu and WOs Porphyrin Dimers. 1. Evidence for an Unusual MO Diagram
James P. Collman, S. T. Harford, Stefan Franzen, Jean-Claude Marchon, Pascale Maldivi, Andrew P. Shreve, and William H. Woodruff
pp 2085 - 2092; DOI:
10.1021/ic981032e
PDF
Resonance Raman and X-ray Crystallographic Studies of Intertriad Metal-Metal Bonds. 2. WRu and MoOs Porphyrin Dimers
James P. Collman, S. T. Harford, Stefan Franzen, Andrew P. Shreve, and William H. Woodruff
pp 2093 - 2097; DOI:
10.1021/ic9810337
PDF
Microporous Montmorillonites Expanded with Alumina Clusters and M[(-OH)Cu(-OCH2CH2NEt2)]6(ClO4)3, (M = Al, Ga, and Fe), or Cr[(-OCH3)(-OCH2CH2NEt2)CuCl]3 Complexes
S. M. Thomas, J. A. Bertrand, M. L. Occelli, F. Huggins, and S. A. C. Gould
pp 2098 - 2105; DOI:
10.1021/ic981127g
PDF
Reactive Intermediates in Olefin Oxidations with Chromyl Chloride. IR-Spectroscopic Proof for O=CrCl2-Epoxide Complexes
Christian Limberg and Ralf Köppe
pp 2106 - 2116; DOI:
10.1021/ic981131s
PDF
Octanuclear Lanthanide Sulfido Clusters: Synthesis, Structure, and Coordination Chemistry
Jonathan H. Melman, Thomas J. Emge, and J. G. Brennan
pp 2117 - 2122; DOI:
10.1021/ic981122j
PDF
Synthesis of Metallacycles by Oxidative Addition of Sn-S, Sn-Se, Sn-Te, and Ge-Te Containing Precursors to Platinum(II)
Michael C. Janzen, Hilary A. Jenkins, Louis M. Rendina, Jagadese J. Vittal, and Richard J. Puddephatt
pp 2123 - 2130; DOI:
10.1021/ic980862p
PDF
X-ray Diffraction and 119Sn Mössbauer Spectroscopy Study of a New Phase in the Bi2Se3-SnSe System: SnBi4Se7
C. Pérez Vicente, J. L. Tirado, K. Adouby, J. C. Jumas, A. Abba Touré, and G. Kra
pp 2131 - 2135; DOI:
10.1021/ic9812858
PDF
The Enthalpy of Insertion of Sulfur into the Metal-Hydrogen Bond. Synthetic, Structural, and Calorimetric Study of the Complexes HS-M(CO)3C5R5 [M = Cr, Mo, W; R = H, Me]
Andreas Bauer, Kenneth B. Capps, Bodo Wixmerten, Khalil A. Abboud, and Carl D. Hoff
pp 2136 - 2142; DOI:
10.1021/ic981221x
PDF
Kinetic and Mechanistic Aspects of Sulfur Recovery from Pd2I2(-S)(-dpm)2 Using I2 and Structures of Pd(II) Complexes with the Chelated Monosulfide of dpm
Terrance Y. H. Wong, Steven J. Rettig, and Brian R. James
pp 2143 - 2149; DOI:
10.1021/ic981039w
PDF
Chloride Substitution Reactions of Cycloruthenated (R)C-(+)-N,N-Dimethyl(1-phenylethyl)amine with Pseudohalides: Ruthenium Atom Stereochemistry
Heather D. Hansen, Kalyani Maitra, and John H. Nelson
pp 2150 - 2156; DOI:
10.1021/ic981304d
PDF
Self-Assembled Porphyrin-C60 and Porphycene-C60 Complexes via Metal Axial Coordination
Francis D'Souza, Gollapalli R. Deviprasad, Muhammad S. Rahman, and Jai-pil Choi
pp 2157 - 2160; DOI:
10.1021/ic981358n
PDF
Experimental Studies of the Interconversion of -2:2-Peroxo- and Bis(-oxo)dicopper Complexes
John Cahoy, Patrick L. Holland, and William B. Tolman
pp 2161 - 2168; DOI:
10.1021/ic990095+
PDF
Cyclic Hydroborate Complexes of Metallocenes. IV. Weak Unsupported Single Hydrogen Bridges in Cp2Zr{(-H)B(X)CH2Ph}{(-H)2BX} (X = C5H10, C4H8)
Fu-Chen Liu, Jianping Liu, Edward A. Meyers, and Sheldon G. Shore
pp 2169 - 2173; DOI:
10.1021/ic981347u
PDF
Oxidation of Benzyl Alcohol by a Dioxo Complex of Ruthenium(VI)
Estelle L. Lebeau and Thomas J. Meyer
pp 2174 - 2181; DOI:
10.1021/ic981040v
PDF
Quadruply Bonded Dichromium Complexes with Variously Fluorinated Formamidinate Ligands
F. Albert Cotton, Carlos A. Murillo, and Isabel Pascual
pp 2182 - 2187; DOI:
10.1021/ic990007l
PDF
Synthesis and Electrochemical Studies of a Series of Fluorinated Dodecaphenylporphyrins
Karl M. Kadish, Eric Van Caemelbecke, Francis D'Souza, Min Lin, Daniel J. Nurco, Craig J. Medforth, Timothy P. Forsyth, Bénédicte Krattinger, Kevin M. Smith, Shunichi Fukuzumi, Ikuo Nakanishi, and John A. Shelnutt
pp 2188 - 2198; DOI:
10.1021/ic9811695
PDF
Spin-Spin Interactions in the Oxides A3M'MO6 (M = Rh, Ir; A = Ca, Sr; M' = Alkaline Earth, Zn, Cd, Na) of the K4CdCl6 Structure Type Examined by Electronic Structure Calculations
K.-S. Lee, H.-J. Koo, and M.-H. Whangbo
pp 2199 - 2203; DOI:
10.1021/ic9813819
PDF
Analysis of Bonding and d-Electron Count in the Transition-Metal Carbides and Transition-Metal-Silicide Carbides with Discrete Linear M-C-M Units (M = Cr, Fe, Re) by Electronic Structure Calculations
H.-J. Koo and M.-H. Whangbo
pp 2204 - 2210; DOI:
10.1021/ic981309a
PDF
Tris[(alkylthio)methyl]silanes: Syntheses and Structures of Chromium, Molybdenum, and Tungsten Complexes with a Tripodal Thioether Ligand
Hing W. Yim, Linh M. Tran, Ebern D. Dobbin, Daniel Rabinovich, Louise M. Liable-Sands, Christopher D. Incarvito, Kin-Chung Lam, and Arnold L. Rheingold
pp 2211 - 2215; DOI:
10.1021/ic981001j
PDF
Preparation and Structure of Two Ditungsten Compounds Synthesized with the 3,5-Dichlorophenylformamidinate Ligand
Kathryn M. Carlson-Day, Judith L. Eglin, Laura T. Smith, and Richard J. Staples
pp 2216 - 2220; DOI:
10.1021/ic9810642
PDF
Identification and Structure of W2(-OH)2[(p-MeC6H4N)2CH]4
F. Albert Cotton, Lee M. Daniels, and Tong Ren
pp 2221 - 2222; DOI:
10.1021/ic981065u
PDF
Solids with Rhombic Channels: Syntheses and Crystal Structures of [Cu3(NTA)2(4,4'-bpy)2(H2O)2]·9H2O and [{Cu(4,4'-bpy)(H2O)4}{Cu2(NTA)2(4,4'-bpy)}]· 7H2O (NTA = Nitrilotriacetate, 4,4'-bpy = 4,4'-Bipyridine)
Quanming Wang, Xintao Wu, Wenjian Zhang, Tianlu Sheng, Ping Lin, and Jianmin Li
pp 2223 - 2226; DOI:
10.1021/ic9802799
PDF
Molecular Aggregates of Nitrate Ion with the Tetravalent Lewis Acid Host 12-Mercuracarborand-4: Novel Trihapto Coordination of NO3-
Alfred A. Zinn, Carolyn B. Knobler, David E. Harwell, and M. Frederick Hawthorne
pp 2227 - 2230; DOI:
10.1021/ic9811244
PDF
Synthesis and Characterization of a Borophosphate Anion Containing a Single Vanadium Atom: [N2C6H14]2VO(PO3OH)4(B3O3OH)·4H2O
Ranko P. Bontchev, Junghwan Do, and Allan J. Jacobson
pp 2231 - 2233; DOI:
10.1021/ic981278j
PDF
Two-Dimensional Assembling of (2,2'-Bipyrimidine)bis(oxalato)chromate(III) Units through Alkaline Cations
Giovanni De Munno, Donatella Armentano, Miguel Julve, Francesc Lloret, Rodrigue Lescouëzec, and Juan Faus
pp 2234 - 2237; DOI:
10.1021/ic981232q
PDF
Gas Phase Photoproduction of Diatomic Metal Nitrides During Metal Nitride Laser Chemical Vapor Deposition
Jinwoo Cheon, Matthew Guile, Peter Muraoka, and Jeffrey I. Zink
pp 2238 - 2239; DOI:
10.1021/ic981365b
PDF
An Improved Interpretation of a Lead Oxo Isopropoxide
Daniel J. Teff and Kenneth G. Caulton
pp 2240 - 2240; DOI:
10.1021/ic9811805
PDF

Issue 10


The First Crystal Structure of a Metal-Stabilized Tetrazine Anion Radical: Formation of a Dicopper Complex through Self-Assembly in a Comproportionation Reaction
Manuela Schwach, Hans-Dieter Hausen, and Wolfgang Kaim
pp 2242 - 2243; DOI:
10.1021/ic9814625
PDF
Dioxygen Reactivity of Fully Reduced [LFeII···CuI]+ Complexes Utilizing Tethered Tetraarylporphyrinates: Active Site Models for Heme-Copper Oxidases
Telvin D. Ju, Reza A. Ghiladi, Dong-Heon Lee, Gino P. F. van Strijdonck, Amina S. Woods, Robert J. Cotter, Victor G. Young Jr., and Kenneth D. Karlin
pp 2244 - 2245; DOI:
10.1021/ic9900511
PDF
Neocuproine-Extended Porphyrin Coordination Complexes
Tommaso A. Vannelli and Timothy B. Karpishin
pp 2246 - 2247; DOI:
10.1021/ic9812914
PDF
Iminophosphine Cycloaddition Reactions of a Diazaphosphoniaaluminatacyclobutane and a Novel Intramolecular Phosphiridine PP Coordination
Neil Burford and Daren J. LeBlanc
pp 2248 - 2249; DOI:
10.1021/ic9813718
PDF
Synthesis, Structure, Photophysical Properties, and Redox Behavior of Cyclometalated Complexes of Iridium(III) with Functionalized 2,2'-Bipyridines
Francesco Neve, Alessandra Crispini, Sebastiano Campagna, and Scolastica Serroni
pp 2250 - 2258; DOI:
10.1021/ic981308i
PDF
Solvent Control in the Synthesis of 3,6-Bis(pyridin-3-yl)-1,2,4,5-tetrazine-Bridged Cadmium(II) and Zinc(II) Coordination Polymers
Matthew A. Withersby, Alexander J. Blake, Neil R. Champness, Paul A. Cooke, Peter Hubberstey, Wan-Sheung Li, and Martin Schröder
pp 2259 - 2266; DOI:
10.1021/ic980898h
PDF
Preparation of Coordinatively Asymmetrical Ruthenium(II) Polypyridine Complexes
Joseph A. Treadway and Thomas J. Meyer
pp 2267 - 2278; DOI:
10.1021/ic981188e
PDF
- Stacking-Induced Cooperativity in Copper(I) Complexes with Phenanthroline Ligands
Michel Meyer, Anne-Marie Albrecht-Gary, Christiane O. Dietrich-Buchecker, and Jean-Pierre Sauvage
pp 2279 - 2287; DOI:
10.1021/ic981259+
PDF
Vanadium Complexes as Insulin Mimetic Agents: Coordination Chemistry and in Vivo Studies of Oxovanadium(IV) and Dioxovanadate(V) Complexes Formed from Naturally Occurring Chelating Oxazolinate, Thiazolinate, or Picolinate Units
Marco Melchior, Katherine H. Thompson, Janet M. Jong, Steven J. Rettig, Ed Shuter, Violet G. Yuen, Ying Zhou, John H. McNeill, and Chris Orvig
pp 2288 - 2293; DOI:
10.1021/ic981231y
PDF
The 195Pt NMR of L2Pt(1,2-dithiolene) Complexes
Christopher E. Keefer, Robert D. Bereman, Suzanne T. Purrington, Brian W. Knight, and Paul D. Boyle
pp 2294 - 2302; DOI:
10.1021/ic980369d
PDF
Highly Efficient Triplet-Triplet Intramolecular Energy Transfer and Enhanced Intersystem Crossing in Rigidly Linked Copper(II) Porphyrin-Free Base Porphyrin Hybrid Dimers
Motoko Asano-Someda and Youkoh Kaizu
pp 2303 - 2311; DOI:
10.1021/ic981009t
PDF
Coordination of N-Donor Ligands by the Monomeric Ferric Porphyrin N-Acetylmicroperoxidase-8
Helder M. Marques, Orde Q. Munro, Tracey Munro, Marina de Wet, and Preeti R. Vashi
pp 2312 - 2319; DOI:
10.1021/ic981293o
PDF
Structural, Magnetic, and Electronic Properties of a Pentacoordinated Intermediate-Spin (S = 3/2) Iron(III) Complex with a Macrocyclic [N4]2- Ligand
H. Keutel, I. Käpplinger, E.-G. Jäger, M. Grodzicki, V. Schünemann, and A. X. Trautwein
pp 2320 - 2327; DOI:
10.1021/ic981276z
PDF
Synthesis, Structure, and Magnetic Properties of a New Chloro-Bridged Dimer [Cu2(dpt)2Cl2]Cl2 with an Unusual Structure and Ferromagnetic Coupling
Montserrat Rodríguez, Antoni Llobet, Montserrat Corbella, Arthur E. Martell, and Joseph Reibenspies
pp 2328 - 2334; DOI:
10.1021/ic9808504
PDF
Synthesis and Structural Characterizations of New Mononuclear and Dinuclear Molybdenum(V) Anions Containing Trithiocarbonate Ligands
C. Simonnet-Jégat, E. Cadusseau, R. Dessapt, and F. Sécheresse
pp 2335 - 2339; DOI:
10.1021/ic980907m
PDF
Lewis Acid Behavior of ReO2F3: Synthesis of (ReO2F3), ReO2F4-, Re2O4F7-, Re3O6F10-, and ReO2F3(CH3CN) and Study by NMR Spectroscopy, Raman Spectroscopy, and Density Functional Theory Calculations; and X-ray Structures of [Li][ReO2F4], [K][Re2O4F7], [K][Re2O4F7]·2ReO2F3, [Cs][Re3O6F10], and ReO3F(CH3CN)2·CH3CN
William J. Casteel, Jr., David A. Dixon, Nicolas LeBlond, Philippa E. Lock, Hélène P. A. Mercier, and Gary J. Schrobilgen
pp 2340 - 2358; DOI:
10.1021/ic980695t
PDF
Fusing Rigid Spin Probes to Paramagnetic Sandwiches. Synthesis, Crystal Structures, and NMR Spectroscopy of Bis(isodicyclopentadienyl)metal Compounds
Irene Gattinger, Martin A. Herker, Wolfgang Hiller, and Frank H. Köhler
pp 2359 - 2368; DOI:
10.1021/ic9812407
PDF
[H2NMe2]CuZrCl6: Hydrogen-Bond Induced Distortions in a Copper Zirconium Chloride Analogue of a Thiophosphate
Andrew M. Dattelbaum and James D. Martin
pp 2369 - 2374; DOI:
10.1021/ic9811906
PDF
A Novel Molybdenum-Iron-Sulfur Cluster. Synthesis, Structure, and Properties of [Et4N]2[MoFe4S4(SC6H11)71/2CH3CN
Changneng Chen, Tingbin Wen, Wenjie Li, Hongpin Zhu, Yihui Chen, Qiutian Liu, and Jiaxi Lu
pp 2375 - 2379; DOI:
10.1021/ic971474a
PDF
Single Crystal EPR Studies of [enH2][{Fe(HEDTA)}2O]·6H2O [en = Ethylenediamine; HEDTA = N-Hydroxyethylethylenediaminetriacetate(3-)]
Stephen J. W. Holgate, Gennadij Bondarenko, David Collison, and Frank E. Mabbs
pp 2380 - 2385; DOI:
10.1021/ic981317r
PDF
Hydrolytic Dealkylation of Organocobaloximes Related to Coenzyme B12: Ligand Influences
Michael P. Jensen, Diana M. Zinkl, and Jack Halpern
pp 2386 - 2393; DOI:
10.1021/ic990058i
PDF
Polysulfide Anions. 1. Structure and Vibrational Spectra of the S22- and S32- Anions. Influence of the Cations on Bond Length and Angle
Omar El Jaroudi, Eric Picquenard, Antoine Demortier, Jean-Pierre Lelieur, and Jacques Corset
pp 2394 - 2401; DOI:
10.1021/ic9811143
PDF
Photophysics of Dinuclear Ru(II) and Os(II) Complexes Based on the Tetrapyrido[3,2-a:2',3'-c:3' ',2' '-h:2' ''-3' ''-j]phenazine (tpphz) Bridging Ligand
Claudio Chiorboli, Carlo Alberto Bignozzi, Franco Scandola, Eléna Ishow, André Gourdon, and Jean-Pierre Launay
pp 2402 - 2410; DOI:
10.1021/ic981284f
PDF
Synthesis and Excited-State Properties of a Novel Ruthenium Nucleoside: 5-[Ru(bpy)2(4-m-4'-pa-bpy)]2+-2'-deoxyuridine
Shoeb I. Khan, Amy E. Beilstein, Gregory D. Smith, Milan Sykora, and Mark W. Grinstaff
pp 2411 - 2415; DOI:
10.1021/ic990067r
PDF
First Row Transition Metal Complexes of 1-Methylcyclobutenedione, a Monosubstituted Squarate Ligand
Bert D. Alleyne, Hazel-Ann Hosein, Hema Jaggernauth, Lincoln A. Hall, Andrew J. P. White, and David J. Williams
pp 2416 - 2421; DOI:
10.1021/ic981011k
PDF
Syntheses, Characterizations, and X-ray Structures of Alkali Metal Derivatives of Titanium(IV) Neopentoxides
Timothy J. Boyle, Todd M. Alam, Cory J. Tafoya, Eric R. Mechenbier, and Joseph W. Ziller
pp 2422 - 2428; DOI:
10.1021/ic981143d
PDF
Synthesis, Structure, and Characterization of Oxomolybdenum(V) Phthalocyaninato(2-) Triiodide
Jan Janczak and Ryszard Kubiak
pp 2429 - 2433; DOI:
10.1021/ic9900410
PDF
Mono- and Dinuclear Ruthenium(II) Complexes of 2,6-Di(pyrazol-3-yl)pyridines: Deprotonation, Functionalization, and Supramolecular Association
Jerzy Zadykowicz and Pierre G. Potvin
pp 2434 - 2441; DOI:
10.1021/ic980817h
PDF
A Powder Neutron Diffraction Study of Lithium-Substituted Gallosilicate and Aluminogermanate Halide Sodalites
Geoffrey M. Johnson and Mark T. Weller
pp 2442 - 2450; DOI:
10.1021/ic9812510
PDF
(CuI)3P4Se4: -P4Se4 Cages between Columns of Copper Iodide
A. Pfitzner and Sara Reiser
pp 2451 - 2454; DOI:
10.1021/ic981042f
PDF
Reactivity of Palladium(II) Complexes Containing the Orthometalated C,C-Chelating Ligand C6H4-2-PPh2C(H)COCH2PPh3 toward Deprotonating Reagents
Larry R. Falvello, Susana Fernández, Rafael Navarro, and Esteban P. Urriolabeitia
pp 2455 - 2463; DOI:
10.1021/ic9812050
PDF
Electrochemical and Photophysical Properties of a Series of Group-14 Metalloles
Justin Ferman, Joseph P. Kakareka, Wim T. Klooster, Jerome L. Mullin, Joseph Quattrucci, John S. Ricci, Henry J. Tracy, William J. Vining, and Scott Wallace
pp 2464 - 2472; DOI:
10.1021/ic980662d
PDF
Water-Soluble Organometallic Compounds. 7.1 Further Studies of 1,3,5-Triaza-7-Phosphaadamantane Derivatives of Group 10 Metals, Including Metal Carbonyls and Hydrides
Donald J. Darensbourg, Jeffrey B. Robertson, David L. Larkins, and Joseph H. Reibenspies
pp 2473 - 2481; DOI:
10.1021/ic981243j
PDF
Encapsulation of Thallium(I) by Tetranuclear Rhodium or Iridium Complexes: Synthesis and Molecular Structure of Heterobimetallic Complexes Stabilized by s2-d8 Bonding Interactions
Miguel A. Casado, Jesús J. Pérez-Torrente, José A. López, Miguel A. Ciriano, Fernando J. Lahoz, and Luis A. Oro
pp 2482 - 2488; DOI:
10.1021/ic980988m
PDF
Synthesis and Structures of Tungsten (1-Pyridinio)imido Complexes and Their Facile N-N Bond Cleavage
Hiroshige Ishino, Shin'ichi Tokunaga, Hidetake Seino, Youichi Ishii, and Masanobu Hidai
pp 2489 - 2496; DOI:
10.1021/ic981116n
PDF
Driving Force and Isotope Dependence of the Kinetics of Proton-Coupled Electron Transfer in Oxoruthenium(IV) Polypyridyl Complexes
Brian T. Farrer and H. Holden Thorp
pp 2497 - 2502; DOI:
10.1021/ic9902323
PDF
Room Temperature Syntheses of AuF6- and PtF6- Salts, Ag+AuF6-, Ag2+PtF62-, and Ag2+PdF62-, and an Estimate for E(MF6-) [M = Pt, Pd]
O. Graudejus, S. H. Elder, G. M. Lucier, C. Shen, and N. Bartlett
pp 2503 - 2509; DOI:
10.1021/ic981397z
PDF
Atropisomerization in cis-[Pd(2-C6BrF4)2L2] (L = Thioether): A Dual Mechanism Involving Ligand-Dissociative and Nondissociative Competitive Pathways
Ana C. Albéniz, Arturo L. Casado, and Pablo Espinet
pp 2510 - 2515; DOI:
10.1021/ic980978l
PDF
Spectroscopic and Photophysical Properties of Complexes of 4'-Ferrocenyl-2,2':6',2' '-terpyridine and Related Ligands
Kimberly Hutchison, James C. Morris, Terence A. Nile, Jerry L. Walsh, David W. Thompson, John D. Petersen, and Jon R. Schoonover
pp 2516 - 2523; DOI:
10.1021/ic980798b
PDF
Ph2PCl3: Covalency in Solution and the Solid State
Stephen A. Bell, Steven J. Geib, and Tara Y. Meyer
pp 2524 - 2526; DOI:
10.1021/ic980994i
PDF
Porphyrin "Flying-Saucers": Solid State and Solution Structure of a Novel Pentameric Array of Axially-Ligated Canted Porphyrins
Enzo Alessio, Silvano Geremia, Stefano Mestroni, Ivana Srnova, Miroslav Slouf, Teresa Gianferrara, and Anna Prodi
pp 2527 - 2529; DOI:
10.1021/ic990084g
PDF
[CuCN·Me3SnCN·C4H4N2]: A Threefold- Interpenetrating, Distorted-Diamondoid Framework (C4H4N2 = Pyrazine)
Eric Siebel, Amany M. A. Ibrahim, and R. Dieter Fischer
pp 2530 - 2532; DOI:
10.1021/ic9808549
PDF
Activation of Molecular Oxygen in Systems Containing Methyltrioxorhenium and Its Derivatives
Matthew D. Eager and James H. Espenson
pp 2533 - 2535; DOI:
10.1021/ic981388q
PDF
Synthesis and Solvent-Dependent Properties of Ru(acac)2dppz
Rajesh B. Nair, Lee K. Yeung, and Catherine J. Murphy
pp 2536 - 2538; DOI:
10.1021/ic981322v
PDF
X-ray Absorption Spectroscopy of Chicken Sulfite Oxidase Crystals
Graham N. George, Ingrid J. Pickering, and Caroline Kisker
pp 2539 - 2540; DOI:
10.1021/ic981451b
PDF
Formation and Crystal Structure of a Polymeric La(H2salen) Complex
Wenhua Xie, Mary Jane Heeg, and Peng George Wang
pp 2541 - 2543; DOI:
10.1021/ic9810539
PDF
Stepwise Cluster Assembly Using VO2(acac) as a Precursor: cis-[VO(OCH(CH3)2)(acac)2], [V2O2(-OCH3)2(acac)2(OCH3)2], [V3O3{,-(OCH2)3CCH3}2(acac)2(OC2H5)], and [V4O4(-O)2(-OCH3)2(3-OCH3)2(acac)2(OCH3)2]· 2CH3CN
Feilong Jiang, Oren P. Anderson, Susie M. Miller, John Chen, Mohammad Mahroof-Tahir, and Debbie C.Crans
pp 2544 - 2544; DOI:
10.1021/ic990148n
PDF

Issue 11


Distortional Isomers of a Mixed-Valence Binuclear Cu Complex
Vincent M. Miskowski, Stefan Franzen, Andrew P. Shreve, Mark R. Ondrias, Stacie E. Wallace-Williams, Mary E. Barr, and William H. Woodruff
pp 2546 - 2547; DOI:
10.1021/ic981415c
PDF
A Homoleptic Copper(II)-Thiocyanato Linear Chain
Christopher A. White, Glenn P. A. Yap, N. P. Raju, J. E. Greedan, and Robert J. Crutchley
pp 2548 - 2549; DOI:
10.1021/ic990083o
PDF
Solvent-Assisted Reversible Proton Transfer within an Intermolecular Dihydrogen Bond and Characterization of an Unstable Dihydrogen Complex
Stephan Gründemann, Stefan Ulrich, Hans-Heinrich Limbach, Nikolai S. Golubev, Gleb S. Denisov, Lina M. Epstein, Sylviane Sabo-Etienne, and Bruno Chaudret
pp 2550 - 2551; DOI:
10.1021/ic981320a
PDF
Spontaneous Magnetization in the M[N(CN)2]2 (M = Cr, Mn) Weak Ferromagnets
Jamie L. Manson, Carmen R. Kmety, Arthur J. Epstein, and Joel S. Miller
pp 2552 - 2553; DOI:
10.1021/ic9901259
PDF
Cooperative Bimetallic Redox Reactivity
B. Bosnich
pp 2554 - 2562; DOI:
10.1021/ic990164k
PDF
Neutron Powder Diffraction Study of Ti2(OH)2OSiO4·1.5H2O
Pilar Pertierra, Miguel A. Salvado, Santiago Garcia-Granda, Anatoly I. Bortun, and Abraham Clearfield
pp 2563 - 2566; DOI:
10.1021/ic980984h
PDF
Inter- and Intramolecular Hydrogen-Bonding Interaction of Hydroxo Groups and Steric Effect of Alkyl Substituents on Pyrazolyl Rings in TpR Ligands: Synthesis and Structural Characterization of Chloro-, Acetylacetonato-, and Hydroxo Complexes of VO2+ with TpPri2 and TpMe2 Ligands
Masahiro Kosugi, Shiro Hikichi, Munetaka Akita, and Yoshihiko Moro-oka
pp 2567 - 2578; DOI:
10.1021/ic9806028
PDF
Oxygenation Catalysis by All-Inorganic, Oxidation-Resistant, Dawson-Type Polyoxoanion-Supported Transition Metal Precatalysts, [(CH3CN)xM]n+ Plus P2W15Nb3O629- (M = MnII, FeII, CoII, NiII, CuI, CuII, ZnII)
Heiko Weiner, Yoshihito Hayashi, and Richard G. Finke
pp 2579 - 2591; DOI:
10.1021/ic990078k
PDF
Molybdenum-Pterin Chemistry. 1. The Five-Electron Oxidation of an Oxo Molybdenum Dithiolate Complex of a Reduced Pterin
Heather Layton Kaufmann, Louise Liable-Sands, Arnold L. Rheingold, and Sharon J. Nieter Burgmayer
pp 2592 - 2599; DOI:
10.1021/ic980881z
PDF
Molybdenum-Pterin Chemistry. 2. Reinvestigation of Molybdenum(IV) Coordination by Flavin Gives Evidence for Partial Pteridine Reduction
Heather Layton Kaufmann, Patrick J. Carroll, and Sharon J. Nieter Burgmayer
pp 2600 - 2606; DOI:
10.1021/ic9808798
PDF
Molybdenum-Pterin Chemistry. 3. Use of X-ray Photoelectron Spectroscopy To Assign Oxidation States in Metal Complexes of Noninnocent Ligands
Sharon J. Nieter Burgmayer, Heather Layton Kaufmann, Giuseppino Fortunato, Paul Hug, and Berthold Fischer
pp 2607 - 2613; DOI:
10.1021/ic9808807
PDF
InCrBr3: A Ternary Indium Bromide Containing Jahn-Teller Unstable Cr2+ and the Magnetic Structures of InCrBr3 and InFeBr3
Michael Scholten, Richard Dronskowski, and Herbert Jacobs
pp 2614 - 2620; DOI:
10.1021/ic981383t
PDF
The Preparation and Phase Transformation of Nanocrystalline Cobalt Sulfides via a Toluene Thermal Process
X. F. Qian, X. M. Zhang, C. Wang, Y. Xie, and Y. T. Qian
pp 2621 - 2623; DOI:
10.1021/ic980177i
PDF
Thermodynamic and Kinetic Study of Oxidative Addition/Reductive Elimination of H2 and D2 to FulvaleneCr2(CO)6: Evidence for Relatively Strong Metal-Metal Bonds in Fulvalenedimetals
K. Peter C. Vollhardt, J. Kevin Cammack, Adam J. Matzger, Andreas Bauer, Kenneth B. Capps, and Carl D. Hoff
pp 2624 - 2631; DOI:
10.1021/ic981360e
PDF
Sn(III) and Ge(III) in the Thiophenolato-Bridged Complexes [LFeSnFeL]n+ and [LFeGeFeL]n+ (n = 2, 3; L = 1,4,7-(4-tert-Butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane)
Thorsten Glaser, Eckhard Bill, Thomas Weyhermüller, Wolfram Meyer-Klaucke, and Karl Wieghardt
pp 2632 - 2642; DOI:
10.1021/ic9902018
PDF
Spectroscopic Determination of Magnetic Exchange Parameters and Structural Geometry for Trinuclear Compounds: (CuL)2Mn·xB (L = N-(4-Methyl-6-oxo-3-azahept-4-enyl)oxamato and B = (CH3)2SO (x = 2) or H2O (x = 5))
Olivier Cador, Corine Mathonière, Olivier Kahn, Jean-Pierre Costes, Marc Verelst, and Pierre Lecante
pp 2643 - 2648; DOI:
10.1021/ic981147i
PDF
Mixed Chloride/Amine Complexes of Dimolybdenum(II,II). 3. Preparation, Characterization, and Crystal Structure of Mo2Cl4(NH2R)4 (R = Et, Prn, But, Cy): First Quadruply-Bonded Dimolybdenum Compounds with Primary Amine Ligands
F. Albert Cotton, Evgeny V. Dikarev, and Santiago Herrero
pp 2649 - 2654; DOI:
10.1021/ic981289c
PDF
Further Study of the Linear Trinickel(II) Complex of Dipyridylamide
Rodolphe Clérac, F. Albert Cotton, Kim R. Dunbar, Carlos A. Murillo, Isabel Pascual, and Xiaoping Wang
pp 2655 - 2657; DOI:
10.1021/ic990006t
PDF
Ni-Fe Hydrogenases: A Density Functional Theory Study of Active Site Models
L. De Gioia, P. Fantucci, B. Guigliarelli, and P. Bertrand
pp 2658 - 2662; DOI:
10.1021/ic9811446
PDF
Solid State Coordination Chemistry of the Copper Halide- and Pseudo-Halide-Organoamine System, Cu-X-[(bis-2,3-(2-pyridyl)pyrazine)] (X = Cl, Br, CN): Hydrothermal Synthesis and Structural Characterization
Douglas J. Chesnut, Anakarin Kusnetzow, Robert R. Birge, and Jon Zubieta
pp 2663 - 2671; DOI:
10.1021/ic990132x
PDF
Cs7In4Bi6: A Zintl Phase Tailored from the PbO-Type Layers of the Parent InBi Compound
Svilen Bobev and Slavi C. Sevov
pp 2672 - 2675; DOI:
10.1021/ic990113n
PDF
N-Confused Tetraphenylporphyrin-Silver(III) Complex
Hiroyuki Furuta, Takuji Ogawa, Yoshiya Uwatoko, and Koiti Araki
pp 2676 - 2682; DOI:
10.1021/ic9901416
PDF
Interaction of Cr(diimine)33+ Complexes with DNA
Rhett T. Watson, Nehal Desai, Justin Wildsmith, John F. Wheeler, and Noel A. P. Kane-Maguire
pp 2683 - 2687; DOI:
10.1021/ic980857l
PDF
Heteropolymetalate Clusters of the Subvalent Main Group Elements BiIII and SbIII
Ina Loose, Elisabeth Droste, Michael Bösing, Heinrich Pohlmann, Michael H. Dickman, Cristina Rosu, Michael T. Pope, and Bernt Krebs
pp 2688 - 2694; DOI:
10.1021/ic981313m
PDF
A New Type of Two-Dimensional Metal Coordination Systems: Hydrothermal Synthesis and Properties of the First Oxalate-bpy Mixed-Ligand Framework %@mt;sys@% %@sx@%%@be@%2%@sxx@%%@mx@% [M(ox)(bpy)] (M = Fe(II), Co(II), Ni(II), Zn(II); ox = C2O42-; bpy = 4,4'-bipyridine)
Jack Y. Lu, Michael A. Lawandy, Jing Li, Tan Yuen, and C. L. Lin
pp 2695 - 2704; DOI:
10.1021/ic990243w
PDF
Multiphoton, Multielectron Transfer Photochemistry in a Soluble Polymer
Laura A. Worl, Wayne E. Jones, Jr., Geoffrey F. Strouse, Janet N. Younathan, Earl Danielson, Kimberly A. Maxwell, Milan Sykora, and Thomas J. Meyer
pp 2705 - 2708; DOI:
10.1021/ic981420g
PDF
Synthesis and Thermal Decomposition Studies of New Nitroso- and Nitrodicyanomethanide Salts
Navamoney Arulsamy, D. Scott Bohle, and Blaine G. Doletski
pp 2709 - 2715; DOI:
10.1021/ic9814064
PDF
Synthesis and Characterization of Alkylammonium Hyponitrites and Base-Stabilized Hyponitrous Acid Salts
Navamoney Arulsamy, D. Scott Bohle, Jerome A. Imonigie, and Elizabeth S. Sagan
pp 2716 - 2725; DOI:
10.1021/ic981340c
PDF
Solution Chemistry of Cyclotrigallazane: Supercritical Ammonia and Lewis Base Catalyzed Dehydrogenation To Produce Poly(imidogallane)
Jolin A. Jegier, Stuart McKernan, and Wayne L. Gladfelter
pp 2726 - 2733; DOI:
10.1021/ic981298l
PDF
Structural Effects on Molecular Dipoles and Solvatochromism of Nickel(diimine)(dithiolate) Complexes
Chin-Ti Chen, Sish-Yuan Liao, Kuan-Jiuh Lin, Chiung-Hsueh Chen, and Tzu-Yao Jeremy Lin
pp 2734 - 2741; DOI:
10.1021/ic981125w
PDF
Electronic Absorption and MCD Spectra for BiX63-, X = Cl-, Br-, and I-, in Acetonitrile Solution: Metal-Centered vs Ligand-to-Metal Charge-Transfer Assignments
W. Roy Mason
pp 2742 - 2745; DOI:
10.1021/ic9813415
PDF
First Cr(II) Complex with a Tetrahedral M4(4-O) Core: [M4(4-O)(-Cl)6(THF)4]
F. Albert Cotton, Carlos A. Murillo, and Isabel Pascual
pp 2746 - 2749; DOI:
10.1021/ic9814468
PDF
Radical Double Helicates of Silver Imino Nitroxides, [Ag2(pyrd-im2)2](PF6)2·2CH3OH and [Ag2(bpy-im2)2](PF6)2·CH3OH
Hiroki Oshio, Taira Yaginuma, and Tasuku Ito
pp 2750 - 2752; DOI:
10.1021/ic9813563
PDF
First Experimental Structure of a 1:1 Metal Complex with a PQQ Cofactor Derivative outside Dehydrogenase Enzymes
Matthias Wanner, Torsten Sixt, Karl-Wilhelm Klinkhammer, and Wolfgang Kaim
pp 2753 - 2755; DOI:
10.1021/ic981390h
PDF
Mechanism of CO2 and H+ Reduction by Ni(cyclam)+ in Aqueous Solution. A Pulse and Continuous Radiolysis Study
Craig A. Kelly, Elliott L. Blinn, Nadia Camaioni, Mila D'Angelantonio, and Quinto G. Mulazzani
pp 2756 - 2756; DOI:
10.1021/ic990341h
PDF
Synthesis, Magnetic Properties, and Incomplete Double-Cubane Structure of Manganese(III)-Metal(II) Complexes [Mn(MeOH)L(OH)M(bpy)]2 (M = Zn, Cu, Ni, and Mn; H4L = 1,2-Bis(2-hydroxybenzamido)benzene; bpy = 2,2'-Bipyridine)
Yukinari Sunatsuki, Hiromitsu Shimada, ToshihiroMatsuo, Masaaki Nakamura, Fumiaki Kai, NaohideMatsumoto, and Nazzareno Re
pp 2756 - 2756; DOI:
10.1021/ic990361j
PDF

Issue 12


Small Molecule-Induced Intramolecular Electron "Pitch and Catch" in a RhodiumI Complex with Substitutionally Inert Redox-Active Ligands
Igor V. Kourkine, Caroline S. Slone, Chad A. Mirkin, Louise M. Liable-Sands, and Arnold L. Rheingold
pp 2758 - 2759; DOI:
10.1021/ic990193v
PDF
Hydrogen Transfer Reactivity of a Ferric Bi-imidazoline Complex That Models the Activity of Lipoxygenase Enzymes
Justine P. Roth and James M. Mayer
pp 2760 - 2761; DOI:
10.1021/ic990251c
PDF
The First Observation and Full Characterization of All Atropisomers and Their Allowed Interconversions in an Octahedral Bis(bipyridine)ruthenium(II) Complex with Two Lopsided Bicyclic Ligands, as Studied by 2D NMR Techniques at Variable Temperature
Aldrik H. Velders, Anna C. G. Hotze, Jaap G. Haasnoot, and Jan Reedijk
pp 2762 - 2763; DOI:
10.1021/ic990053l
PDF
Why Are Copper(II) Amino Acid Complexes Not Planar in Their Crystal Structures? An ab Initio and Molecular Mechanics Study
Jasmina Sabolovi and Klaus R. Liedl
pp 2764 - 2774; DOI:
10.1021/ic980471a
PDF
A Series of the Twelve-Vertex Ferratricarbollides [2-(5-C5H5)-9-X-closo-2,1,7,9-FeC3B8H10] (Where X = H2N, MeHN, Me2N, ButHN, But(Me)N). A Highly Stable Metallatricarbaborane System with Amine Functions in the Para Position to the Metal Center
Josef Holub, Bohumír Grüner, Ivana Císaová, Jií Fusek, Zbynk Plzák, Francesc Teixidor, Clara Viñas, and Bohumil tíbr
pp 2775 - 2780; DOI:
10.1021/ic981400e
PDF
Ligand-Based Redox Isomers of [ZnII(C28H40NO2)2]: Molecular and Electronic Structures of a Diamagnetic Green and a Paramagnetic Red Form
Phalguni Chaudhuri, Martina Hess, Knut Hildenbrand, Eckhard Bill, Thomas Weyhermüller, and Karl Wieghardt
pp 2781 - 2790; DOI:
10.1021/ic990003g
PDF
Chemistry of Diazaphospholephosphines. 2. Exocyclic Phosphine-Sulfido, -Selenido, and -Imido Derivatives of a Diazaphospholephosphine System. Crystal and Molecular Structures of Two Diazaphospholephosphine Imines: 4-(Difluoro((p-cyanotetrafluorophenyl)imino)phosphorano)-2,5-dimethyl-2H-1,2,32-diazaphosphole and 4-(Bis(dimethylamino)(((pentamethylcyclopentadienyl)dichlorotitanio)imino)phosphorano)-2,5-dimethyl-2H-1,2,32-diazaphosphole
Michael D. Mikoluk, Robert McDonald, and Ronald G. Cavell
pp 2791 - 2801; DOI:
10.1021/ic9802101
PDF
A[Bi3Ti4O13] and A[Bi3PbTi5O16] (A = K, Cs): New n = 4 and n = 5 Members of the Layered Perovskite Series, A[A'n-1BnO3n+1], and Their Hydrates
J. Gopalakrishnan, T. Sivakumar, V. Thangadurai, and G. N. Subbanna
pp 2802 - 2806; DOI:
10.1021/ic981427y
PDF
The Preparation, Characterization, and Magnetism of Copper 15-Metallacrown-5 Lanthanide Complexes
Ann J. Stemmler, Jeff W. Kampf, Martin L. Kirk, Bassel H. Atasi, and Vincent L. Pecoraro
pp 2807 - 2817; DOI:
10.1021/ic9800233
PDF
Iridium(III, 0, and -I) Complexes Stabilized by 1,1'-Bis(diphenylphosphino)ferrocene (dppf): Synthesis and Characterization. Crystal Structures of [Na(THF)5][Ir(dppf)2]·THF and [Ir(dppf)2]
Bruno Longato, Lorenzo Riello, Giuliano Bandoli, and Giuseppe Pilloni
pp 2818 - 2823; DOI:
10.1021/ic981166s
PDF
New Robust Bleomycin Analogues: Synthesis, Spectroscopy, and Crystal Structures of the Copper(II) Complexes
Hiromasa Kurosaki, Kentarou Hayashi, Yoshinobu Ishikawa, Masafumi Goto, Kazufumi Inada, Isao Taniguchi, Mitsuhiko Shionoya, and Eiichi Kimura
pp 2824 - 2832; DOI:
10.1021/ic980510i
PDF
Copper(I) Complexes with a NS2-Macrocyclic Ligand Bearing a Pendant Naphthyl Group: Structures of {N-[2-(1-Naphthyl)ethyl]-1-aza-4,8-dithiacyclodecane}copper(I)-Ligand, where Ligand = 2-Naphthalene, Acetonitrile, or Triphenylphosphine
Rebecca R. Conry, William S. Striejewske, and A. Alex Tipton
pp 2833 - 2843; DOI:
10.1021/ic981418p
PDF
Inner-Sphere Cluster Formation by [Ru(NH3)5H2O]3+ or [Os(NH3)5H2O]3+ in Combination with [M(CN)6]4- (M = Fe, Ru, or Os)
Vassiliki G. Poulopoulou, Henry Taube, and Fabio S. Nunes
pp 2844 - 2850; DOI:
10.1021/ic980932s
PDF
Preparation of Cationic Dinuclear Hydrido Complexes of Ruthenium, Rhodium, and Iridium with Bridging Thiolato Ligands and Their Reactions with Nitrosobenzene
Takafumi Iwasa, Hitoshi Shimada, Atsushi Takami, Hiroyuki Matsuzaka, Youichi Ishii, and Masanobu Hidai
pp 2851 - 2859; DOI:
10.1021/ic981274e
PDF
Structure, Chemical Bonding, and Nuclear Quadrupole Interactions of -Cd(OH)2: Experiment and First Principles Calculations
L. Hemmingsen, R. Bauer, M. J. Bjerrum, K. Schwarz, P. Blaha, and P. Andersen
pp 2860 - 2867; DOI:
10.1021/ic990018e
PDF
A Deuterium NMR Spectroscopic Study of Solid BH3NH3
Glenn H. Penner, Y. C. Phillis Chang, and Jennifer Hutzal
pp 2868 - 2873; DOI:
10.1021/ic981370f
PDF
Stereochemically Controlled Synthesis of Ruthenium(II) Complexes Containing Bis(oxazolin-2'-yl)pyridine Ligands. X-ray Crystal Structures of trans-[RuCl2(PPh3){3-N,N,N-(S,S)-iPr-pybox}] and [RuCl(=C=C=CPh2)(PPh3){3-N,N,N-(S,S)-iPr-pybox}][PF6] ((S,S)-iPr-pybox= 2,6-Bis[4'-(S)-isopropyloxazolin-2'-yl]pyridine)
Victorio Cadierno, M. Pilar Gamasa, José Gimeno, Luis Iglesias, and Santiago García-Granda
pp 2874 - 2879; DOI:
10.1021/ic9813258
PDF
Theoretical Model Studies of the Iron Dimer Complex of MMO and RNR
Per E. M. Siegbahn
pp 2880 - 2889; DOI:
10.1021/ic981332w
PDF
Re(V)=O(N2S2) Complexes with N2S2 = Thio-Amido-Secondary Amine-Thio Chelate Ligands: Synthesis, Structure, and Characterization of Solution Forms
Lory Hansen, Xiaolong Xu, Malgorzata Lipowska, Andrew Taylor, Jr., and Luigi G. Marzilli
pp 2890 - 2897; DOI:
10.1021/ic981151u
PDF
Ultraviolet Photochemistry of CoIIIL(H2O)SO3+ [L = Me6[14]dieneN4, [14]aneN4] Complexes. Quandaries about the Linkage Isomerization to O-Bonded Sulfite and the Photogeneration of Cobalt(I) in Sequential Biphotonic Photolysis
S. C. Gibney, G. Ferraudi, and M. Shang
pp 2898 - 2905; DOI:
10.1021/ic9813213
PDF
Synthesis, X-ray Structure, and Solution NMR Studies of Ln(III) Complexes with a Macrocyclic Asymmetric Compartmental Schiff Base. Preference of the Ln(III) Ions for a Crown-Like Coordination Site
Umberto Casellato, Sergio Tamburini, Patrizia Tomasin, Pietro A. Vigato, Silvio Aime, and Mauro Botta
pp 2906 - 2916; DOI:
10.1021/ic980715r
PDF
Raman Spectroscopy Study of the Reaction between Sodium Sulfide or Disulfide and Sulfur: Identity of the Species Formed in Solid and Liquid Phases
Omar El Jaroudi, Eric Picquenard, Noelle Gobeltz, Antoine Demortier, and Jacques Corset
pp 2917 - 2923; DOI:
10.1021/ic9900096
PDF
Excited-State Electron Transfer in a Chromophore-Quencher Complex. Spectroscopic Identification of a Redox-Separated State
Rosa López, Ana M. Leiva, Fernando Zuloaga, Bárbara Loeb, Ester Norambuena, Kristin M. Omberg, Jon R. Schoonover, Durwin Striplin, Martin Devenney, and Thomas J. Meyer
pp 2924 - 2930; DOI:
10.1021/ic981050w
PDF
Sb-Sb Interactions in the Hafnium-Rich Antimonide Hf6TiSb4
Holger Kleinke
pp 2931 - 2935; DOI:
10.1021/ic990138m
PDF
Synthesis of 3-Amino-1-carboxy-o-carborane and an Improved, General Method for the Synthesis of All Three C-Amino-C-carboxycarboranes
Ramesh A. Kasar, Giselle M. Knudsen, and Stephen B. Kahl
pp 2936 - 2940; DOI:
10.1021/ic990037o
PDF
Synthesis, Characterization, and Photochemistry of a Dinuclear Cyanide-Bridged Iron(II)-Platinum(IV) Mixed-Valence Compound and Its Implications for the Corresponding Iron(II)-Platinum(IV)-Iron(II) Complex
Brian W. Pfennig, Jenny V. Lockard, Jamie L. Cohen, David F. Watson, Douglas M. Ho, and Andrew B. Bocarsly
pp 2941 - 2946; DOI:
10.1021/ic981441a
PDF
Flash Photolysis Studies of Roussin's Black Salt Anion: Fe4S3(NO)7-
James Bourassa, Brian Lee, Stefan Bernard, Jon Schoonover, and Peter C. Ford
pp 2947 - 2952; DOI:
10.1021/ic981282v
PDF
Synthesis and Characterization of Tetrahydrofurfurylcyclopentadienyl Molybdenum Tricarbonyl Dimer: Evidence for 19-Electron Intramolecular "Solvento" Interactions
Michelle Gallagher, Pat Dougherty, Pamela S. Tanner, Denis C. Barbini, Jurgen Schulte, and Wayne E. Jones, Jr.
pp 2953 - 2956; DOI:
10.1021/ic9811603
PDF
Reactions of LiE(SiMe3)3, E = Si, Ge: X-ray Crystal Structure of the Cyclotetrastannane [ClSnSi(SiMe3)3]4
S. P. Mallela, Yochen Saar, Sven Hill, and R. A. Geanangel
pp 2957 - 2960; DOI:
10.1021/ic9900455
PDF
Structure-Reactivity Studies in Copper(II)-Catalyzed Phosphodiester Hydrolysis
Eric L. Hegg, Stephen H. Mortimore, Chin Li Cheung, Jennifer E. Huyett, Douglas R. Powell, and Judith N. Burstyn
pp 2961 - 2968; DOI:
10.1021/ic981087g
PDF
Nanoporous, Interpenetrated Metal-Organic Diamondoid Networks
Owen R. Evans, Zhiyong Wang, Ren-Gen Xiong, Bruce M. Foxman, and Wenbin Lin
pp 2969 - 2973; DOI:
10.1021/ic990022q
PDF
Unusual Ligand Isomerization Dictated by Coordination Requirements of the Metal Ion: A Double-Bond Shift in Cu(II)-Assisted Template Condensation between Diacetylpyridine and a Tripodal Tetramine
Elena V. Rybak-Akimova, Alexander Y. Nazarenko, and Svetlana S. Silchenko
pp 2974 - 2980; DOI:
10.1021/ic990027n
PDF
The Reagent [K(18-crown-6)][RuH(PPh3)2(5-7,8-C2B9H11)] as a Precursor to New Ruthenacarborane Complexes
Dianne D. Ellis, Samantha M. Couchman, John C. Jeffery, John M. Malget, and F. Gordon A. Stone
pp 2981 - 2988; DOI:
10.1021/ic990057q
PDF
Retro Models of Pt Anticancer Drug DNA Adducts: Chirality-Controlling Chelate Ligand Restriction of Guanine Dynamic Motion in (2,2'-Bipiperidine)PtG2 Complexes (G = Guanine Derivative)
Susan O. Ano, Francesco P. Intini, Giovanni Natile, and Luigi G. Marzilli
pp 2989 - 2999; DOI:
10.1021/ic981409g
PDF
Reactions of Nitridorhenium(V) and -Osmium(VI) Complexes with Acylating Agents
Wa-Hung Leung, Joyce L. C. Chim, Ian D. Williams, and Wing-Tak Wong
pp 3000 - 3005; DOI:
10.1021/ic981244b
PDF
Possible Intermediate Formation of Cyclic Nitrous Oxide, N2O: Reaction of Oxygen Difluoride, OF2, with Cesium Azide, CsN3
Margaret-Jane Crawford and Thomas M. Klapötke
pp 3006 - 3009; DOI:
10.1021/ic990240j
PDF
Synthesis and Structure of Asymmetric Bis(sulfonamide) Based Copper(II) Complexes: Influence of Diastereomeric Interactions in the Solid State
Alaganandan Nanthakumar, Joanne Miura, Sandra Diltz, Chao-Kang Lee, Gerardo Aguirre, Fernando Ortega, Joseph W. Ziller, and Patrick J. Walsh
pp 3010 - 3013; DOI:
10.1021/ic981093c
PDF
An "Open Cube" Lithium Chloride Tetramer Containing Azetidine Ligands
Alexander Jockisch and Hubert Schmidbaur
pp 3014 - 3016; DOI:
10.1021/ic9900307
PDF

Issue 13


Direct Observation of Ligand-Centered Redox in Cp*2Rh2(-C2S4)Clx (x = 2, 0)
Geoffrey A. Holloway and Thomas B. Rauchfuss
pp 3018 - 3019; DOI:
10.1021/ic990150e
PDF
First Evidence of the LIESST Effect in a Langmuir-Blodgett Film
Jean François Létard, Olivier Nguyen, Hélène Soyer, Christophe Mingotaud, Pierre Delhaès, and Olivier Kahn
pp 3020 - 3021; DOI:
10.1021/ic990259m
PDF
Dealkylation Reactions of Trialkylamines with 1,3,5-Trichloro-1,2,4,6-cyclothiatriazine: A Novel Route to Regiospecific Dialkylamino Substitution on Cyclocarbathiazines
T. V. V. Ramakrishna, Anil. J. Elias, and Ashwani Vij
pp 3022 - 3026; DOI:
10.1021/ic980687c
PDF
Further Structural Information on the Intra- and Interunit Contacts in Dimeric Ruthenium Phthalocyanine
R. Caminiti, M. P. Donzello, C. Ercolani, and C. Sadun
pp 3027 - 3029; DOI:
10.1021/ic9806838
PDF
Electronic, Magnetic, and Spectroscopic Properties of Binuclear Diruthenium Tetracarboxylates: A Theoretical and Experimental Study
Guillermina Estiú, Fabio D. Cukiernik, Pascale Maldivi, and Olivier Poizat
pp 3030 - 3039; DOI:
10.1021/ic981098+
PDF
1H NMR Investigations of Triphenylporphyrin Metal Complexes and Electronic Interactions in Iron(III) Complexes of meso-meso-Linked 5,5'-Bis(10,15,20-triphenylporphyrin)
Jacek Wojaczyski, Lechosaw Latos-Grayski, Piotr J. Chmielewski, Pamela Van Calcar, and Alan L. Balch
pp 3040 - 3050; DOI:
10.1021/ic990038g
PDF
Gas Phase Structure of Methyl Trifluoromethanesulfonate, CH3OSO2CF3, and Conformational Properties of Covalent Sulfonates
Frank Trautner, Aida Ben Altabef, Lis E. Fernandez, Eduardo L. Varetti, and Heinz Oberhammer
pp 3051 - 3055; DOI:
10.1021/ic9901766
PDF
Syntheses and Characterizations of One-Dimensional Coordination Polymers Generated from Cadmium Nitrate and Bipyridine Ligands
Yu-Bin Dong, Ralph C. Layland, Mark D. Smith, Neil G. Pschirer, Uwe H. F. Bunz, and Hans-Conrad zur Loye
pp 3056 - 3060; DOI:
10.1021/ic9814569
PDF
Controlling the Singlet-Triplet Splitting in Bisverdazyl Diradicals: Steps toward Magnetic Polymers
Michael T. Green and Thomas A. McCormick
pp 3061 - 3065; DOI:
10.1021/ic981424l
PDF
Trifluorosulfite Anion, SOF3-
Andreas Kornath, Daniel Kadzimirsz, and Ralf Ludwig
pp 3066 - 3069; DOI:
10.1021/ic9809005
PDF
Linear and Bent M(-CN)Pt(-CN)M Chains: Probes for Remote Metal-Metal Interactions
Guy N. Richardson, Udo Brand, and Heinrich Vahrenkamp
pp 3070 - 3079; DOI:
10.1021/ic981384l
PDF
Structures of Dysprosium(III) Triflates in Water, Methanol, and 2-Propanol As Studied by 17O and 19F NMR Spectroscopy
Arjen M. van Loon, Herman van Bekkum, and Joop A. Peters
pp 3080 - 3084; DOI:
10.1021/ic981345+
PDF
Rhodium(I) and Iridium(I) Complexes Containing -Diketonate or Pyrazole Ligands. Liquid Crystal and Nonlinear Optical Properties
Joaquín Barberá, Anabel Elduque, Raquel Giménez, Fernando J. Lahoz, José A. López, Luis A. Oro, José Luis Serrano, Belén Villacampa, and Julio Villalba
pp 3085 - 3092; DOI:
10.1021/ic9814017
PDF
Oxo- and Hydroxo-Bridged Heme-Copper Assemblies Formed from Acid-Base or Metal-Dioxygen Chemistry
Marie-Aude Kopf, Yorck-Michael Neuhold, Andreas D. Zuberbühler, and Kenneth D. Karlin
pp 3093 - 3102; DOI:
10.1021/ic981431+
PDF
Volumes of Activation for Electron Transfer in Low-Spin/Low-Spin Cationic Couples in Aqueous Solution
Peter D. Metelski, Yansong Fu, Kashif Khan, and Thomas W. Swaddle
pp 3103 - 3109; DOI:
10.1021/ic990064e
PDF
Structure and Magnetic Properties of Trigonal Bipyramidal Iron Nitrosyl Complexes
Manabendra Ray, Adina P. Golombek, Michael P. Hendrich, Glenn P. A. Yap, Louise M. Liable-Sands, Arnold, L. Rheingold, and A. S. Borovik
pp 3110 - 3115; DOI:
10.1021/ic990070a
PDF
Synthesis of Heterobridged (-CCR)(-X) (X = PPh2, PPh2O) Platinum-Rhodium or Platinum-Iridium Dimers
Larry R. Falvello, Juan Forniés, Antonio Martín, Julio Gómez, Elena Lalinde, M. Teresa Moreno, and Jorge Sacristán
pp 3116 - 3125; DOI:
10.1021/ic9900049
PDF
Barriers to Inversion of Nonplanar Ferric Porphyrin Radical Cations: Comparison with the Corresponding Neutral Complexes
Mikio Nakamura, Tatsuya Yamaguchi, and Yoshiki Ohgo
pp 3126 - 3131; DOI:
10.1021/ic990139e
PDF
Existence of the Halocarbonyl and Trifluoromethyl Cations in the Condensed Phase
K. O. Christe, B. Hoge, J. A. Boatz, G. K. S. Prakash, G. A. Olah, and J. A. Sheehy
pp 3132 - 3142; DOI:
10.1021/ic990572o
PDF
Experimental and Theoretical Characterization of the Oxygen-Coordinated Donor-Acceptor Adducts of COCl2, COClF, and COF2 with AsF5 and SbF5
Berthold Hoge, Jerry A. Boatz, Joachim Hegge, and Karl O. Christe
pp 3143 - 3149; DOI:
10.1021/ic990157w
PDF
Peroxo-Bridged Dinuclear Cobalt(III) Complexes Containing N-Glycoside Ligands from Tris(2-aminoethyl)amine and D-Glucose or Maltose
Tomoaki Tanase, Tomoko Onaka, Masako Nakagoshi, Isamu Kinoshita, Kozo Shibata, Matsumi Doe, Junko Fujii, and Shigenobu Yano
pp 3150 - 3159; DOI:
10.1021/ic9809310
PDF
A Major, pH-Induced Stereochemical Switch of Pairs of trans-Oriented Ligands in Complexes of trans-a2PtII (a = NH3, CH3NH2)
Jens Müller, Frank Glahé, Eva Freisinger, and Bernhard Lippert
pp 3160 - 3166; DOI:
10.1021/ic990044c
PDF
Synthesis, Characterization, and Solution Properties of Skeletally Stabilized Triphosphazanes
Monte L. Helm, Stephanie A. Katz, Tomasz W. Imiolczyk, Robert M. Hands, and Arlan D. Norman
pp 3167 - 3172; DOI:
10.1021/ic981408o
PDF
Spectroscopic and Quantum Chemical Studies of Excited States of One- and Two-Electron Oxidation Products of a Lutetium Triple-Decker Phthalocyanine Complex
Naoto Ishikawa, Tomoko Okubo, and Youkoh Kaizu
pp 3173 - 3181; DOI:
10.1021/ic981463x
PDF
Reactions of Ruthenium Bipyridine Catalyst Precursors: Synthetic, Structural, and Theoretical Studies on Ruthenium Mono(bipyridine) Carbonyls in Ethylene Glycol Solutions
Matti Haukka, Pipsa Hirva, Saija Luukkanen, Mirja Kallinen, Markku Ahlgrén, and Tapani A. Pakkanen
pp 3182 - 3189; DOI:
10.1021/ic981266y
PDF
1H NMR in Solution and Solid State Structural Study of Lanthanide(III) Cryptates
C. Platas, F. Avecilla, A. de Blas, C. F. G. C. Geraldes, T. Rodríguez-Blas, H. Adams, and J. Mahía
pp 3190 - 3199; DOI:
10.1021/ic981314e
PDF
Synthesis and Characterization of Dinuclear Ruthenium Complexes with Tetra-2-pyridylpyrazine as a Bridge
Chris M. Hartshorn, Nadime Daire, Valerie Tondreau, Barbara Loeb, Thomas J. Meyer, and Peter S. White
pp 3200 - 3206; DOI:
10.1021/ic990110a
PDF
2,5-Diphenyl-3,4-bis(trimethylsilyl)-1-phosphacyclopentadienide as a Ligand at Calcium, Strontium, and Tin(II)
Matthias Westerhausen, Matthias H. Digeser, Heinrich Nöth, Werner Ponikwar, Thomas Seifert, and Kurt Polborn
pp 3207 - 3214; DOI:
10.1021/ic981132k
PDF
Catalytic Hydrolysis of Adenosine 2',3'-Cyclic Monophosphate by CuII Terpyridine
Lisa A. Jenkins, James K. Bashkin, Jennifer D. Pennock, Jan Florián, and Arieh Warshel
pp 3215 - 3222; DOI:
10.1021/ic990228r
PDF
Interaction of Carbon Dioxide with [IrH2{(tBu2)PCH2CH2CHCH2CH2P(tBu2)}]
Margaret A. McLoughlin, Nancy L. Keder, William T. A. Harrison, Robert J. Flesher, Hermann A. Mayer, and William C. Kaska
pp 3223 - 3227; DOI:
10.1021/ic980722f
PDF
Cyclic Hydroborate Complexes of Metallocenes. V. Syntheses and Structures of Zirconocene Organoborate Derivatives: Cp2ZrH{(-H)2BC4H8}, Cp2Zr(CH2Ph){(-H)2BC4H8}, and Cp2Zr(CH2Ph){(-H)2BC5H10}
Fu-Chen Liu, Bin Du, Jianping Liu, Edward A. Meyers, and Sheldon G. Shore
pp 3228 - 3234; DOI:
10.1021/ic990221+
PDF
Solid State Structure of {[HC(3,5-Me2pz)3][HB(3,5-Me2pz)3]Cd}{B[3,5-(CF3)2C6H3]4}: Comparison of the Bonding of Tris(pyrazolyl)methane and Tris(pyrazolyl)borate Ligands
Daniel L. Reger, James E. Collins, Arnold L. Rheingold, and Louise M. Liable-Sands
pp 3235 - 3237; DOI:
10.1021/ic981453w
PDF
Biomimetic Alkane Hydroxylations by an Iron(III) Porphyrin Complex with H2O2 and by a High-Valent Iron(IV) Oxo Porphyrin Cation Radical Complex
Wonwoo Nam, Yeong Mee Goh, Yoon Jung Lee, Mi Hee Lim, and Cheal Kim
pp 3238 - 3240; DOI:
10.1021/ic980670u
PDF
Synthesis and Characterization of the Tetranuclear RuII Complex [RuCl(-Cl)- (P(OMe)3)2(,1,2-S2)Ru(P(OMe)3)(-P(OMe)3- P,O)]2 Containing a trans-RuIISSRuII Core
Tetsuya Koyama, Yoshihiro Koide, and Kazuko Matsumoto
pp 3241 - 3243; DOI:
10.1021/ic9812508
PDF
Three-Membered -SCoCH2 Chelate Ring Complex Formed by Photodecarboxylation Reaction of Optically Active trans(O)-[Co(edtda)(en)]Cl (edtda = Ethylenedithiodiacetate)
Toshiaki Yonemura, Kimi Shibuya, Tomoharu Ama, Hiroshi Kawaguchi, Ken-ichi Okamoto, Jinsai Hidaka, and Takaji Yasui
pp 3244 - 3247; DOI:
10.1021/ic981391+
PDF
pH Induced Active ("Uphill") Liquid Membrane Transport of Ferrioxamine B by the Ionizable Ionophore Lasalocid
Ivan Spasojevi and Alvin L. Crumbliss
pp 3248 - 3250; DOI:
10.1021/ic9813664
PDF
Copper(II) Complexes of Histamine and Cysteine Produced by Thiosulfate-Assisted Synthesis Using Copper(I) Cyanide. The in Situ Formation of the Thiocyanate Anion and the 2-Amino-2-thiazoline-4-carboxylic Acid Ligand
Fred B. Stocker, Paul Fadden, Spencer Dreher, and Doyle Britton
pp 3251 - 3253; DOI:
10.1021/ic9814118
PDF
Photophysics and Photoredox Properties of the Tungsten Carbyne Complex Cp{P(OPh)3}(CO)WCPh
Carla C. S. Cavalheiro, Karen E. Torraca, Kirk S. Schanze, and Lisa McElwee-White
pp 3254 - 3257; DOI:
10.1021/ic990077s
PDF
Carboxamido Nitrogens Are Good Donors for Fe(III): Syntheses, Structures, and Properties of Two Low-Spin Nonmacrocyclic Iron(III) Complexes with Tetracarboxamido-N Coordination
Dana S. Marlin, Marilyn M. Olmstead, and Pradip K. Mascharak
pp 3258 - 3260; DOI:
10.1021/ic981461c
PDF

Issue 14


A Linear Tetrapyrrole as a Binucleating Ligand with Copper(II). Coordination beyond the Usual M-N4 Bonding
Richard Koerner, Marilyn M. Olmstead, Andrzej Ozarowski, and Alan L. Balch
pp 3262 - 3263; DOI:
10.1021/ic9901113
PDF
Excited-State Self-Quenching Reactions of Square Planar Platinum(II) Diimine Complexes in Room-Temperature Fluid Solution
William B. Connick, David Geiger, and Richard Eisenberg
pp 3264 - 3265; DOI:
10.1021/ic981387y
PDF
Synthesis and Structural Characterization of Novel Terminal and Bridging Re(V)-Sulfido Complexes
Josemon Jacob, Ilia A. Guzei, and James H. Espenson
pp 3266 - 3267; DOI:
10.1021/ic990354v
PDF
197Au Mössbauer Characterization of the Noncovalent Adducts Formed between Serum Albumin and Dicyanoaurate(I), a Gold-Drug Metabolite
Annapurna Canumalla, C. Frank Shaw, III, and Friedrich E. Wagner
pp 3268 - 3269; DOI:
10.1021/ic9901261
PDF
The FeIII/FeII vs Fe22.5 Formulation in Mixed-Valent Species [(NC)4Fe(BL)Fe(CN)4]3-, BL = 2,2'-Bipyrimidine and 3,6-Bis(2-pyridyl)-1,2,4,5-tetrazine. Distance and Size Do Not Always Matter
Markus Glöckle, Wolfgang Kaim, Néstor E. Katz, Mónica García Posse, Edgardo H. Cutin, and Jan Fiedler
pp 3270 - 3274; DOI:
10.1021/ic990249l
PDF
Solution Characterization of Vanadium(V) and -(IV) N-(Phosphonomethyl)iminodiacetate Complexes: Direct Observation of One Enantiomer Converting to the Other in an Equilibrium Mixture
Debbie C. Crans, Feilong Jiang, Iman Boukhobza, Istvan Bodi, and Tamas Kiss
pp 3275 - 3282; DOI:
10.1021/ic9812454
PDF
Carbohydrate Binding to VO3+. Sugar Vanadate Esters Incorporating L-Amino Acid Schiff Bases as Coligands
Kajal Krishna Rajak, Sankar Prasad Rath, Sujit Mondal, and Animesh Chakravorty
pp 3283 - 3289; DOI:
10.1021/ic981344h
PDF
A Nucleophilic Chromium(V) Dioxo Radical Anion
Aaron L. Odom, Daniel J. Mindiola, and Christopher C. Cummins
pp 3290 - 3295; DOI:
10.1021/ic981403r
PDF
Mononuclear and Binuclear Ruthenium(II) Complexes Containing 2,2'-Bipyridine or 1,10-Phenanthroline and Pyrazole-3,5-Bis(benzimidazole). Synthesis, Structure, Isomerism, Spectroscopy, and Proton-Coupled Redox Activity
Sujoy Baitalik, Ulrich Flörke, and Kamalaksha Nag
pp 3296 - 3308; DOI:
10.1021/ic980564s
PDF
Fluoride Reactions with Hydrotris(pyrazolyl)borate Rhenium Oxo Complexes: Re-F vs B-F Bond Formation
Darin D. DuMez, Todd O. Northcutt, Yoshihiro Matano, and James M. Mayer
pp 3309 - 3312; DOI:
10.1021/ic981334g
PDF
Synthesis and Structural Characterization of an Unusual Oxygen-Linked Double Cubane-Like Cluster {[Mo3PbOS3](OAc)2(py)3(dtp)2O}2
Rong-Min Yu, Shao-Fang Lu, Xiao-Ying Huang, Qiang-Jin Wu, and Jian-Quan Huang
pp 3313 - 3315; DOI:
10.1021/ic9703890
PDF
Bis-macrocyclic Ligands with Two Ferrocenyl End Groups, and Their Tetranuclear Dicopper(I) Compounds
Peter Comba, Jürgen Ensling, Philipp Gütlich, Andreas Kühner, Alexander Peters, and Hans Pritzkow
pp 3316 - 3320; DOI:
10.1021/ic981389i
PDF
High-Field EPR Study of Resonance-Delocalized [Fe2(OH)3(tmtacn)2]2+
Michael J. Knapp, J. Krzystek, Louis-Claude Brunel, and David N. Hendrickson
pp 3321 - 3328; DOI:
10.1021/ic9901012
PDF
Formation and Redox Reactivity of Osmium(II) Thionitrosyl Complexes
El-Sayed El-Samanody, Konstantinos D. Demadis, Laurie A. Gallagher, Thomas J. Meyer, and Peter S. White
pp 3329 - 3336; DOI:
10.1021/ic981449k
PDF
Crystal Structure of [Ru(terpy)2]0: A New Crystalline Material from the Reductive Electrocrystallization of [Ru(terpy)2]2+
Soomi Pyo, Eduardo Pérez-Cordero, Simon G. Bott, and Luis Echegoyen
pp 3337 - 3343; DOI:
10.1021/ic981395e
PDF
Lanthanoid Rhenium Aluminides with a High Content of Aluminum: LnRe2Al10 (Ln = Ho-Lu) with a New Structure Type and NdRe2Al10 with CaCr2Al10-Type Structure
Birgit Fehrmann and Wolfgang Jeitschko
pp 3344 - 3351; DOI:
10.1021/ic990073n
PDF
An Interpretation of Gated Behavior: Kinetic Studies of the Oxidation and Reduction Reactions of Bis(2,9-dimethyl-1,10-phenanthroline)copper(I/II) in Acetonitrile
Nobuyoshi Koshino, Yoshio Kuchiyama, Hiroshi Ozaki, Shigenobu Funahashi, and Hideo D. Takagi
pp 3352 - 3360; DOI:
10.1021/ic9810687
PDF
Aqueous Organometallic Chemistry of Ruthenium(II). Aquo Carbonyl Derivatives and Related Ethene Hydrocarboxylation in Fully Aqueous Solvent
Tiziana Funaioli, Claudia Cavazza, Fabio Marchetti, and Giuseppe Fachinetti
pp 3361 - 3368; DOI:
10.1021/ic981429i
PDF
Chloro- and Fluoro-Substituted Phosphites, Phosphates, and Phosphoranes Exhibiting Sulfur and Oxygen Coordination
A. Chandrasekaran, Paul Sood, Roberta O. Day, and Robert R. Holmes
pp 3369 - 3376; DOI:
10.1021/ic9901214
PDF
Synthesis and Crystal Structure of Zr2Te. Distinctions in Bonding to Isotypic Sc2Te and the Relationship to the Structures of Congeneric Hf2Te and Zr2Se
Gissur Örlygsson and Bernd Harbrecht
pp 3377 - 3383; DOI:
10.1021/ic990024a
PDF
Mixed Chloride/Phosphine Complexes of the Dirhenium Core. 5. Reduction or Disproportionation at the Re26+ Unit in Reactions with Tertiary Phosphines in Different Solvents
F. Albert Cotton, Evgeny V. Dikarev, and Marina A. Petrukhina
pp 3384 - 3389; DOI:
10.1021/ic990114f
PDF
Metal Iodides in Polyiodide Networks: Synthesis and Structure of Binary Metal Iodide-Iodine Compounds Stable under Ambient Conditions
Per H. Svensson and Lars Kloo
pp 3390 - 3393; DOI:
10.1021/ic981348m
PDF
Covalent Three-Dimensional Titanium(IV)-Aryloxide Networks
Thomas P. Vaid, Joseph M. Tanski, John M. Pette, Emil B. Lobkovsky, and Peter T. Wolczanski
pp 3394 - 3405; DOI:
10.1021/ic990109b
PDF
Reactivity of a Vanadium(III) Center over an Oxo Surface Modeled by Calix[4]arene
Barbara Castellano, Euro Solari, Carlo Floriani, Rosario Scopelliti, and Nazzareno Re
pp 3406 - 3413; DOI:
10.1021/ic990017m
PDF
Effects of Sterics and Electronic Delocalization on the Photophysical, Structural, and Electrochemical Properties of 2,9-Disubstituted 1,10-Phenanthroline Copper(I) Complexes
Mark T. Miller, Peter K. Gantzel, and Timothy B. Karpishin
pp 3414 - 3422; DOI:
10.1021/ic9900399
PDF
Molecular Shape and Solvation of the Lacunar, Saddle-Shaped, and Planar Metal Cyclidene Complexes: Molecular Dynamics Studies
Elena V. Rybak-Akimova, Krzysztof Kuczera, Gouri S. Jas, Yanpei Deng, and Daryle H. Busch
pp 3423 - 3434; DOI:
10.1021/ic9904485
PDF
M3Ni3Sb4 (M = Zr, Hf) and Zr3Pt3Sb4. Ternary Antimonides with the Y3Au3Sb4 Structure
Meitian Wang, Robert McDonald, and Arthur Mar
pp 3435 - 3438; DOI:
10.1021/ic990144i
PDF
Fast Oxygen Atom Transfer from in Situ Generated Peroxynitrous Acid to Thiolato Sulfur Coordinated to Cobalt(III)
Stéphane Vayssié and Horst Elias
pp 3439 - 3442; DOI:
10.1021/ic981423t
PDF
Preparation and Photophysical Properties of Amide-Linked, Polypyridylruthenium-Derivatized Polystyrene
Duane A. Friesen, Toru Kajita, Earl Danielson, and Thomas J. Meyer
pp 3442 - 3442; DOI:
10.1021/ic990543d
PDF

Issue 15


Abnormal Broadening of Free Radical EPR Lines: A New Test Probe for Singlet Dioxygen in Solution
Alexander E. Gekhman, Natalia I. Moiseeva, Vadim V. Minin, Gennady M. Larin, and Ilya I. Moiseev
pp 3444 - 3445; DOI:
10.1021/ic990063m
PDF
Terphenyl Ligand Systems in Lanthanide Chemistry: Synthesis and Structural Characterization of Two 2,6-Dimesitylphenyl Derivatives of Trivalent Ytterbium
Gerd W. Rabe, Christine S. Strissel, Louise M. Liable-Sands, Thomas E. Concolino, and Arnold L. Rheingold
pp 3446 - 3447; DOI:
10.1021/ic990290o
PDF
Cu(C10H9N3)2MOF5·2H2O (M = Nb, Ta): Aligned [MOF5]2- Oxide Fluoride Anions
Alexander J. Norquist, Charlotte L. Stern, and Kenneth R. Poeppelmeier
pp 3448 - 3449; DOI:
10.1021/ic990366g
PDF
Preparation, X-ray Structure, and Spectroscopic Characterization of 1,5-Se2S2N4
Arto Maaninen, Risto S. Laitinen, Tristram Chivers, and Tapani A. Pakkanen
pp 3450 - 3454; DOI:
10.1021/ic990179i
PDF
First Tin Pnictide Halides Sn24P19.3I8 and Sn24As19.3I8: Synthesis and the Clathrate-I Type of the Crystal Structure
Mikhail M. Shatruk, Kirill A. Kovnir, Andrei V. Shevelkov, Igor A. Presniakov, and Boris A. Popovkin
pp 3455 - 3457; DOI:
10.1021/ic990153r
PDF
Hydrothermal Synthesis and Characterization of a Novel Two-Dimensional Tellurite of Molybdenum(VI), (NH4)6Mo8Te8O43·H2O
Vidyavathy Balraj and K. Vidyasagar
pp 3458 - 3462; DOI:
10.1021/ic9901160
PDF
Magic Electron Counts for Networks of Condensed Octahedral Niobium Clusters in Oxoniobates
Grigori V. Vajenine and Arndt Simon
pp 3463 - 3473; DOI:
10.1021/ic981460k
PDF
On the Structural Dichotomy of Cationic, Anionic, and Neutral FeS2
Detlef Schröder, Ilona Kretzschmar, Helmut Schwarz, Chad Rue, and P. B. Armentrout
pp 3474 - 3480; DOI:
10.1021/ic990241b
PDF
A Supramolecular Synthon for H-Bonded Transition Metal Arrays
Paul V. Bernhardt
pp 3481 - 3483; DOI:
10.1021/ic990074f
PDF
Design of Ligands That Stabilize Cu(I) and Shift the Reduction Potential of the CuII/I Couple Cathodically in Aqueous Solutions
Nadav Navon, Gilad Golub, Haim Cohen, Piero Paoletti, Barbara Valtancoli, Andrea Bencini, and Dan Meyerstein
pp 3484 - 3488; DOI:
10.1021/ic9812048
PDF
Iron-Molybdenum Electron Delocalization in Substituted Keggin Polyoxoanions
Hélène Duclusaud and Serguei A. Borshch
pp 3489 - 3493; DOI:
10.1021/ic990183u
PDF
Gold(I) Compounds without Significant Aurophilic Intermolecular Interactions: Synthesis, Structure, and Electronic Properties of Ph3PAuC(O)NHMe and Au3(PhCH2N=COMe)3: Comparative Monomeric and Trimeric Analogues of the Solvoluminescent Trimer, Au3(MeN=COMe)3
Alan L. Balch, Marilyn M. Olmstead, and Jess C. Vickery
pp 3494 - 3499; DOI:
10.1021/ic990080b
PDF
Mechanistic Information on the Redox Cycling of Nickel(II/III) Complexes in the Presence of Sulfur Oxides and Oxygen. Correlation with DNA Damage Experiments
Vasilios Lepentsiotis, Joanna Domagala, Irena Grgic, Rudi van Eldik, James G. Muller, and Cynthia J. Burrows
pp 3500 - 3505; DOI:
10.1021/ic981342x
PDF
Side Arm Effects on Cyclen-Alkali Metal Cation Complexation: Highly Selective and Three-Dimensional Encapsulation of Na+ Ion
Hiroshi Tsukube, Yoshihisa Mizutani, Satoshi Shinoda, Tsuyoshi Okazaki, Makoto Tadokoro, and Kenzi Hori
pp 3506 - 3512; DOI:
10.1021/ic980590q
PDF
Deprotonation-Induced Enantioselective Aggregation and Deprotonation-Induced Ligand Rearrangement of Copper(II) Complexes Yield 1D Homochiral and Heterochiral Chains and a Cyclic Tetramer, Respectively
Yoshiki Shii, Yuri Motoda, Toshihiro Matsuo, Fumiaki Kai, Toshio Nakashima, Jean-Pierre Tuchagues, and Naohide Matsumoto
pp 3513 - 3522; DOI:
10.1021/ic9813260
PDF
UVRR Spectroscopy and Vibrational Analysis of Mercury Thiolate Compounds Resembling d10 Metal Binding Sites in Proteins
Gerhard Fleissner, Pawel M. Kozlowski, Mária Vargek, James W. Bryson, Thomas V. O'Halloran, and Thomas G. Spiro
pp 3523 - 3528; DOI:
10.1021/ic9810384
PDF
Electron Spin Relaxation in Chromium-Nitrosyl Complexes
Lenny M. Carruthers, Christina L. Closken, Karen L. Link, Surendra N. Mahapatro, Malavosklish Bikram, Jing-Long Du, Sandra S. Eaton, and Gareth R. Eaton
pp 3529 - 3534; DOI:
10.1021/ic981063+
PDF
Synthesis, Structure, Biological Activity, and DNA Binding of Platinum(II) Complexes of the Type trans-[PtCl2(NH3)L] (L = Planar Nitrogen Base). Effect of L and Cis/Trans Isomerism on Sequence Specificity and Unwinding Properties Observed in Globally Platinated DNA
Ulrich Bierbach, Yun Qu, Trevor W. Hambley, John Peroutka, Holly L. Nguyen, Marijo Doedee, and Nicholas Farrell
pp 3535 - 3542; DOI:
10.1021/ic981181x
PDF
Effect of Included Solvent Molecules on the Physical Properties of the Paramagnetic Charge Transfer Salts ' '-(bedt-ttf)4[(H3O)Fe(C2O4)3]·Solvent (bedt-ttf = Bis(ethylenedithio)tetrathiafulvalene)
Scott S. Turner, Peter Day, K. M. Abdul Malik, Michael B. Hursthouse, Simon J. Teat, Elizabeth J. MacLean, Lee Martin, and Samual A. French
pp 3543 - 3549; DOI:
10.1021/ic990102u
PDF
Investigation of the Unusual Electronic Structure of Pyrococcus furiosus 4Fe Ferredoxin by EPR Spectroscopy of Protein Reduced at Ambient and Cryogenic Temperatures
Joshua Telser, Roman Davydov, Chul-Hwan Kim, Michael W. W. Adams, and Brian M. Hoffman
pp 3550 - 3553; DOI:
10.1021/ic990209h
PDF
Molybdenum(V) on an Oxide String. Synthesis and Structure of the Novel Linear Trinuclear Complex {[MoO(TPP)][O-Mo(TPP)-O][MoO(TPP)]}ClO4
Brent J. Hamstra, Beisong Cheng, Mary K. Ellison, and W. Robert Scheidt
pp 3554 - 3561; DOI:
10.1021/ic990566s
PDF
The Synthesis and Characterization of 4, 5, and 6 Coordinate Ni(II) Complexes of the "Heteroscorpionate" Ligand (3-tert-Butyl-2-hydroxy-5-methylphenyl)bis(3,5-dimethylpyrazolyl)methane
Brian S. Hammes and Carl J. Carrano
pp 3562 - 3568; DOI:
10.1021/ic9900962
PDF
Methylation of Iron-Sulfur Complexes by Trimethyl Phosphate
Jonathan J. Wilker and Stephen J. Lippard
pp 3569 - 3574; DOI:
10.1021/ic9808899
PDF
Biomimetic Oxidation Studies. 11. Alkane Functionalization in Aqueous Solution Utilizing in Situ Formed [Fe2O(1-H2O)(1-OAc)(TPA)2]3+, as an MMO Model Precatalyst, Embedded in Surface-Derivatized Silica and Contained in Micelles
Karine Neimann, Ronny Neumann, Alain Rabion, Robert M. Buchanan, and Richard H. Fish
pp 3575 - 3580; DOI:
10.1021/ic990155b
PDF
Crystal Structure and Solution Fluxionality of Lanthanide Complexes of 2,4,6,-Tris-2-pyridyl-1,3,5-triazine
Raphaël Wietzke, Marinella Mazzanti, Jean-Marc Latour, and Jacques Pécaut
pp 3581 - 3585; DOI:
10.1021/ic990122w
PDF
{[AuL2]+[LAuCl][AuCl2]-} (L = 2-Aminopyridine): A Trinuclear Gold(I) Unit in the Pattern [+ Neutral -]
John H. K. Yip, Ren Feng, and Jagadese J. Vittal
pp 3586 - 3589; DOI:
10.1021/ic990230i
PDF
Nickel(II) and Zinc(II) meso-Tetracyclohexylporphyrins. Structural and Electronic Effects Induced by meso-Cyclohexyl Substitution in Metalloporphyrins
Marc Veyrat, René Ramasseul, Ilona Turowska-Tyrk, W. Robert Scheidt, Marie Autret, Karl M. Kadish, and Jean-Claude Marchon
pp 3590 - 3590; DOI:
10.1021/ic9904900
PDF

Issue 16


Synthesis and Characterization of Novel Alkylperoxo Mononuclear Iron(III) Complexes with a Tripodal Pyridylamine Ligand: A Model for Peroxo Intermediates in Reactions Catalyzed by Non-Heme Iron Enzymes
Akira Wada, Seiji Ogo, Yoshihito Watanabe, Masahiro Mukai, Teizo Kitagawa, Koichiro Jitsukawa, Hideki Masuda, and Hisahiko Einaga
pp 3592 - 3593; DOI:
10.1021/ic9900298
PDF
Assembly of a Heterobimetallic Diazasulfate Cluster via an Li4O4 Ladder
Justin K. Brask, Tristram Chivers, Masood Parvez, and Glenn P. A. Yap
pp 3594 - 3595; DOI:
10.1021/ic9903578
PDF
SiO2 Sol-Gel Composite Films Containing Redox-Active, Polypyridyl-Ruthenium Polymers
Milan Sykora, Kimberly A. Maxwell, and Thomas J. Meyer
pp 3596 - 3597; DOI:
10.1021/ic990054d
PDF
Structure, Single Crystal EPR Spectra, and Exchange Interactions in [Cu(L-PROLINE)2]2·5H2O AND CU(D,L-proline)2·2H2O
R. P. Sartoris, L. Ortigoza, N. M. C. Casado, R. Calvo, E. E. Castellano, and O. E. Piro
pp 3598 - 3604; DOI:
10.1021/ic9900758
PDF
Synthesis of Pyridine NS2 Ligands Incorporating 1-Methoxycarbonyl-2-thio(o-carborane). Are They a Route to "Carboranethiophene" Compounds?
Francesc Teixidor, Pilar Anglès, and Clara Viñas
pp 3605 - 3608; DOI:
10.1021/ic9716060
PDF
Relationships among Ionic Lattice Energies, Molecular (Formula Unit) Volumes, and Thermochemical Radii
H. Donald B. Jenkins, Helen K. Roobottom, Jack Passmore, and Leslie Glasser
pp 3609 - 3620; DOI:
10.1021/ic9812961
PDF
Magnetic Transitions in the Cyano-Bridged Bimetallic Ferromagnet Mn2(H2O)5Mo(CN)7·4.75H2O ( Phase)
Joulia Larionova, Olivier Kahn, Stéphane Golhen, Lahcène Ouahab, and Rodolphe Clérac
pp 3621 - 3627; DOI:
10.1021/ic981262t
PDF
Quenching of Triplet State Tetrakis(-pyrophosphito-PP')diplatinate(II) by Nickel(II) Macrocyclic and Tris-diimine Complexes
I. Mackay, L.-Z. Cai, A. D. Kirk, and A. McAuley
pp 3628 - 3633; DOI:
10.1021/ic990093p
PDF
Cobalt Cage Complexes with N3S3 Donor Sets and Differing Cavity Sizes: A Novel Macrobicyclic Cage with a Contracted Cap
Peter Osvath, Alan M. Sargeson, Alex McAuley, Rosa E. Mendelez, S. Subramanian, Michael J. Zaworotko, and Louise Broge
pp 3634 - 3643; DOI:
10.1021/ic981380g
PDF
A Study of the Spin-State Transition and Phase Transformation in [Fe(bpp)2][CF3SO3]2·H2O and [Fe(bpp)2][BF4]2 Using Mn2+ Electron Spin Resonance
Raymond C. W. Sung and Bruce R. McGarvey
pp 3644 - 3650; DOI:
10.1021/ic990099e
PDF
Complexes of Triamidoamines with the Early Actinides. Synthetic Routes to Monomeric Compounds of Tetravalent Uranium and Thorium Containing Halide and Amide Ligands
Paul Roussel, Nathaniel W. Alcock, Rita Boaretto, Andrew J. Kingsley, Ian J. Munslow, Christopher J. Sanders, and Peter Scott
pp 3651 - 3656; DOI:
10.1021/ic990563f
PDF
Metal Pyrazolato Complexes. Synthesis, Characterization, and X-ray Powder Diffraction Studies of Group 12 Coordination Polymers
Norberto Masciocchi, G. Attilio Ardizzoia, Angelo Maspero, Girolamo LaMonica, and Angelo Sironi
pp 3657 - 3664; DOI:
10.1021/ic990258u
PDF
Sensitization of TiO2 by Phosphonate-Derivatized Proline Assemblies
Scott A. Trammell, John A. Moss, John C. Yang, Bassam M. Nakhle, Cheryl A. Slate, Fabrice Odobel, Milan Sykora, Bruce W. Erickson, and Thomas J. Meyer
pp 3665 - 3669; DOI:
10.1021/ic990052t
PDF
A Novel Dimeric Ni-Substituted -Keggin Silicotungstate: Structure and Magnetic Properties of K12[{-SiNi2W10O36(OH)2(H2O)}2]·20H2O
Ulrich Kortz, Yves P. Jeannin, André Tézé, Gilbert Hervé, and Samih Isber
pp 3670 - 3675; DOI:
10.1021/ic990008d
PDF
Spectroscopic Investigation of Reduced Protocatechuate 3,4-Dioxygenase: Charge-Induced Alterations in the Active Site Iron Coordination Environment
Mindy I. Davis, Erik C. Wasinger, Tami E. Westre, Jeffrey M. Zaleski, Allen M. Orville, John D. Lipscomb, Britt Hedman, Keith O. Hodgson, and Edward I. Solomon
pp 3676 - 3683; DOI:
10.1021/ic981464p
PDF
Synthesis and Structure of [{Mo(CO)4}2(cis--F2SbF4)3]x[Sb2F11]x: An Ionic Coordination Polymer
Raimund Bröchler, Daniel Freidank, Matthias Bodenbinder, Iona H. T. Sham, Helge Willner, Steven J. Rettig, James Trotter, and Friedhelm Aubke
pp 3684 - 3687; DOI:
10.1021/ic981439j
PDF
X-ray Absorption Spectroscopy Studies of Ruthenoxane Phthalocyanine Derivative HO-[(Pc)RuO]n-H
L. Alagna, A. Capobianchi, P. Marovino, A. M. Paoletti, G. Pennesi, T. Prosperi, and G. Rossi
pp 3688 - 3691; DOI:
10.1021/ic9812860
PDF
Nature of the Interaction between LnIII and CuII Ions in the Ladder-Type Compounds {Ln2[Cu(opba)]3}·S (Ln = Lanthanide Element; opba = ortho-Phenylenebis(oxamato), S = Solvent Molecules)
Myrtil L. Kahn, Corine Mathonière, and Olivier Kahn
pp 3692 - 3697; DOI:
10.1021/ic9811998
PDF
Synthesis and Dimer Cleavage Reactions of the N2S Thiolate Bridged Dimer [(mmp-dach)2Ni2]Cl2
Craig A. Grapperhaus, John A. Bellefeuille, Joseph H. Reibenspies, and Marcetta Y. Darensbourg
pp 3698 - 3703; DOI:
10.1021/ic990106z
PDF
Catalysis of the Electroreduction of O2 to H2O by Vanadium-salen Complexes in Acidified Dichloromethane
Eishun Tsuchida, Kenichi Oyaizu, Eniya Listiani Dewi, Takahiro Imai, and Fred C. Anson
pp 3704 - 3708; DOI:
10.1021/ic990268v
PDF
Synthesis and Characterization of Zinc and Cadmium Compounds with Arenephosphinothiol Ligands. Crystal and Molecular Structures of [Cd2{2-(Ph2PO)C6H4S}4], [Zn{2-(Ph2P)-6-(Me3Si)C6H3S}2], [Cd{2-(Ph2PO)-6-(Me3Si)C6H3S}2(CH3OH)], and [Zn{PhPO(C6H4S-2)2}(bipy)]
Paulo Pérez-Lourido, Jaime Romero, José A. García-Vázquez, Antonio Sousa, Kevin P. Maresca, and Jon Zubieta
pp 3709 - 3715; DOI:
10.1021/ic981405b
PDF
First-Row Transition-Metal Complexes of the 1-Methoxycyclobutenedionate(1-) Ion
Hazel-Ann Hosein, Hema Jaggernauth, Bert D. Alleyne, Lincoln A. Hall, Andrew J. P. White, and David J. Williams
pp 3716 - 3720; DOI:
10.1021/ic990199k
PDF
Redox Behavior of [H6-nNi38Pt6(CO)48]n- (n = 4-6) Anions: A Series of Metal Carbonyl Clusters Displaying Electron-Sink Features
Fabrizia Fabrizi de Biani, Cristina Femoni, Maria Carmela Iapalucci, Giuliano Longoni, Piero Zanello, and Alessandro Ceriotti
pp 3721 - 3724; DOI:
10.1021/ic9813516
PDF
Experimental Investigations and Ab Initio Studies of Tellurium(II) Dithiolates, Te(SR)2
Holger Fleischer, Sandra Stauf, and Dieter Schollmeyer
pp 3725 - 3729; DOI:
10.1021/ic990104e
PDF
Synthesis and Structure of Bis(-cyclopentadienyl)vanadium(IV) 1,10-Phenanthroline and 2,2'-Bipyridine Compounds and Their Interactions with Artificial Membranes
Phalguni Ghosh, Ann T. Kotchevar, Darin D. DuMez, Sutapa Ghosh, John Peiterson, and Fatih M. Uckun
pp 3730 - 3737; DOI:
10.1021/ic9902469
PDF
Synthesis, Characterization, and Explosive Properties of the Nitrogen-Rich Borazine [H3N3B3(N3)3]
Robert T. Paine, Wolfgang Koestle, Theodore T. Borek, Gary L. Wood, Eugene A. Pruss, Eileen N. Duesler, and Michael A. Hiskey
pp 3738 - 3743; DOI:
10.1021/ic990316b
PDF
Novel Three-Dimensional Cage Assembly of a 4-Carbonato-Bridged Cobalt(II) Compound [Co2(bpm)(H2O)2(CO3)(OH)]NO3·4H2O
Donatella Armentano, Giovanni De Munno, Francesc Lloret, and Miguel Julve
pp 3744 - 3747; DOI:
10.1021/ic981323n
PDF
Synthesis and Crystal Structure of a New Hexahydro-closo-hexaborate Copper(I) Complex Cu2[(C6H5)3P]4B6H6
Raifah M. Kabbani, Arnold L. Rheingold, Kin-Chung Lam, Yevgeniy Margulis, and Max Vovchenko
pp 3748 - 3750; DOI:
10.1021/ic990248t
PDF
New Synthetic Route, X-ray Structure, and Molecular Orbital Analysis for trans,trans- Dichlorobis(triphenylphosphine)(phenyl)- rhodium(III). Do Agostic Rh···H(PPh3), Hydrogen-Bond (Rh)Cl···H(PPh3), or Steric Intramolecular Interactions Prevail?
Renzo Cini and Alessandro Cavaglioni
pp 3751 - 3754; DOI:
10.1021/ic9900760
PDF

Issue 17


Mono-, Di-, Tri-, and Tetracarbonyls of Copper(I), Including the Structures of Cu(CO)2(1-Bn-CB11F11) and [Cu(CO)4][1-Et-CB11F11]
Svetlana M. Ivanova, Sergei V. Ivanov, Susie M. Miller, Oren P. Anderson, Konstantin A. Solntsev, and Steven H. Strauss
pp 3756 - 3757; DOI:
10.1021/ic990321f
PDF
Asymmetric Epoxidation of 1,2-Dihydronaphthalene Catalyzed by Manganese Chiroporphyrins: Stereoinduction Directed by Steric Exclusion
Céline Pérollier, Jacques Pécaut, René Ramasseul, and Jean-Claude Marchon
pp 3758 - 3759; DOI:
10.1021/ic990295l
PDF
Effect of Stepwise Oxidation on Molecular Structure in Osmium Hydrazido Complexes
My Hang V. Huynh, El-Sayed El-Samanody, Peter S. White, and Thomas J. Meyer
pp 3760 - 3761; DOI:
10.1021/ic990680a
PDF
Monomerization of a Rhenium(V) Dimer by Ligation
Josemon Jacob, Gábor Lente, Ilia A. Guzei, and James H. Espenson
pp 3762 - 3763; DOI:
10.1021/ic990370s
PDF
Bi- and Mononuclear Nickel(II) Trimethylacetate Complexes with Pyridine Bases as Ligands
Igor L. Eremenko, Sergei E. Nefedov, Aleksei A. Sidorov, Margarita A. Golubnichaya, Pavel V. Danilov, Vladimir N. Ikorskii, Yury G. Shvedenkov, Vladimir M. Novotortsev, and Ilya I. Moiseev
pp 3764 - 3773; DOI:
10.1021/ic981292w
PDF
Lanthanide Complexes of 3-Diphenylamino-4-hydroxycyclobut-3-ene-1,2-dione (Diphenylaminosquarate)
Bert D. Alleyne, Leonard St. Bernard, Hema Jaggernauth, Lincoln A. Hall, Ian Baxter, Andrew J. P. White, and David J. Williams
pp 3774 - 3778; DOI:
10.1021/ic990200f
PDF
Dehydrogenative Route to Metallo Dithiolenes: The Reaction of Zinc Polysulfides and Alkenes
Robert J. Pafford, Jun-Hong Chou, and Thomas B. Rauchfuss
pp 3779 - 3786; DOI:
10.1021/ic990090c
PDF
Quercetin 2,3-Dioxygenase Mimicking Ring Cleavage of the Flavonolate Ligand Assisted by Copper. Synthesis and Characterization of Copper(I) Complexes [Cu(PPh3)2(fla)] (fla = Flavonolate) and [Cu(PPh3)2(O-bs)] (O-bs = O-Benzoylsalicylate)
Éva Balogh-Hergovich, József Kaizer, Gábor Speier, Vilmos Fülöp, and László Párkányi
pp 3787 - 3795; DOI:
10.1021/ic990175d
PDF
Synthesis and Characterization of Dialkylmetal Boryloxides [(-9-BBN-9-O)MMe2]2, M = Al, Ga, In
Romana Anulewicz-Ostrowska, Sergiusz Luliski, and Janusz Serwatowski
pp 3796 - 3800; DOI:
10.1021/ic981454o
PDF
Synthesis, Crystal Structure, and Spectroscopic Characterization of a Series of Cubane-like Mo-Sb Clusters Containing a [Mo3SbOS3]7+ Core
Shao-Fang Lu, Jian-Quan Huang, Xiao-Ying Huang, Qiang-Jin Wu, and Rong-Min Yu
pp 3801 - 3805; DOI:
10.1021/ic971464+
PDF
Effect of Protonation and Zn(II) Coordination on the Fluorescence Emission of a Phenanthroline-Containing Macrocycle. An Unusual Case of "Nonemissive" Zn(II) Complex
Carla Bazzicalupi, Andrea Bencini, Antonio Bianchi, Claudia Giorgi, Vieri Fusi, Barbara Valtancoli, M. Alexandra Bernardo, and Fernando Pina
pp 3806 - 3813; DOI:
10.1021/ic981374k
PDF
Synthesis, Structure, and Reactivity of Zirconium and Hafnium Imido Metalloporphyrins
Joseph L. Thorman, Ilia A. Guzei, Victor G. Young, Jr., and L. Keith Woo
pp 3814 - 3824; DOI:
10.1021/ic981399j
PDF
-K4R6I14Os (R = La, Pr): A Novel Iodine-Rich Structure with a Layered Network of Electron-Poor Clusters. An Incipient Delocalized System with Metal-like Conductivity
S. Uma, James D. Martin, and John D. Corbett
pp 3825 - 3830; DOI:
10.1021/ic990638f
PDF
-K4La6I14Os: A New Structure Type for Rare-Earth-Metal Cluster Compounds That Contains Discrete Tetrahedral K4I3+ Units
S. Uma and John D. Corbett
pp 3831 - 3835; DOI:
10.1021/ic990072v
PDF
Electrochemical and Spectroscopic Studies on the Oxidation of the cis-(Et2-dcbpy)2RuX2 Series of Photovoltaic Sensitizer Precursor Complexes (Et2-dcbpy = 2,2'-Bipyridine-4,4'-diethoxydicarboxylic Acid, X = Cl-, I-, NCS-, CN-)
Georg Wolfbauer, Alan M. Bond, and Douglas R. MacFarlane
pp 3836 - 3846; DOI:
10.1021/ic990344u
PDF
Superexchange and Spin-Orbit Coupling in Chlorine-Bridged Binuclear Cobalt(II) Complexes
K. Fink, C. Wang, and V. Staemmler
pp 3847 - 3856; DOI:
10.1021/ic990280n
PDF
Electron Configuration of Ferric Ions in Low-Spin (Dicyano)(meso-tetraarylporphyrinato)iron(III) Complexes
Mikio Nakamura, Takahisa Ikeue, Akira Ikezaki, Yoshiki Ohgo, and Hiroshi Fujii
pp 3857 - 3862; DOI:
10.1021/ic990328x
PDF
Condensation of Pyramidal [AsSe3]3- Anions for the Construction of Polymeric Networks: Solventothermal Synthesis of K3AgAs2Se5·0.25MeOH, K2AgAs3Se6, and Rb2AgAs3Se6
M. Wachhold and M. G. Kanatzidis
pp 3863 - 3870; DOI:
10.1021/ic990274r
PDF
Synthesis and Characterization of Homo- and Heterodinuclear Complexes Containing the N3M(2-SR)3MN3 Core (M = Fe, Co, Ni)
Berthold Kersting, Dieter Siebert, Dirk Volkmer, Mario J. Kolm, and Christoph Janiak
pp 3871 - 3882; DOI:
10.1021/ic990087t
PDF
Formation of Isolated Nickel-Centered Gallium Clusters in Na10Ga10Ni and a 2-D Network of Gallium Octahedra in K2Ga3
Robert W. Henning and John D. Corbett
pp 3883 - 3888; DOI:
10.1021/ic990335l
PDF
Mixed Chloride/Phosphine Complexes of the Dirhenium Core. 6. Rare or Unprecedented Isomers of [Re2Cl6(PR3)2] Stoichiometry
F. Albert Cotton, Evgeny V. Dikarev, and Marina A. Petrukhina
pp 3889 - 3894; DOI:
10.1021/ic9906095
PDF
Fe(N2)n (n = 1-5): Structure, Bonding, and Vibrations from Density Functional Theory
Hélio A. Duarte, Dennis R. Salahub, Tom Haslett, and Martin Moskovits
pp 3895 - 3903; DOI:
10.1021/ic990066z
PDF
Reactions of DNA Purines with Dirhodium Formamidinate Compounds That Display Antitumor Behavior
K. V. Catalan, J. S. Hess, M. M. Maloney, D. J. Mindiola, D. L. Ward, and K. R. Dunbar
pp 3904 - 3913; DOI:
10.1021/ic990194n
PDF
Synthesis and Structures of Salen-Supported Borates Containing Siloxides
Pingrong Wei, Timothy Keizer, and David A. Atwood
pp 3914 - 3918; DOI:
10.1021/ic9812003
PDF
Oxygen Exchange on ReO4- and TcO4- by 17O-NMR
Silvia S. Jurisson and R. Kent Murmann
pp 3919 - 3921; DOI:
10.1021/ic9902830
PDF
Automated Solid-Phase DNA Synthesis and Photophysical Properties of Oligonucleotides Labeled at the 5'-Terminus with Ru(bpy)32+
Shoeb I. Khan, Amy E. Beilstein, Milan Sykora, Gregory D. Smith, Xi Hu, and Mark W. Grinstaff
pp 3922 - 3925; DOI:
10.1021/ic990177y
PDF
Bond Valence Sums in Coordination Chemistry. Sodium-Oxygen Complexes
Richard M. Wood and Gus J. Palenik
pp 3926 - 3930; DOI:
10.1021/ic9903331
PDF
A Density Functional Approach to the Jahn-Teller Effect of [Cu(en)3]2+ as a Model for a Macrobicyclic Cage Complex of Copper(II)
Tapan Kumar Kundu, Raf Bruyndonckx, Claude Daul, and Periakaruppan T. Manoharan
pp 3931 - 3934; DOI:
10.1021/ic981111q
PDF
A Room-Temperature Molten Salt Prepared from AuCl3 and 1-Ethyl-3-methylimidazolium Chloride
Eric R. Schreiter, Jonathan E. Stevens, Michael F. Ortwerth, and R. Griffith Freeman
pp 3935 - 3937; DOI:
10.1021/ic990062u
PDF
Mechanism of the Reaction between Iodate and Iodide Ions in Acid Solutions (Dushman Reaction)
Yi Xie, Michael R. McDonald, and Dale W. Margerum
pp 3938 - 3940; DOI:
10.1021/ic9807442
PDF
Novel Heterometallic Lanthanide Silsesquioxane
Judith Annand, Helen C. Aspinall, and Alexander Steiner
pp 3941 - 3943; DOI:
10.1021/ic990208p
PDF
Reaction of [Pd2Cl2(-dppm)2] with Arenesulfonyl Azides. Kinetics and Mechanism of Formation of Arenesulfonylimido-Bridged A-Frame Adducts
Isabella Foch, Gábor Besenyei, and László I. Simándi
pp 3944 - 3946; DOI:
10.1021/ic980937p
PDF
Dimerization of the Octaethylporphyrin Cation Radical Complex of Cobalt(II): Thermodynamic, Kinetic, and Spectroscopic Studies
Yaping Ni, Sin Lee, and Bradford B. Wayland
pp 3947 - 3949; DOI:
10.1021/ic9904034
PDF
Water-Soluble Organometallic Compounds. 7. Further Studies of 1,3,5-Triaza-7-Phosphaadamantane Derivatives of Group 10 Metals, Including Metal Carbonyls and Hydrides
Donald J. Darensbourg, Jeffrey B. Robertson, David L.Larkins, and Joseph H. Reibenspies
pp 3950 - 3950; DOI:
10.1021/ic9906813
PDF

Issue 18


The First Hydrogen Bonded Anionic Phosphates Exhibiting Sulfur Donor Coordination
A. Chandrasekaran, Paul Sood, Roberta O. Day, and Robert R. Holmes
pp 3952 - 3953; DOI:
10.1021/ic990486o
PDF
Effects of Multiple Covalent Attachments on Immobilized Iron(II)-1,10-Phenanthroline Complexes in Silica Sol-Gels
Grant M. Kloster, Colleen M. Taylor, and Stephen P. Watton
pp 3954 - 3955; DOI:
10.1021/ic990471q
PDF
Coordination Chemistry of the 2-Pyridyldiphosphine Ligands, (py)2P(CH(CH2)3CH)P(py)2 and (py)2P(CH2)2P(py)2 (py = 2-Pyridyl), with Platinum(II) and Ruthenium(II). Ruthenium-Catalyzed Hydrogenation of Imines
Nathan D. Jones, Kenneth S. MacFarlane, Martin B. Smith, Richard P. Schutte, Steven J. Rettig, and Brian R. James
pp 3956 - 3966; DOI:
10.1021/ic990002o
PDF
Manganese (II) Coordination Complexes Involving Nitronyl Nitroxide Radicals
Mohammed Fettouhi, Mazen Khaled, Abdel Waheed, Stéphane Golhen, Lahcène Ouahab, Jean-Pascal Sutter, and Olivier Kahn
pp 3967 - 3971; DOI:
10.1021/ic9905751
PDF
Halogenation of (CF3)3B·NH3: N,N-Dihaloamino- and Halo-tris(trifluoromethyl)borates [(CF3)3B-NX2]- and [(CF3)3B-X]-, X = F, Cl, Br
David J. Brauer, Hans Bürger, Yonas Chebude, and Gottfried Pawelke
pp 3972 - 3977; DOI:
10.1021/ic990352a
PDF
Crystal Engineering of Gold(I) Thiolate Based Compounds via Cooperative Aurophilic and Hydrogen-Bonding Interactions
Biing-Chiau Tzeng, Annette Schier, and Hubert Schmidbaur
pp 3978 - 3984; DOI:
10.1021/ic990308v
PDF
Soft Bending Modes of Terminal Chlorides in Gaseous Two- and Three-Coordinate Cu(II)-Cl Species
Beate K. Ystenes and Vidar R. Jensen
pp 3985 - 3993; DOI:
10.1021/ic990270m
PDF
Synthesis, Spectroscopic Studies, and Structural Studies of O,O-Alkylene Dithiophosphate and N,N-Dimethyl and Diethyl Dithiocarbamate Derivatives of Halodimethyltellurium(IV)
John E. Drake, Layla N. Khasrou, Anil G. Mislankar, and Raju Ratnani
pp 3994 - 4004; DOI:
10.1021/ic990281f
PDF
Division of the Effects of Cation Symmetry and Its Packing on the Mixed-Valence State of 1',1' ''-Bis(2-methylbutyl)-1,1' '-biferrocenium Triiodide Having Asymmetric Carbon in the Substituent
Satoru Nakashima, Takashi Oda, Tsutomu Okuda, and Masanobu Watanabe
pp 4005 - 4010; DOI:
10.1021/ic990269n
PDF
Relationship among Redox Potentials, Proton Dissociation Constants of Pyrrolic Nitrogens, and in Vivo and in Vitro Superoxide Dismutating Activities of Manganese(III) and Iron(III) Water-Soluble Porphyrins
Ines Batini-Haberle, Ivan Spasojevi, Peter Hambright, Ludmil Benov, Alvin L. Crumbliss, and Irwin Fridovich
pp 4011 - 4022; DOI:
10.1021/ic990118k
PDF
Reevaluation of the Gas-Phase Valence Photoelectron Spectra of Octaethylporphyrin and Tetraphenylporphyrin
Nadine E. Gruhn, Dennis L. Lichtenberger, Hiroshi Ogura, and F. Ann Walker
pp 4023 - 4027; DOI:
10.1021/ic990279o
PDF
Protection of Proton-Initiated Ligand Dissociation from Hg(II) Complexes with Bulky Cholyl Amide Arenethiolate by NH···S Hydrogen Bonding in an Aqueous Micellar Solution
Norikazu Ueyama, Masahiro Inohara, Akira Onoda, Takafumi Ueno, Taka-aki Okamura, and Akira Nakamura
pp 4028 - 4031; DOI:
10.1021/ic9811042
PDF
Electron-Rich Nitrido-Bridged Complexes. Structure and Bonding in Triosmium Dinitrido Compounds
Claire Newton, Kimberly D. Edwards, Joseph W. Ziller, and Nancy M. Doherty
pp 4032 - 4037; DOI:
10.1021/ic981257p
PDF
(-Phenoxo)2CoIIMII (M = Mn, Co, Zn) Complexes with a Co(salen) Entity in a Macrocyclic Framework: Core Structures and Neighboring MII Effects upon Oxygenation at the Co(salen) Center
Satoru Kita, Hideki Furutachi, and Hisashi kawa
pp 4038 - 4045; DOI:
10.1021/ic9809456
PDF
Probing d8-d8 Interactions in Luminescent Mono- and Binuclear Cyclometalated Platinum(II) Complexes of 6-Phenyl-2,2'-bipyridines
Siu-Wai Lai, Michael Chi-Wang Chan, Tsz-Chun Cheung, Shie-Ming Peng, and Chi-Ming Che
pp 4046 - 4055; DOI:
10.1021/ic990238s
PDF
Chemistry of Heterobifunctional Diazaphospholylphosphines. 4. Complexation and Reduction Reactions of Platinum(II) and Palladium(II) with Phosphine-Substituted (Fluoro, Dimethylamino, Trifluoroethoxy) 4-Phosphino-2,5-dimethyl-2H-1,2,32-diazaphospholes. Structure of a Novel Platinum(0) Tetrakis(difluorophosphine) Complex
Michael D. Mikoluk, Robert McDonald, and Ronald G. Cavell
pp 4056 - 4063; DOI:
10.1021/ic980622+
PDF
Kinetics and Mechanism of the Complexation of La3+ and Cu2+ Ions with N-Methylacetohydroxamic Acid and Desferrioxamine B
Mladen Biru, Mario Gabrievi, Olga Kronja, Branimir Klai, Rudi van Eldik, and Achim Zahl
pp 4064 - 4069; DOI:
10.1021/ic990107r
PDF
Syntheses and Properties of a Series of Oxo-Centered Triruthenium Complexes and Their Bridged Dimers with Isocyanide Ligands at Terminal and Bridging Positions
Ken-ichiro Ota, Hirokazu Sasaki, Taeko Matsui, Tomohiko Hamaguchi, Tadashi Yamaguchi, Tasuku Ito, Hiroaki Kido, and Clifford P. Kubiak
pp 4070 - 4078; DOI:
10.1021/ic990234n
PDF
Synthesis and Characterization of O,N-Chelated Vanadium(IV) Oxo Phenolate Complexes: Electronic Effect of Meta and Para Substituents on the Vanadium Center
Henk Hagen, Antonio Barbon, Ernst E. van Faassen, Bert T. G. Lutz, Jaap Boersma, Anthony L. Spek, and Gerard van Koten
pp 4079 - 4086; DOI:
10.1021/ic9901564
PDF
Crystal Chemistry of Cobalamins. Structural Characterization of the Co-S Bond in Cobalamins
Lucio Randaccio, Silvano Geremia, Giorgio Nardin, Miroslav louf, and Ivana Srnova
pp 4087 - 4092; DOI:
10.1021/ic9903376
PDF
Syntheses of THF Solutions of SeX2 (X = Cl, Br) and a New Route to Selenium Sulfides SenS8-n (n = 1-5): X-ray Crystal Structures of SeCl2(tht)2 and SeCl2·tmtu
Arto Maaninen, Tristram Chivers, Masood Parvez, Jarkko Pietikäinen, and Risto S. Laitinen
pp 4093 - 4097; DOI:
10.1021/ic981430h
PDF
Structural and Spectroscopic Comparisons between (-Oxo)- and (-Hydroxo)bis(-carboxylato)diiron(III) Complexes That Contain All-Oxygen-Donor Ligands
Tadashi J. Mizoguchi, Roman M. Davydov, and Stephen J. Lippard
pp 4098 - 4103; DOI:
10.1021/ic990303y
PDF
The Unperturbed Oxo-Sulfido Functional Group cis-MoVIOS Related to That in the Xanthine Oxidase Family of Molybdoenzymes: Synthesis, Structural Characterization, and Reactivity Aspects
Anders Thapper, James P. Donahue, Kristin B. Musgrave, Michael W. Willer, Ebbe Nordlander, Britt Hedman, Keith O. Hodgson, and R. H. Holm
pp 4104 - 4114; DOI:
10.1021/ic990440v
PDF
Carboxy and Diphosphate Ester Hydrolysis by a Dizinc Complex with a New Alcohol-Pendant Macrocycle
Carla Bazzicalupi, Andrea Bencini, Emanuela Berni, Antonio Bianchi, Valentina Fedi, Vieri Fusi, Claudia Giorgi, Piero Paoletti, and Barbara Valtancoli
pp 4115 - 4122; DOI:
10.1021/ic9902929
PDF
Hydroxylation, Epoxidation, and DNA Cleavage Reactions Mediated by the Biomimetic Mn-TMPyP/O2/Sulfite Oxidation System
Karine Wietzerbin, James G. Muller, Rachel A. Jameton, Geneviève Pratviel, Jean Bernadou, Bernard Meunier, and Cynthia J. Burrows
pp 4123 - 4127; DOI:
10.1021/ic990537h
PDF
Titanium(III)-Ruthenium(III) Electron Transfer through 3,6-Dihydroxy-1,4-benzoquinonate Ligands: an Ultra-short Insulated Wire
Edward A. Robinson and Joseph E. Earley
pp 4128 - 4131; DOI:
10.1021/ic9901158
PDF
Theoretical Study of SiH2n2+ (n = 1-3) Dications
Golam Rasul, G. K. Surya Prakash, and George A. Olah
pp 4132 - 4134; DOI:
10.1021/ic9901620
PDF
Thermodynamic and Activation Parameters for Dissociation of [CpCr(CO)3]2 and [Cp*Cr(CO)3]2 into Paramagnetic Monomers from 1H NMR Shift and Line Width Measurements
David C. Woska, Yaping Ni, and Bradford B. Wayland
pp 4135 - 4138; DOI:
10.1021/ic990342+
PDF
First Investigation on the L Edges of the 249Cf Aquo Ion by X-ray Absorption Spectroscopy
R. Revel, C. Den Auwer, C. Madic, F. David, B. Fourest, S. Hubert, J.-F. Le Du, and L. R. Morss
pp 4139 - 4141; DOI:
10.1021/ic990214l
PDF
Crystalline Inclusion Compounds of Urea with Oxoboron Components. Stabilization of the Elusive Dihydrogen Borate Anion in a Hydrogen-Bonded Host Lattice
Qi Li, Feng Xue, and Thomas C. W. Mak
pp 4142 - 4145; DOI:
10.1021/ic971527o
PDF
Enhanced Kinetic Lability of Ru(III) Centers in Oxo-Centered Mixed-Metal Ru2M Trinuclear Complexes (M = Zn and Mg)
Masaaki Abe, Maiko Tanaka, Keisuke Umakoshi, and Yoichi Sasaki
pp 4146 - 4148; DOI:
10.1021/ic990047p
PDF
Photochemically Generated Organometallic Molecular Square Complexes
Helen A. Cruse and Nicholas E. Leadbeater
pp 4149 - 4151; DOI:
10.1021/ic981455g
PDF
Synthesis and X-ray Crystal Structure of [CuIN(R2PS)2]3
David J. Birdsall, Alexandra M. Z. Slawin, and J. Derek Woollins
pp 4152 - 4155; DOI:
10.1021/ic990276b
PDF
Synthesis and Crystal Structure of UO2Cl2(THF)3: A Simple Preparation of an Anhydrous Uranyl Reagent
Marianne P. Wilkerson, Carol J. Burns, Robert T. Paine, and Brian L. Scott
pp 4156 - 4158; DOI:
10.1021/ic990159g
PDF
[Ta6Cl12(PrCN)6][(Ta6Cl12)Cl6]·2PrCN, A Compound with Homonuclear Mixed-Charge Cluster Units [Ta6Cl12]2+ and [Ta6Cl12]4+
Nevenka Brnievi, Sinia irac, Ivan Baic, Zhihong Zhang, Robert E. McCarley, and Ilia A. Guzei
pp 4159 - 4162; DOI:
10.1021/ic9903073
PDF
Neutral Pentacoordinate and Hexacoordinate Germanium(IV) Complexes: Valence Expansion At Gemanium By Transannular Bonding Of Selenium in an Eight-Membered Ring
Thomas Thompson, Stephen D. Pastor, and Grety Rihs
pp 4163 - 4167; DOI:
10.1021/ic990460x
PDF
Dehydrohalogenation as a Source of OsHnCl(PPh3)3 (n = 1, 3)
German Ferrando and Kenneth G. Caulton
pp 4168 - 4170; DOI:
10.1021/ic981402z
PDF
Anionic Iridium Monohydrides
Robert D. Simpson, William J. Marshall, Amy A. Farischon, D. Christopher Roe, and Vladimir V. Grushin
pp 4171 - 4173; DOI:
10.1021/ic990068j
PDF
Preparation and Some Properties of a Phosphorus(V) Complex of Tetra-tert-butylphthalocyanine
Kuninobu Kasuga, Liang Lin, Makoto Handa, Tamotsu Sugimori, Kimio Isa, Kenji Matsuura, and Yoshiko Takinami
pp 4174 - 4176; DOI:
10.1021/ic980812k
PDF
Small Molecule-Induced Intramolecular Electron "Pitch and Catch" in a RhodiumI Complex with Substitutionally Inert Redox-Active Ligands.
Igor V. Kourkine, Caroline S. Slone, Chad A. Mirkin, Louise M. Liable-Sands, and Arnold L. Rheingold:
pp 4176 - 4176; DOI:
10.1021/ic990704d
PDF
Volume Profile for Substitution in Labile Chromium(III) Complexes: Reactions of Aqueous [Cr(Hedta)OH2] and [Cr(edta)]- with Thiocyanate Ion
Colin L. Beswick, Richard D. Shalders, and Thomas W.Swaddle
pp 4176 - 4176; DOI:
10.1021/ic9907260
PDF

Issue 19


RbAg2As3Se6: A Unique Three-Dimensional Silver-Selenoarsenate Framework %@mt;sys@% %@mh;-%pxwidth@%%@sx@%%@be@%3%@sxx@%%@mx@% [Ag2As3Se6]-, Assembled from [As3Se6]3- Rings and "Ag22+" Dumbbell Units
Michael Wachhold and Mercouri G. Kanatzidis
pp 4178 - 4180; DOI:
10.1021/ic9905392
PDF
New Self-Assembly Luminescent Molecular Triangle and Square Rhenium(I) Complexes
Shih-Sheng Sun and Alistair J. Lees
pp 4181 - 4182; DOI:
10.1021/ic990129d
PDF
Synthesis and Structural Characterization of the First Organically Templated Vanadyl(IV) Arsenato- and Phosphato-oxalates: (C4H12N2)[VO(C2O4)HXO4] (X = As, P)
Yu-Min Tsai, Sue-Lein Wang, Ching-Hui Huang, and Kwang-Hwa Lii
pp 4183 - 4187; DOI:
10.1021/ic990501p
PDF
Metal Tetrahydridoborates and Tetrahydridoborato Metalates. 23.1 Amine Solvates of Lithium and Sodium Tetrahydridoborate
Hans-Hermann Giese, Tassilo Habereder, Heinrich Nöth, Werner Ponikwar, Steffen Thomas, and Marcus Warchhold
pp 4188 - 4196; DOI:
10.1021/ic990205c
PDF
Novel Six-Coordinate Oxorhenium "3 + 2" Mixed-Ligand Complexes Carrying the SNS/PO Donor Atom Set: Synthesis and Characterization
Berthold Nock, Theodosia Maina, Francesco Tisato, Minas Papadopoulos, Catherine P. Raptopoulou, Aris Terzis, and Efstratios Chiotellis
pp 4197 - 4202; DOI:
10.1021/ic9905796
PDF
Conjugated Polyrotaxanes Incorporating Mono- or Divalent Copper Complexes
Pierre-Louis Vidal, Bernadette Divisia-Blohorn, Gérard Bidan, Jean-Marc Kern, Jean-Pierre Sauvage, and Jean-Louis Hazemann
pp 4203 - 4210; DOI:
10.1021/ic990516n
PDF
Effects of Zinc on the New Preparation Method of Hydroxy Double Salts
Hiroyuki Morioka, Hideyuki Tagaya, Masa Karasu, Jun-ichi Kadokawa, and Koji Chiba
pp 4211 - 4216; DOI:
10.1021/ic9812149
PDF
Hydrothermal Syntheses: A Route to the Stepwise Condensation of Reduced Keggin Polyanions. From Reduced -[HmSiMo12O40]n- Monomers to Bicapped Dimerized [Si2Mo28O84(H2O)2]6- Anions
Anne Dolbecq, Emmanuel Cadot, Dirk Eisner, and Francis Sécheresse
pp 4217 - 4223; DOI:
10.1021/ic990420t
PDF
Spherical and Aspherical Intermolecular Force Fields for Sulfur Allotropes
Aron Abraha and Donald E. Williams
pp 4224 - 4228; DOI:
10.1021/ic990573g
PDF
Structural and Magnetic Properties of Cu[C(CN)3]2 and Mn[C(CN)3]2
H. Hoshino, K. Iida, T. Kawamoto, and T. Mori
pp 4229 - 4232; DOI:
10.1021/ic990336d
PDF
Influence of Coordination Geometry upon Copper(II/I) Redox Potentials. Physical Parameters for Twelve Copper Tripodal Ligand Complexes
Edna A. Ambundo, Marie-Veronique Deydier, Andrew J. Grall, Natalia Aguera-Vega, Luke T. Dressel, Thomas H. Cooper, Mary Jane Heeg, L. A. Ochrymowycz, and D. B. Rorabacher
pp 4233 - 4242; DOI:
10.1021/ic990334t
PDF
Synthesis of a New Mesostructured Lamellar Oxovanadium Phosphate Assembled through an S+X-I0 Mechanism
Jamal El Haskouri, Saúl Cabrera, Manuel Roca, Jaime Alamo, Aurelio Beltrán-Porter, Daniel Beltrán-Porter, M. Dolores Marcos, and Pedro Amorós
pp 4243 - 4248; DOI:
10.1021/ic9902931
PDF
Derivation of Force Field Parameters, and Force Field and Quantum Mechanical Studies of Layered - and -Zirconium Phosphates
Giulio Alberti, Antonio Grassi, Giuseppe M. Lombardo, Giuseppe C. Pappalardo, and Riccardo Vivani
pp 4249 - 4255; DOI:
10.1021/ic9903937
PDF
Effects of Temperature and Pressure on the Mössbauer Spectra of Models for the [4Fe-4S]2+ Clusters of Iron-Sulfur Proteins and the Structure of [PPh4]2[Fe4S4(SCH2CO2C2H5)4]
Jack Silver, George R. Fern, John R. Miller, Catherine A. McCammon, David J. Evans, and G. Jeffery Leigh
pp 4256 - 4261; DOI:
10.1021/ic980157g
PDF
Spectroscopic Properties of Luminescent Platinum(II) Complexes Containing 4,4',4' '-Tri-tert-butyl-2,2':6',2' '-terpyridine (tBu3tpy). Crystal Structures of [Pt(tBu3tpy)Cl]ClO4 and [Pt(tBu3tpy){CH2C(O)Me}]ClO4
Siu-Wai Lai, Michael C. W. Chan, Kung-Kai Cheung, and Chi-Ming Che
pp 4262 - 4267; DOI:
10.1021/ic990446k
PDF
Variable-Temperature Emission Studies of Solvation Dynamics: Evidence for Coupling of Solvation to Chromophore Structural Dynamics in the Evolution of Charge-Transfer Excited States
Niels H. Damrauer and James K. McCusker
pp 4268 - 4277; DOI:
10.1021/ic990703l
PDF
Rhenium(V) Dioxo Complexes with Dihydrobis(pyrazolyl)borates: Synthesis and Reactivity toward Electrophilic Substrates
K. Rajender Reddy, Ângela Domingos, António Paulo, and Isabel Santos
pp 4278 - 4282; DOI:
10.1021/ic990229j
PDF
Carbon-13 and Oxygen-17 Chemical Shifts, (16O/18O) Isotope Effects on 13C Chemical Shifts, and Vibrational Frequencies of Carbon Monoxide in Various Solvents and of the Fe-C-O Unit in Carbonmonoxy Heme Proteins and Synthetic Model Compounds
Charalampos G. Kalodimos, Ioannis P. Gerothanassis, Roberta Pierattelli, and Bernard Ancian
pp 4283 - 4293; DOI:
10.1021/ic9814165
PDF
Molecular Structures and Magnetochemistry of Two (-Oxooctaethylchlorinato)copper(II) Derivatives: [Cu(oxoOEC)] and [Cu(oxoOEC)]SbCl6
Teresa J. Neal, Seong-Joo Kang, Charles E. Schulz, and W. Robert Scheidt
pp 4294 - 4302; DOI:
10.1021/ic9903026
PDF
Vanadium(V) Complexes of 2,2'-Thiobis(4-methyl-6-tert-butylphenol) (H2mbp2S) and 2,2'-Sulfinylbis(4-methyl-6-tert-butylphenol) (H2mbp2SO)
Charles R. Cornman, Katherine M. Geiser-Bush, and Jeff W. Kampf
pp 4303 - 4308; DOI:
10.1021/ic9900253
PDF
Mechanistic Investigation on the Water Substitution in the 5-Organometallic Complexes Cp*Ir(H2O)32+ and Cp*Rh(H2O)32+
Sonia Cayemittes, Tilo Poth, Maria J. Fernandez, Peter G. Lye, Michael Becker, Horst Elias, and André E. Merbach
pp 4309 - 4316; DOI:
10.1021/ic990364w
PDF
The Yield of Hydroxyl Radical from the Decomposition of Peroxynitrous Acid
Oleg V. Gerasimov and Sergei V. Lymar
pp 4317 - 4321; DOI:
10.1021/ic990384y
PDF
A Structural Strategy for Generating Rapid Electron-Transfer Kinetics in Copper(II/I) Systems
Ksenia Krylova, Chandrika P. Kulatilleke, Mary Jane Heeg, Cynthia A. Salhi, L. A. Ochrymowycz, and D. B. Rorabacher
pp 4322 - 4328; DOI:
10.1021/ic990365o
PDF
A New Method for Incorporating Thiolate Donors into a Metal Coordination Sphere. Synthesis and Crystal Structures of the First Nickel Complexes of an N3S Ligand
Niranjan Goswami and David M. Eichhorn
pp 4329 - 4333; DOI:
10.1021/ic990492k
PDF
Syntheses of Metal Dithiolene Complexes from Thiometalates by Induced Internal Redox Reactions
Kun Wang, Jonathan M. McConnachie, and Edward I. Stiefel
pp 4334 - 4341; DOI:
10.1021/ic990204k
PDF
Highly Restricted Dimensionality in Cesium Aryl Phosphides
Gerd W. Rabe, Louise M. Liable-Sands, Christopher D. Incarvito, Kin-Chung Lam, and Arnold L. Rheingold
pp 4342 - 4346; DOI:
10.1021/ic9902119
PDF
Entrapment of Lithium Salts by the Lithium Amidinate Li[(nBu)C(NtBu)2]
Tristram Chivers, Andrew Downard, and Masood Parvez
pp 4347 - 4353; DOI:
10.1021/ic990757v
PDF
Synthesis, Structure, and Chemical Vapor Deposition Studies of Molecular Precursors to NbP Films
Joseph T. Scheper, Kumudini C. Jayaratne, Louise M. Liable-Sands, Glenn P. A. Yap, Arnold L. Rheingold, and Charles H. Winter
pp 4354 - 4360; DOI:
10.1021/ic990198s
PDF
A Sterically Enforced Bent Form of an Edge-Sharing Dipalladium(II) Complex Attained by a Linked-Bisphosphido Bridge
Tsutomu Mizuta, Shizuka Aoki, Koji Nakayama, and Katsuhiko Miyoshi
pp 4361 - 4364; DOI:
10.1021/ic990032r
PDF
Tris 1-Nitroso-2-naphtholate Complex of Ruthenium(II): An Efficient Building Unit for Polynuclear Complexes
Anjan Kumar Das, Angel Rueda, Larry R. Falvello, Shie-Ming Peng, and Samaresh Bhattacharya
pp 4365 - 4368; DOI:
10.1021/ic990191a
PDF
Basicity of Coordinated Pyrazine and Bonding Interactions with [MII(CN)5]3- Fragments (M = Fe, Ru, Os)
Leonardo D. Slep, Sergio Pollak, and José A. Olabe
pp 4369 - 4371; DOI:
10.1021/ic990250k
PDF
New Robust Bleomycin Analogues: Synthesis, Spectroscopy, and Crystal Structures of the Copper(II) Complexes.
Hiromasa Kurosaki, Kentarou Hayashi, YoshinobuIshikawa, Masafumi Goto, Kazufumi Inada, IsaoTaniguchi, Mitsuhiko Shionoya, and Eiichi Kimura:
pp 4372 - 4372; DOI:
10.1021/ic990898x
PDF
Technetium Complexes of a Hydrazinonicotinamide-Conjugated Cyclic Peptide and 2-Hydrazinopyridine: Synthesis and Characteri-zation.
Shuang Liu, D. Scott Edwards, Anthony R. Harris, Stuart J. Heminway, and John A. Barrett:
pp 4372 - 4372; DOI:
10.1021/ic9909328
PDF

Issue 20


Synthesis and Properties of a Molecular Dumbbell with Bis-4-oxo Copper(II/I) Hepta Metal Centers
Mi Young Han, Kil Sik Min, and Myunghyun Paik Suh
pp 4374 - 4375; DOI:
10.1021/ic990555z
PDF
Synthesis, Structure, and Catecholase Reaction of a Vanadate Ester System Incorporating Monoionized Catechol Chelation
Sankar Prasad Rath, Kajal Krishna Rajak, and Animesh Chakravorty
pp 4376 - 4377; DOI:
10.1021/ic990551u
PDF
Terminal-to-Interior Energy Transfer in a "Linear" Oligomeric Diphosphine-Bridged Complex of Re(I)
Stephen M. Woessner, Jeffrey B. Helms, K. M. Lantzky, and B. Patrick Sullivan
pp 4378 - 4379; DOI:
10.1021/ic981280a
PDF
Luminescent Squares and Rings Based on Metal-to-Ligand Charge Transfer Excited States
Stephen M. Woessner, Jeffrey B. Helms, James F. Houlis, and B. Patrick Sullivan
pp 4380 - 4381; DOI:
10.1021/ic9812813
PDF
Light-Harvesting Arrays with Coumarin Donors and MLCT Acceptors
Daniel S. Tyson and Felix N. Castellano
pp 4382 - 4383; DOI:
10.1021/ic9905300
PDF
A Model for Ferricyanide-Inhibited Sulfite Oxidase
Matthew E. Helton and Martin L. Kirk
pp 4384 - 4385; DOI:
10.1021/ic990291g
PDF
Visible Region Photooxidation on TiO2 with a Chromophore-Catalyst Molecular Assembly
Joseph A. Treadway, John A. Moss, and Thomas J. Meyer
pp 4386 - 4387; DOI:
10.1021/ic990466m
PDF
Cooperative Substituent Effects on the Excited States of Copper Phenanthrolines
Corey T. Cunningham, Kurstan L. H. Cunningham, Joseph F. Michalec, and David R. McMillin
pp 4388 - 4392; DOI:
10.1021/ic9906611
PDF
Synthesis, Structure, Magnetic Properties, and 1H NMR Studies of a Moderately Antiferromagnetically Coupled Binuclear Copper(II) Complex
Anbanandam Asokan, Babu Varghese, and Periakaruppan T. Manoharan
pp 4393 - 4399; DOI:
10.1021/ic9813617
PDF
(THF)8Ln8E6(EPh)12 Cluster Reactivity: Systematic Control of Ln, E, EPh, and Neutral Donor Ligands
Deborah Freedman, Thomas J. Emge, and John G. Brennan
pp 4400 - 4404; DOI:
10.1021/ic9905493
PDF
Photoinduced Long-Range Magnetic Ordering of a Cobalt-Iron Cyanide
O. Sato, Y. Einaga, A. Fujishima, and K. Hashimoto
pp 4405 - 4412; DOI:
10.1021/ic980741p
PDF
Crystal Structures and Magnetic Properties of CuX2(pdmp)2 Complexes (X = Br, Cl)
Antonio J. Costa-Filho, Claudia E. Munte, Claudio Barberato, Eduardo E. Castellano, M. P. D. Mattioli, Rafael Calvo, and Otaciro R. Nascimento
pp 4413 - 4421; DOI:
10.1021/ic990245g
PDF
Synthesis, Structural Evolution, and Theoretical and Physical Studies of the Novel Compounds M2Mo9S11 (M = K, Rb) and Related Metastable Materials CuxK1.8Mo9S11 (x = 0 or 2) Containing Bioctahedral Mo9 Clusters
Soazig Picard, Jean-François Halet, Patrick Gougeon, and Michel Potel
pp 4422 - 4429; DOI:
10.1021/ic990362b
PDF
Magnetic Behavior and Crystal Structure of [Fe(cyclam)(NCS)2](TCNQ)2: An Unusual One-Dimensional (TCNQ)2- Radical-Ion System
Loreto Ballester, Angel Gutiérrez, M. Felisa Perpiñán, Susana Rico, M. Teresa Azcondo, and Carlo Bellitto
pp 4430 - 4434; DOI:
10.1021/ic990217y
PDF
Crystallographic Characterization of Stepwise Changes in Ligand Conformations as Their Internal Topology Changes and Two Novel Cross-Bridged Tetraazamacrocyclic Copper(II) Complexes
Timothy J. Hubin, James M. McCormick, Nathaniel W. Alcock, Howard J. Clase, and Daryle H. Busch
pp 4435 - 4446; DOI:
10.1021/ic990491s
PDF
Indium Fluoroalkoxide Compounds
Liliana A. Mîinea, Seigi Suh, and David M. Hoffman
pp 4447 - 4454; DOI:
10.1021/ic990315j
PDF
Synthesis, Physical Properties, and Theoretical Study of R16Mo21O56 Compounds (R = La, Ce, Pr, and Nd) Containing Bioctahedral Mo10 Clusters and Single Mo Atoms
Philippe Gall, Régis Gautier, Jean-François Halet, and Patrick Gougeon
pp 4455 - 4461; DOI:
10.1021/ic981234a
PDF
Synthesis, Structural Characterization, and MO Calculations of Vanadium Imido Complexes Containing Bidentate Phosphine Coligands
Francisco Montilla, Angeles Monge, Enrique Gutiérrez-Puebla, Antonio Pastor, Diego del Río, Norge Cruz Hernández, Javier Fernández Sanz, and Agustín Galindo
pp 4462 - 4466; DOI:
10.1021/ic9900152
PDF
The Reaction of LiAlH4 with 1,4-Di-tert-butyl-1,4-diazabutadiene: Imine-Containing Aluminum Hydrides Stabilized by Lithium Coordination
Michael G. Gardiner, Stacey M. Lawrence, and Colin L. Raston
pp 4467 - 4472; DOI:
10.1021/ic990298y
PDF
Synthesis of a Novel Class of Trigonal Bipyramidal Nitrido Tc(V) Complexes with Phosphino-Thiol Ligands. Crystal Structure of [99gTc(N)(L1)2] [L1 = 2-(Diphenylphosphino)ethanethiolato] and [99gTc(N)(L5)2] [L5 = 2-(Ditolylphosphino)propanethiolato]
Cristina Bolzati, Alessandra Boschi, Licia Uccelli, Erica Malagò, Giuliano Bandoli, Francesco Tisato, Fiorenzo Refosco, Roberto Pasqualini, and Adriano Duatti
pp 4473 - 4479; DOI:
10.1021/ic9903477
PDF
Solid-State Coordination Chemistry of Metal Oxides: Hydrothermal Synthesis and Structural Characterization of o-Phenanthroline-Ligated Copper- and Zinc-Molybdenum Oxides
Pamela J. Hagrman and Jon Zubieta
pp 4480 - 4485; DOI:
10.1021/ic990340p
PDF
DNA Binding of Ruthenium Tris(1,10-phenanthroline): Evidence for the Dependence of Binding Mode on Metal Complex Concentration
Delia Z. M. Coggan, Ian S. Haworth, Paula J. Bates, Alan Robinson, and Alison Rodger
pp 4486 - 4497; DOI:
10.1021/ic990654c
PDF
NMR Study of Dendrimer Structures Using Paramagnetic Cobalt(II) as a Probe
Jon D. Epperson, Li-June Ming, Barry D. Woosley, Gregory R. Baker, and George R. Newkome
pp 4498 - 4502; DOI:
10.1021/ic9906860
PDF
A New Rare-Earth Indium Antimonide, (RE)In1-xSb2 (RE = La-Nd), Featuring In Zigzag Chains and Sb Square Nets
Michael J. Ferguson, Robert E. Ellenwood, and Arthur Mar
pp 4503 - 4509; DOI:
10.1021/ic9905244
PDF
Synthesis, Characterization, and Reactivity of Palladium(II) Salen and Oxazoline Complexes
Kimberly J. Miller, Jun Ho Baag, and Mahdi M. Abu-Omar
pp 4510 - 4514; DOI:
10.1021/ic981450j
PDF
Oxidations of (R3tach)M(CO)3 Complexes [M = Cr, Mo, W; R3tach = 1,3,5-Trialkyl-1,3,5-triazacyclohexane (R = t-Bu, Bn)]. Crystal Structures of (t-Bu3tach)MO3·15H2O (M = Mo, W)
Murray V. Baker, Michael R. North, Brian W. Skelton, and Allan H. White
pp 4515 - 4521; DOI:
10.1021/ic990031z
PDF
A Novel Salicylate-Based Macrobicycle with a "Split Personality"
Seth M. Cohen, Stéphane Petoud, and Kenneth N. Raymond
pp 4522 - 4529; DOI:
10.1021/ic990411k
PDF
Chemical Transport Synthesis, Electrochemical Behavior, and Electronic Structure of Superconducting Zirconium and Hafnium Nitride Halides
Mikhail Vlassov, M. Rosa Palacín, Daniel Beltrán-Porter, Judith Oró-Solé, Enric Canadell, Pere Alemany, and Amparo Fuertes
pp 4530 - 4538; DOI:
10.1021/ic9903127
PDF
Synthesis, Structure, and Molecular Orbital Studies of Yttrium, Erbium, and Lutetium Complexes Bearing 2-Pyrazolato Ligands: Development of a New Class of Precursors for Doping Semiconductors
Dirk Pfeiffer, Bhekumusa J. Ximba, Louise M. Liable-Sands, Arnold L. Rheingold, Mary Jane Heeg, David M. Coleman, H. Bernhard Schlegel, Thomas F. Kuech, and Charles H. Winter
pp 4539 - 4548; DOI:
10.1021/ic990319o
PDF
Synthesis of Bis{(2-dimethylphosphino)ethane-1-thiolato}bis(tert-butylthiolato)- molybdenum(IV) and Its Cluster-Forming Reactions with FeCl2 and CuBr
Yasuhiro Arikawa, Hiroyuki Kawaguchi, Kazuo Kashiwabara, and Kazuyuki Tatsumi
pp 4549 - 4553; DOI:
10.1021/ic990435r
PDF
Two Novel Lithium-15-Crown-5 Complexes: An Extended LiCl Chain Stabilized by Crown Ether and a Dimeric Complex Stabilized by Hydrogen Bonding with Water
Roman Boulatov, Bin Du, Edward A. Meyers, and Sheldon G. Shore
pp 4554 - 4558; DOI:
10.1021/ic9904790
PDF
Coordination and Conversion of Urea at Dinuclear -Acetato Nickel(II) Complexes with Symmetric and Asymmetric Cores
Matthias Konrad, Franc Meyer, Albrecht Jacobi, Peter Kircher, Peter Rutsch, and Laszlo Zsolnai
pp 4559 - 4566; DOI:
10.1021/ic990137u
PDF
Chemical Twinning in Zintl Phases
Fabio Zürcher, Steffen Wengert, and Reinhard Nesper
pp 4567 - 4569; DOI:
10.1021/ic990147v
PDF
Disproportionation of Ag(II) to Ag(I) and Ag(III) in Fluoride Systems and Syntheses and Structures of (AgF+)2AgF4-MF6- Salts (M = As, Sb, Pt, Au, Ru)
Ciping Shen, Boris emva, George M. Lucier, Oliver Graudejus, John A. Allman, and Neil Bartlett
pp 4570 - 4577; DOI:
10.1021/ic9905603
PDF
Synthesis and Characterization of Thiolate-Thiol Complexes of Ruthenium Nitrosyl Porphyrins and Their Symmetrical and Unsymmetrical Dithiolate-Bridged Bimetallic Derivatives
Jonghyuk Lee, Geun-Bae Yi, Masood A. Khan, and George B. Richter-Addo
pp 4578 - 4584; DOI:
10.1021/ic990402b
PDF
Coordination of Lanthanide Nitrates with N,N,N',N'-Tetramethylsuccinamide
Brian M. Rapko, Bruce K. McNamara, Robin D. Rogers, Gregg J. Lumetta, and Benjamin P. Hay
pp 4585 - 4592; DOI:
10.1021/ic990535x
PDF
Synthesis and Characterization of Pseudotetrahedral N2O and N2S Zinc(II) Complexes of Two Heteroscorpionate Ligands: Models for the Binding Sites of Several Zinc Metalloproteins
Brian S. Hammes and Carl J. Carrano
pp 4593 - 4600; DOI:
10.1021/ic990233v
PDF
Solvothermal Synthesis, Crystal Structure, and Characterization of an Oxothiomolybdate, [N(CH3)4]4Mo6O6S14, Exhibiting a New Mo6O6S14 Core
Jan Ellermeier, Christian Näther, and Wolfgang Bensch
pp 4601 - 4604; DOI:
10.1021/ic990021y
PDF
Photophysical Features of the M2(CO)10, M = Mn and Re, Solution Photochemistry
M. Sarakha and G. Ferraudi
pp 4605 - 4607; DOI:
10.1021/ic990133p
PDF
Cu-X-bpy (X = Cl, Br; bpy = 4,4'-bipyridine) Coordination Polymers: The Stoichiometric Control and Structural Relations of %@mt;sys@% %@mh;-%pxwidth@%%@sx@%%@be@%2%@sxx@%%@mx@% [Cu2X2(bpy)] and %@mt;sys@%%@sx@%%@be@%3%@sxx@%%@mx@% [CuBr(bpy)]
Jack Y. Lu, Brenda R. Cabrera, Ru-Ji Wang, and Jing Li
pp 4608 - 4611; DOI:
10.1021/ic990536p
PDF
Synthesis and Crystal Structure of the New Quaternary Polysulfide Na8Cu4Nb2S21 Containing S2-, S32-, and S52- Anions in Different Bridging Modes
Christian Rumpf, Christian Näther, and Wolfgang Bensch
pp 4612 - 4614; DOI:
10.1021/ic9900206
PDF

Issue 21


Novel Luminescent Au(I) Pyrimidinethiolate Dimer Having an Unusual -Stacking Structure
Leijun Hao, Rene J. Lachicotte, Henry J. Gysling, and Richard Eisenberg
pp 4616 - 4617; DOI:
10.1021/ic990662t
PDF
[NH3(CH2)4NH3]Fe2[CH3C(OH)(PO3)(PO3H)]2·2H2O: A Novel Iron(II) Diphosphonate with a Supramolecular Open Network Structure
Li-Min Zheng, Hui-Hua Song, Chia-Heir Lin, Sue-Lein Wang, Zheng Hu, Zhi Yu, and Xin-Quan Xin
pp 4618 - 4619; DOI:
10.1021/ic990482j
PDF
Theoretical Overview of Pd(I) and Pt(I) Dimers with Bridging Phosphido Ligand(s)
Carlo Mealli, Andrea Ienco, Agustín Galindo, and Enrique Perez Carreño
pp 4620 - 4625; DOI:
10.1021/ic990275j
PDF
Structure and Bonding of Diiodine Adducts of the Sulfur-Rich Donors 1,3-Dithiacyclohexane-2-thione (ptc) and 4,5-Ethylenedithio-1,3-dithiole-2-thione (ttb)
Francesco Bigoli, Paola Deplano, Andrea Ienco, Carlo Mealli, Maria Laura Mercuri, Maria Angela Pellinghelli, Gloria Pintus, Giuseppe Saba, and Emanuele F. Trogu
pp 4626 - 4636; DOI:
10.1021/ic9901867
PDF
Enantioselective Synthesis of Optically Active Polymeric Homo- and Bimetallic Oxalate-Bridged Networks [M2(ox)3]n
Román Andrés, Michel Gruselle, Bernard Malézieux, Michel Verdaguer, and Jacqueline Vaissermann
pp 4637 - 4646; DOI:
10.1021/ic9904135
PDF
Crystal Structure and Spectroscopic and Magnetic Properties of the Manganese(II) and Copper(II) Azido-Tetramethylammonium Systems
Franz A. Mautner, Samy Hanna, Roberto Cortés, Luis Lezama, M. Gotzone Barandika, and Teófilo Rojo
pp 4647 - 4652; DOI:
10.1021/ic981373s
PDF
Preparation and Characterization of Hybrid Organic-Inorganic Composite Materials Using the Amphoteric Property of Amino Acids: Amino Acid Intercalated Layered Double Hydroxide and Montmorillonite
Á. Fudala, I. Pálinkó, and I. Kiricsi
pp 4653 - 4658; DOI:
10.1021/ic981176t
PDF
Ligand Close-Packing and the Lewis Acidity of BF3 and BCl3
Bryan D. Rowsell, Ronald J. Gillespie, and George L. Heard
pp 4659 - 4662; DOI:
10.1021/ic990713m
PDF
Two-Step Spin Conversion for the Three-Dimensional Compound Tris(4,4'-bis-1,2,4-triazole)iron(II) Diperchlorate
Yann Garcia, Olivier Kahn, Louis Rabardel, Benoit Chansou, Lionel Salmon, and Jean Pierre Tuchagues
pp 4663 - 4670; DOI:
10.1021/ic990511q
PDF
New Fluorinated Stannic Compounds as Precursors of F-Doped SnO2 Materials Prepared by the Sol-Gel Route
A. Gamard, B. Jousseaume, T. Toupance, and G. Campet
pp 4671 - 4679; DOI:
10.1021/ic990163s
PDF
Ferro- and Antiferromagnetic Coupling through 1,n-Dithiosquarate Bridges (n = 2, 3) in Copper(II) Dimers. Syntheses, Crystal Structures, and Magnetic Properties of [Cu2(bpca)2(1,2-dtsq)(H2O)]·2H2O and [Cu2(bpca)2(1,3-dtsq)]·2H2O
Isabel Castro, María Luisa Calatayud, Jorunn Sletten, Francesc Lloret, Juan Cano, Miguel Julve, Gunther Seitz, and Klaus Mann
pp 4680 - 4687; DOI:
10.1021/ic9904384
PDF
Photoelectron Spectra of Trimethylphosphine-Substituted Tungsten Carbonyls: Ligand Field Effects, Ligand Additivity Effects, and Core-Valence Ionization Correlations
Jingcun Wu, G. Michael Bancroft, Richard J. Puddephatt, Y. F. Hu, Xiaorong Li, and K. H. Tan
pp 4688 - 4695; DOI:
10.1021/ic9904687
PDF
Raman Spectroscopic Investigation of Matrix Isolated Rubidium and Cesium Molecules: Rb2, Rb3, Cs2, and Cs3
Andreas Kornath, Anja Zoermer, and Ralf Ludwig
pp 4696 - 4699; DOI:
10.1021/ic990506m
PDF
Synthesis and Structural Characterization of (1,4-Dihydropyrid-1-yl)aluminum Complexes
Karl Hensen, Alexander Lemke, Thorsten Stumpf, Michael Bolte, Holger Fleischer, Colin R. Pulham, Robert O. Gould, and Steven Harris
pp 4700 - 4704; DOI:
10.1021/ic9905695
PDF
Structural and Spectroscopic Studies of 16-Electron, Unsaturated Derivatives of Low-Valent, Group 6 Carbonyl Complexes Containing -Donor Ligands
Donald J. Darensbourg, Jennifer D. Draper, Brian J. Frost, and Joseph H. Reibenspies
pp 4705 - 4714; DOI:
10.1021/ic9804216
PDF
Coordination Chemistry, Structure, and Reactivity of Thiouracil Derivatives of Tungsten(0) Hexacarbonyl: A Theoretical and Experimental Investigation into the Chelation/Dechelation of Thiouracil via CO Loss and Addition
Donald J. Darensbourg, Brian J. Frost, Agnes Derecskei-Kovacs, and Joseph H. Reibenspies
pp 4715 - 4723; DOI:
10.1021/ic990758n
PDF
Structural, Conformational, and Spectroscopic Studies of Primary Amine Complexes of Iron(II) Porphyrins
Orde Q. Munro, P. Sizwe Madlala, Richard A. F. Warby, Takele B. Seda, and Giovanni Hearne
pp 4724 - 4736; DOI:
10.1021/ic990178q
PDF
Room Temperature Synthesis of Metal Chalcogenides in Ethylenediamine
Yadong Li, Zhaoyu Wang, and Yi Ding
pp 4737 - 4740; DOI:
10.1021/ic990174l
PDF
Hybrid Organic-Inorganic Frameworks (MIL-n). Hydrothermal Synthesis of a Series of Pillared Lanthanide Carboxyethylphosphonates and X-ray Powder ab Initio Structure Determination of MIL-19, Pr[O3P(CH2)2CO2]
F. Serpaggi and G. Férey
pp 4741 - 4744; DOI:
10.1021/ic981440i
PDF
Synthesis, Crystal Structure, and Magnetic Properties of Tetraphenylarsonium Tetrachloro(oxalato)rhenate(IV) and Bis(2,2'-bipyridine)tetrachloro(-oxalato)copper(II)rhenium(IV)
Raúl Chiozzone, Ricardo González, Carlos Kremer, Giovanni De Munno, Joan Cano, Francesc Lloret, Miguel Julve, and Juan Faus
pp 4745 - 4752; DOI:
10.1021/ic990376h
PDF
Synthesis, Structure, and Magnetism of Mono- and Binuclear Manganese(II) Compounds of Nitronyl Nitroxide Substituted Phosphine Oxides
Corinne Rancurel, Daniel B. Leznoff, Jean-Pascal Sutter, Stéphane Golhen, Lahcène Ouahab, Janis Kliava, and Olivier Kahn
pp 4753 - 4758; DOI:
10.1021/ic990527g
PDF
Synthesis and Spectroscopic Characterization of a Zeolite-Entrapped Ru(bpy)2(dpp)2+ Complex
Anwar A. Bhuiyan and James R. Kincaid
pp 4759 - 4764; DOI:
10.1021/ic990359s
PDF
Determination by Multi-NMR Studies of New Stable Aluminum Complexes with Pyrophosphate and Fluoride in Aqueous Solution
Eric J. Martinez, Jean-Luc Girardet, Claude Maerschalk, and Claude Morat
pp 4765 - 4770; DOI:
10.1021/ic9811493
PDF
Photochemical Reactivity of W(CO)4(phen): Evidence for Prompt One-Electron Transfer in Competition with Vibrational Relaxation
Elspeth M. Lindsay, Cooper H. Langford, and Alexander D. Kirk
pp 4771 - 4776; DOI:
10.1021/ic980655p
PDF
Reactions of Dimethyl Sulfite with Diorganotin Oxides. One-Pot Synthesis of Methoxydiorganotin Methanesulfonates through the Arbuzov Rearrangement, Spectroscopic Characterization of These Compounds and Their Derivatives, and X-ray Crystal Structures of n-Bu2Sn(X)OS(O)2Me (X = acac, bzbz, OH)
Suraj P. Narula, Sukhjeevan Kaur, Ravi Shankar, Sushma Verma, Paloth Venugopalan, Surinder K. Sharma, and Raj K. Chadha
pp 4777 - 4783; DOI:
10.1021/ic981337t
PDF
Preparation, Characterization, and Physical Properties of Bis(imidazole)sulfur Difluoride and Bis(4-phenylimidazole)sulfur Difluoride. New Compositions with Unexpected Thermal Stability
Robert G. Syvret
pp 4784 - 4788; DOI:
10.1021/ic990318w
PDF
Syntheses and Structures of Bis(azole)difluorosulfuranes
Jens Wessel, Ulrich Behrens, Enno Lork, Paul G. Watson, Markus Schröter, and Rüdiger Mews
pp 4789 - 4794; DOI:
10.1021/ic990401j
PDF
-Bi4(P2Se6)3: A New Ternary Selenophosphate Obtained in a P2Se5 Flux
Jennifer A. Aitken, Shannon Brown, Konstantinos Chondroudis, Stéphane Jobic, Raymond Brec, and Mercouri G. Kanatzidis
pp 4795 - 4800; DOI:
10.1021/ic990180h
PDF
Reactivity of [{MnIV(salpn)}2(-O,-OCH3)]+ and [{MnIV(salpn)}2(-O,-OH)]+: Effects of Proton Lability and Hydrogen Bonding
Michael J. Baldwin, Neil A. Law, Timothy L. Stemmler, Jeff W. Kampf, James E. Penner-Hahn, and Vincent L. Pecoraro
pp 4801 - 4809; DOI:
10.1021/ic990346e
PDF
Synthesis of Iridium(III) Carboxamides via the Bimetallic Reaction between Cp*(PMe3)IrPh(OH) and [Cp*(PMe3)Ir(Ph)NCR]+
David M. Tellers, Joachim C. M. Ritter, and Robert G. Bergman
pp 4810 - 4818; DOI:
10.1021/ic9907157
PDF
Theoretical Study of Reactions of Arduengo-Type Carbene, Silylene, and Germylene with CH4
Ming-Der Su and San-Yan Chu
pp 4819 - 4823; DOI:
10.1021/ic990442f
PDF
Acid-Base Adducts of Catalytically Active Titanium(IV) Lewis Acids
Andrew O. Larsen, Peter S. White, and Michel R. Gagné
pp 4824 - 4828; DOI:
10.1021/ic990473a
PDF
Palladium Phosphinothiolato Complexes. Syntheses and Crystal Structures of Mononuclear [PdCl(SC2H4PPh2)PPh3] and Binuclear [Pd2Cl2(-SC3H6PPh2)2] and Their Performance in Catalytic Carbonylation
Nuria Brugat, Alfonso Polo, Ángel Álvarez-Larena, J. Francesc Piniella, and Julio Real
pp 4829 - 4837; DOI:
10.1021/ic981224+
PDF
Observation of Magnetic Ordering as High as 28 K for meso-Tetrakis(4-halophenyl)porphinatomanganese(III) Tetracyanoethenide, [MnTXPP][TCNE] (X = F, Br, I)
Durrell K. Rittenberg and Joel S. Miller
pp 4838 - 4848; DOI:
10.1021/ic990170g
PDF
Effects of Metalation State (Free Base, Mg, Zn, Cd) on Excited-State Energy Transfer in Diarylethyne-Linked Porphyrin Dimers
Philippe Hascoat, Sung Ik Yang, Robin K. Lammi, Jennifer Alley, David F. Bocian, Jonathan S. Lindsey, and Dewey Holten
pp 4849 - 4853; DOI:
10.1021/ic990469z
PDF
Relationship between the Dipole Strength of Ligand Pre-Edge Transitions and Metal-Ligand Covalency
Frank Neese, Britt Hedman, Keith O. Hodgson, and Edward I. Solomon
pp 4854 - 4860; DOI:
10.1021/ic990461p
PDF
Efficient Photodissociation of Anions from Benzoyl-Functionalized Ferrocene Complexes
Yoshikazu Yamaguchi and Charles Kutal
pp 4861 - 4867; DOI:
10.1021/ic990173t
PDF
Theoretical Study of the Electronic Structure of Group 6 [M(CO)5X]- Species (X = NH2, OH, Halide, H, CH3) and a Reinvestigation of the Role of -Donation in CO Lability
Stuart A. Macgregor and David MacQueen
pp 4868 - 4876; DOI:
10.1021/ic990355n
PDF
Studies of Dirhodium Tetra(trifluoroacetate). 3. Solid State Isomers of the Compound Rh2(O2CCF3)4(THF) Prepared by Sublimation
F. Albert Cotton, Evgeny V. Dikarev, and Salah-Eddine Stiriba
pp 4877 - 4881; DOI:
10.1021/ic990618d
PDF
Mixed Chloride/Amine Complexes of Dimolybdenum(II,II). 4. Rotational Isomers of Mo2Cl4(R-py)4 (R-py = 4-Picoline, 3,5-Lutidine, and 4-tert-Butylpyridine)
F. Albert Cotton, Evgeny V. Dikarev, Santiago Herrero, and Barbara Modec
pp 4882 - 4887; DOI:
10.1021/ic990728k
PDF
Synthesis and Structures of Solvated Monoclusters and Bridged Di- and Triclusters Based on the Cubic Building Block [Re6(3-Se)8]2+
Zhiping Zheng, Thomas G. Gray, and R. H. Holm
pp 4888 - 4895; DOI:
10.1021/ic9906050
PDF
Deuteration of Decaborane(14) via Exchange with Deuterated Aromatic Solvents
Joel A. Dopke and Donald F. Gaines
pp 4896 - 4897; DOI:
10.1021/ic990451o
PDF
Monomeric Niobium Persulfide Complexes: The Synthesis and Structural Characterization of Pentagonal-Pyramidal [Ph4P]2[Nb(E)(S2)2(SPh)] (E = O, S) Complexes
Jung Woo Park and Sang Man Koo
pp 4898 - 4900; DOI:
10.1021/ic981328k
PDF
Characterization of Iron(III) Tetramesitylporphyrin and Microperoxidase-8 Incorporated into the Molecular Sieve MCM-41
Volker Schünemann, Alfred X. Trautwein, Ivonne M. C. M. Rietjens, Marelle G. Boersma, Cees Veeger, Dominique Mandon, Raymond Weiss, Kapil Bahl, Christopher Colapietro, Martin Piech, and Rachel N. Austin
pp 4901 - 4905; DOI:
10.1021/ic990255h
PDF
Direct Synthesis of Rigid Ligand-Bridged Homo- and Heterodinuclear Complexes via Stereoselective 1,3-Dipolar Coupling of Mononuclear Ruthenium(II) and Osmium(II) Precursors
Austin C. Schultz, Laurence S. Kelso, Martin R. Johnston, Ronald N. Warrener, and F. Richard Keene
pp 4906 - 4909; DOI:
10.1021/ic9902370
PDF
Spin-Crossover in the Complex Bis(cis-1,2-dicyano-1,2-ethylenedithiolato)[2-(p-pyridyl)-4,4,5,5-tetramethylimidazolinium]iron(III)
Mohammed Fettouhi, Mohammed Morsy, Abdel Waheed, Stéphane Golhen, Lahcène Ouahab, Jean-Pascal Sutter, Olivier Kahn, Nieves Menendez, and François Varret
pp 4910 - 4912; DOI:
10.1021/ic990299q
PDF
Isolation, Characterization, and Molecular Structure of 1,2-(Me2S)2B12H10
Roman G. Kultyshev, Jianping Liu, Edward A. Meyers, and Sheldon G. Shore
pp 4913 - 4915; DOI:
10.1021/ic990808o
PDF
Syntheses and Crystal Structures of 9-Acetyl- and 9-Cyano-1,2-dicarbadodecaborane: Supramolecular Association in Carboranyl C-H Hydrogen-Bonded -Networks
Liliana Crciun and Radu Custelcean
pp 4916 - 4919; DOI:
10.1021/ic9904889
PDF
Synthesis, Characterization, and Explosive Properties of the Nitrogen-Rich Borazine [H3N3B3(N3)3].
Robert T. Paine, Wolfgang Koestle, Theodore T. Borek, Gary L. Wood, Eugene A. Pruss, Eileen N. Duesler, and Michael A. Hiskey:
pp 4920 - 4920; DOI:
10.1021/ic991042v
PDF

Issue 22


Dioxygen Reactivity of Reduced Heme and Heme-Copper Complexes Utilizing Tetraarylporphyrinates Tethered with Both a Pyridyl Axial Ligand and N,N-Bis[2-(2-pyridyl)ethyl]amine Chelate
Marie-Aude Kopf and Kenneth D. Karlin
pp 4922 - 4923; DOI:
10.1021/ic990546q
PDF
Intramolecular Migration of Coordinated Platinum(II) from the N7 Site to the Exocyclic Amino Group in 9-Methyladenine
Jussi Viljanen, Karel D. Klika, Reijo Sillanpää, and Jorma Arpalahti
pp 4924 - 4925; DOI:
10.1021/ic990498+
PDF
The Synthesis of [Me4N]2[a2-B20H16(NH3)2] and trans-B20H16(NH3)2 from [Me3NH][cis-B20H17NH3] and Their Structural Characterization
Fangbiao Li, Kenneth Shelly, Carolyn B. Knobler, and M. Frederick Hawthorne
pp 4926 - 4927; DOI:
10.1021/ic990744h
PDF
Preparation, Spectroscopic Characterization, and Frontier MO Study of the Heteronuclear Luminescent [Pt2Au2(dmb)2(PPh3)4](PF6)2 Cluster (dmb = 1,8-Diisocyano-p-menthane). A Cluster with a Formal Au0-Au0 Bond Encapsulated inside a "Pt2(dmb)22+ " Fragment
Tianle Zhang, Marc Drouin, and Pierre D. Harvey
pp 4928 - 4936; DOI:
10.1021/ic981187m
PDF
New Tetrameric Alkylmetal Boryloxides [(3-R2BO)MR']4 of Zinc and Cadmium with Heterocubane Structure
Sergiusz Luliski, Izabela Madura, Janusz Serwatowski, and Janusz Zachara
pp 4937 - 4941; DOI:
10.1021/ic990412c
PDF
Theoretical Studies on the Higher Oxidation States of Iron
M. Atanasov
pp 4942 - 4948; DOI:
10.1021/ic990263y
PDF
Ligand Field Stabilization Energies of the Hexaaqua 3+ Complexes of the First Transition Series
David A. Johnson and Peter G. Nelson
pp 4949 - 4955; DOI:
10.1021/ic990426i
PDF
Solid-State 199Hg MAS NMR and Vibrational Spectroscopic Studies of Dimercury(I) Compounds
Graham A. Bowmaker, Robin K. Harris, and David C. Apperley
pp 4956 - 4962; DOI:
10.1021/ic9905648
PDF
Freeze-Quench Magnetic Circular Dichroism Spectroscopic Study of the "Very Rapid" Intermediate in Xanthine Oxidase
Robert M. Jones, Frank E. Inscore, Russ Hille, and Martin L. Kirk
pp 4963 - 4970; DOI:
10.1021/ic990154j
PDF
"Axial-Bonding"-Type Hybrid Porphyrin Arrays: Synthesis, Spectroscopy, Electrochemistry, and Singlet State Properties
L. Giribabu, T. Anita Rao, and Bhaskar G. Maiya
pp 4971 - 4980; DOI:
10.1021/ic990326c
PDF
Synthesis, Structure, and Magnetic Properties of (n-Bu4N)2[{Ni(MeOH)2}2{Mo(NO)}2(3-OH)2(-OMe)4{Mo5O13(OMe)4(NO)}2], a New Type of Polyoxometalate Incorporating a Rhomb-like Cluster
Richard Villanneau, Anna Proust, Francis Robert, Pierre Veillet, and Pierre Gouzerh
pp 4981 - 4985; DOI:
10.1021/ic990480z
PDF
Metal Ion Dependent Molecular Inclusion Chemistry: Inclusion of p-Toluenesulfonate and p-Nitrophenolate within the Structure of Coordinated 1,4,7,10-Tetrakis((S)-2-hydroxy-3-phenoxypropyl)-1,4,7,10-tetraazacyclododecane
Christopher B. Smith, Kia S. Wallwork, Jennifer M. Weeks, Mark A. Buntine, Stephen F. Lincoln, Max R. Taylor, and Kevin P. Wainwright
pp 4986 - 4992; DOI:
10.1021/ic990739d
PDF
Synthesis and Chemistry of Bis(borylphosphino)silanes and -germanes
Tuqiang Chen, Eileen N. Duesler, Robert T. Paine, and Heinrich Nöth
pp 4993 - 4999; DOI:
10.1021/ic990507e
PDF
Migration Reactivities of -Bonded Ligands of Organoiron and Organocobalt Porphyrins Depending on Different High Oxidation States
Shunichi Fukuzumi, Ikuo Nakanishi, Keiko Tanaka, Alain Tabard, Roger Guilard, Eric Van Caemelbecke, and Karl M. Kadish
pp 5000 - 5006; DOI:
10.1021/ic990324s
PDF
An Iron-Based Molecular Redox Switch as a Model for Iron Release from Enterobactin via the Salicylate Binding Mode
Thomas R. Ward, Andreas Lutz, Serge P. Parel, Jürgen Ensling, Philipp Gütlich, Péter Buglyó, and Chris Orvig
pp 5007 - 5017; DOI:
10.1021/ic990225e
PDF
Complexes with S-Donor Ligands. 7. New 1,1-Ethylenedithiolato Complexes of Thallium(I), Gold(I), and Gold(III): Syntheses, Structure, and Molecular Cubic Hyperpolarizabilities
José Vicente, María Teresa Chicote, Pablo González-Herrero, Peter G. Jones, Mark G. Humphrey, Marie P. Cifuentes, Marek Samoc, and Barry Luther-Davies
pp 5018 - 5026; DOI:
10.1021/ic990379u
PDF
Reactions of Cu(hfacac)2·H2O (hfacac = Hexafluoroacetylacetonate) with Bidentate Ligands. Preparation, Characterization, and X-ray Structures of the Molecular Complexes Cu(hfacac)2(pyrazine)2 and Cu(hfacac)2(3-cyanopyridine)2 and the One-Dimensional Coordination Polymers Cu(hfacac)2(1,2-bis(4-pyridyl)ethane) and Cu(hfacac)2(4,4'-trimethylenebipyridine)
Yu-Bin Dong, Mark D. Smith, Ralph C. Layland, and Hans-Conrad zur Loye
pp 5027 - 5033; DOI:
10.1021/ic9906104
PDF
Synthesis and Crystal and Electronic Structures of the Dinuclear Platinum Compounds [PEtPh3]2[Pt2(-PPh2)2(C6F5)4] and [Pt2(-PPh2)2(C6F5)4]: A Computational Study by Density Functional Theory
Ester Alonso, José M. Casas, F. Albert Cotton, Xuejung Feng, Juan Forniés, Consuelo Fortuño, and Milagros Tomas
pp 5034 - 5040; DOI:
10.1021/ic981437z
PDF
A New Method for Preparation and Crystal Structure of (Trifluoromethyl)iodine Dichloride
Rolf Minkwitz and Michael Berkei
pp 5041 - 5044; DOI:
10.1021/ic990441n
PDF
Crystal and Molecular Structure of a Potential DNA Groove-Spanning Chelate: [MV][Pt2(hdta)Cl2]·4H2O (MV2+ = 1,1'-Dimethyl-4,4'-bipyridinium, hdta4- = 1,6-Hexanediamine-N,N,N',N'-tetraacetate)
Richard A. Kortes, Steven J. Geib, Fu-Tyan Lin, and Rex E. Shepherd
pp 5045 - 5052; DOI:
10.1021/ic990123o
PDF
Molecular Structures of M2(CO)9 and M3(CO)12 (M = Fe, Ru, Os): New Theoretical Insights
Elke Hunstock, Carlo Mealli, Maria José Calhorda, and Joachim Reinhold
pp 5053 - 5060; DOI:
10.1021/ic9905289
PDF
Template-Directed One- and Two-Dimensional Copper(II) Diphosphonates: Structures and Characterizations of (NH4)2Cu3(hedp)2(H2O)4, [NH3(CH2)4NH3]Cu3(hedp)2·2H2O, and [NH2(C2H4)2NH2]Cu3(hedp)2 (hedp = 1-Hydroxyethylidenediphosphonate)
Li-Min Zheng, Hui-Hua Song, Chun-Ying Duan, and Xin-Quan Xin
pp 5061 - 5066; DOI:
10.1021/ic990481r
PDF
Mechanisms of Reactions of Dihydrogen Complexes: Formation of trans-[RuH(H2)(dppe)2]+ and Substitution of Coordinated Dihydrogen
Manuel G. Basallote, Joaquín Durán, M. Jesús Fernández-Trujillo, and M. Angeles Máñez
pp 5067 - 5071; DOI:
10.1021/ic9902267
PDF
Observation of Ferromagnetic and Antiferromagnetic Coupling in 1-D and 2-D Extended Structures of Copper(II) Terephthalates
Laura Deakin, Atta M. Arif, and Joel S. Miller
pp 5072 - 5077; DOI:
10.1021/ic990400r
PDF
Stepwise Complexation of Ni(II) and Cu(II) Ions by 6,6'-C-spirobi(cyclam) (cyclam = 1,4,8,11-Tetraazacyclotetradecane), L1. Syntheses and Redox Chemistry of [M(H2L1)]X4 (M = Cu2+, Ni2+), [Cu2(L1)]X4, and [CuNi(L1)]X4 (X = ClO4-) and the X-ray Crystal Structure of [Cu2(L1)](ClO4)4
A. McAuley, S. Subramanian, M. J. Zaworotko, and K. Biradha
pp 5078 - 5085; DOI:
10.1021/ic9904844
PDF
Electrochemistry of Macrocyclic Cobalt(III/II) Hexaamines: Electrocatalytic Hydrogen Evolution in Aqueous Solution
Paul V. Bernhardt and Lathe A. Jones
pp 5086 - 5090; DOI:
10.1021/ic981425d
PDF
Ground-State, Mode-Dependent Vibronic Coupling in Some Simple, Cyanide-Bridged Transition-Metal Donor-Acceptor Complexes
Ariel V. Macatangay, Selma Elaine Mazzetto, and John F. Endicott
pp 5091 - 5101; DOI:
10.1021/ic9904743
PDF
Rigid Molecular Rods with Cumulene-Bridged Polyphosphines: Synthesis, Electronic Communication, Molecular Photophysics, Mixed-Valence State, and X-ray Photoelectron Spectroscopic Study
Jeffrey V. Ortega, Bo Hong, Sutapa Ghosal, John C. Hemminger, Brian Breedlove, and Clifford P. Kubiak
pp 5102 - 5112; DOI:
10.1021/ic990673m
PDF
Synthesis of Azo-Bridged Ferrocene Oligomers and a Polymer and Electrochemical and Optical Analysis of Internuclear Electronic Interactions in Their Mixed-Valence States
Masaru Kurosawa, Takuya Nankawa, Takayuki Matsuda, Kenya Kubo, Masato Kurihara, and Hiroshi Nishihara
pp 5113 - 5123; DOI:
10.1021/ic990646w
PDF
Tuning of Charge Density Wave Strengths by Competition between Electron-Phonon Interaction of PdII-PdIV Mixed-Valence States and Electron Correlation of NiIII States in Quasi-One-Dimensional Bromo-Bridged Ni-Pd Mixed-Metal MX Chain Compounds Ni1-xPdx(chxn)2Br3
Masahiro Yamashita, Tomohiko Ishii, Hiroyuki Matsuzaka, Toshio Manabe, Takuya Kawashima, Hiroshi Okamoto, Hiroshi Kitagawa, Tadaoki Mitani, Kazuhiro Marumoto, and Shin-ichi Kuroda
pp 5124 - 5130; DOI:
10.1021/ic990219i
PDF
Redox Chemistry of (1,4,7-Tris(4-tert-butyl-2-mercaptobenzyl)-1,4,7- triazacyclononane)ruthenium(III), [RuIIIL]: Synthesis and Characterization of [RuII2(L-L)](BPh4)4·10CH3CN and [LRuRuRuL](PF6)2·H2O
Belén Albela, Eberhard Bothe, Oliver Brosch, Katsura Mochizuki, Thomas Weyhermüller, and Karl Wieghardt
pp 5131 - 5138; DOI:
10.1021/ic9906297
PDF
Vacancy Ordering and Bonding Competition in the Group 9 Tellurides MxTe2 (M = Rh, Ir; 0.75 x 2): A Theoretical Study
Chi-Shen Lee and Gordon J. Miller
pp 5139 - 5150; DOI:
10.1021/ic990652s
PDF
Topological Aspects of the Skeletal Bonding in "Isocloso" Metallaboranes Containing "Anomalous" Numbers of Skeletal Electrons
R. B. King
pp 5151 - 5153; DOI:
10.1021/ic990601v
PDF
Spectroscopy and Dynamics of Re4+ Near-IR-to-Visible Luminescence Upconversion
Daniel R. Gamelin and Hans U. Güdel
pp 5154 - 5164; DOI:
10.1021/ic990556r
PDF
Reactions of the Dirhenium(II) Complexes Re2X4(-dppm)2 (X = Cl, Br; dppm = Ph2PCH2PPh2) with Isocyanides. 19.1 Studies of the Reactions of Five Structural Isomers of Re2Cl2(-dppm)2(CO)(CNXyl)3 That Lead to the Dirhenium(I) Complexes [Re2(-Cl)(-CO)(-dppm)2(CNXyl)4]O3SCF3 and [Re2Cl(-dppm)2(CO)(CNXyl)3(NCCH3)]O3SCF3
Yan Ding, Phillip E. Fanwick, and Richard A. Walton
pp 5165 - 5170; DOI:
10.1021/ic990538+
PDF
Reactions of cis-[tBuNTe(-NtBu)]2 with CF3SO3Me and M[O3SCF3] (M = Ag, Cu): Chelation, Cis Trans Isomerization, and the Spirocyclic Ligand [tBuNTe(-NtBu)2Te(-O)]2
Tristram Chivers, Masood Parvez, and Gabriele Schatte
pp 5171 - 5177; DOI:
10.1021/ic9903681
PDF
Synthesis, Structure, and Modeling of a Cyclic Rhodium(III) Porphyrin Dimer with an Encapsulated 4,4'-Bipyridine Ligand
Hee-Joon Kim, James E. Redman, Moshe Nakash, Neil Feeder, Simon J. Teat, and Jeremy K. M. Sanders
pp 5178 - 5183; DOI:
10.1021/ic990593i
PDF
Aminoferrocene Derivatives in Chloride Recognition and Electrochemical Sensing
Konstantinos Kavallieratos, Sharon Hwang, and Robert H. Crabtree
pp 5184 - 5186; DOI:
10.1021/ic990813s
PDF
Organophosphazenes. 24. Ultraviolet Photoelectron Spectra of Selected Alkenyl- and Alkynylfluorocyclotriphosphazenes
Christopher W. Allen and S. Davis Worley
pp 5187 - 5188; DOI:
10.1021/ic9904236
PDF
1,2-Cyclopentadienyl Diimine-Group 13 Complexes
Christopher M. Ong and Douglas W. Stephan
pp 5189 - 5191; DOI:
10.1021/ic9903782
PDF
Radioactive Origin of Emissions Observed from Uranium Compounds and Their Silica Cells
J. P. Young, R. W. Shaw, and Oren F. Webb
pp 5192 - 5194; DOI:
10.1021/ic990558b
PDF

Issue 23


Flipping the Molecular Light Switch Off: Formation of DNA-Bound Heterobimetallic Complexes Using Ru(bpy)2tpphz2+ and Transition Metal Ions
Steven A. Tysoe, Roni Kopelman, and Dietrich Schelzig
pp 5196 - 5197; DOI:
10.1021/ic9901315
PDF
Kinetics of Iron(III) Chelation from Polynuclear Oxo-Hydroxy Aggregates by Hydroxamic Acids: Understanding Ferritin Iron(III) Sequestration
David A. Brown, Kara M. Herlihy, and Stephen K. O'Shea
pp 5198 - 5202; DOI:
10.1021/ic990158o
PDF
Preference of np-np Bonding (n = 3, 4) over Purely -Bonded Species in M42+ (M = S, Se): Geometries, Bonding, and Energetics of Several M42+ Isomers
Ingo Krossing and Jack Passmore
pp 5203 - 5211; DOI:
10.1021/ic990048h
PDF
High-Resolution Double-Quantum 31P MAS NMR Study of the Intermediate-Range Order in Crystalline and Glass Lead Phosphates
Franck Fayon, Catherine Bessada, Jean-Pierre Coutures, and Dominique Massiot
pp 5212 - 5218; DOI:
10.1021/ic990375p
PDF
Dinuclear Molybdenum and Tungsten Complexes with Metal-Metal Triple Bonds Supported by p-tert-Butylcalix[4]arene Ligands
Malcolm H. Chisholm, Kirsten Folting, William E. Streib, and De-Dong Wu
pp 5219 - 5229; DOI:
10.1021/ic990513a
PDF
Kinetics and Mechanism of Oxygen Atom Abstraction from Sulfenatocobalt(III) Complexes by Hydrated Methyldioxorhenium(V)
David W. Lahti and James H. Espenson
pp 5230 - 5234; DOI:
10.1021/ic990425q
PDF
An Alternative Approach to Al2O2 Ring Systems by Unexpected Cleavage of Stable Al-F- and Si-O- Bonds
Carsten Rennekamp, Helge Wessel, Herbert W. Roesky, Peter Müller, Hans-Georg Schmidt, Mathias Noltemeyer, Isabel Usón, and Andrew R. Barron
pp 5235 - 5240; DOI:
10.1021/ic990185e
PDF
Synthesis and Reactivity of Ru(II)/Chloro/Hydrido/Carbonyls with Cis Bulky Phosphines: An Unsaturated Ru(II) Monohydride
Torsten Gottschalk-Gaudig, Kirsten Folting, and Kenneth G. Caulton
pp 5241 - 5245; DOI:
10.1021/ic9902020
PDF
Phenylethynyl Substituent Effects on the Photophysics and Electrochemistry of [Cu(dpp)2]+ (dpp = 2,9-Diphenyl-1,10-phenanthroline)
Mark T. Miller and Timothy B. Karpishin
pp 5246 - 5249; DOI:
10.1021/ic990588e
PDF
Synthesis of Amine-dicyanohydroboranes, [Amine-bis(ethylnitrilium)hydroboron(2+)] Tetrafluoroborates, and Their Derivatives as Precursors of Amine-dicarboxyboranes
Zoltán Berente and Béla Györi
pp 5250 - 5256; DOI:
10.1021/ic990023i
PDF
Experimental and Theoretical Study of the Kinetic and Thermodynamic Sites of Protonation in (CO)Pt(-PBut2)2Pt(PBut2H)
Piero Leoni, Marco Pasquali, Valerio Cittadini, Alessandro Fortunelli, and Massimo Selmi
pp 5257 - 5265; DOI:
10.1021/ic9903228
PDF
Tetranuclear Copper(II) and Nickel(II) Cluster Complexes Derived by Self-Assembly from a Series of Tetradentate Diazine Ligands: Structural and Magnetic Studies
Craig J. Matthews, Karen Avery, Zhiqiang Xu, Laurence K. Thompson, Liang Zhao, David O. Miller, Kumar Biradha, Karen Poirier, Michael J. Zaworotko, Claire Wilson, Andrés E. Goeta, and Judith A. K. Howard
pp 5266 - 5276; DOI:
10.1021/ic990598f
PDF
Synthetic, Thermochemical, and Catalytic Studies of Fluorinated Tertiary Phosphine Ligands R2PRf [R = Cy, Ph, iPr; Rf = CH'2CH2(CF2)5CF3] in Rhodium Systems
Dale C. Smith, Jr., Edwin D. Stevens, and Steven P. Nolan
pp 5277 - 5281; DOI:
10.1021/ic990430u
PDF
Synthesis and Reactivity of Early-Late Heterodinuclear Complexes Stabilized by a Trisilylsilane-Based Tripodal Amido Ligand
Lutz H. Gade, Martin Schubart, Bernd Findeis, Sylvie Fabre, Izoldi Bezougli, Matthias Lutz, Ian J. Scowen, and Mary McPartlin
pp 5282 - 5294; DOI:
10.1021/ic990562n
PDF
Heterodi- and Heterotrinuclear Complexes Containing Highly Polar Metal-Metal Bonds
Lutz H. Gade, Stefan Friedrich, Dominique J. M. Trösch, Ian J. Scowen, and Mary McPartlin
pp 5295 - 5307; DOI:
10.1021/ic990350q
PDF
Synthesis of Alkynyl Amino Acids and Peptides and Their Palladium-Catalyzed Coupling to Ferrocene
Oliver Brosch, Thomas Weyhermüller, and Nils Metzler-Nolte
pp 5308 - 5313; DOI:
10.1021/ic990256+
PDF
Transition Metal Complexes with Sulfur Ligands. 136.1 Enforced Trans Coordination of Thiolate Donors in Electron Rich Iron, Ruthenium, and Nickel [M(L)(pyN2H2S2)] and [M(L)(pyS4)] Complexes (L = CO, PPh3, DMSO) (pyN2H2S22- = 2,6-Bis(2-mercaptophenylamino)dimethylpyridine(2-); pyS42- = 2,6-Bis(2-mercaptophenylthio)dimethylpyridine(2-))
Dieter Sellmann, Jürgen Utz, and Frank W. Heinemann
pp 5314 - 5322; DOI:
10.1021/ic990169h
PDF
Synthesis and Molecular Structures in the Gas Phase of N,N-Dimethylaminoxy-trimethylsilane and -trimethylgermane
Norbert W. Mitzel, Udo Losehand, and Alan D. Richardson
pp 5323 - 5328; DOI:
10.1021/ic990689c
PDF
Reduced Anionic Mn12 Molecules with Half-Integer Ground States as Single-Molecule Magnets
Sheila M. J. Aubin, Ziming Sun, Luca Pardi, J. Krzystek, Kirsten Folting, Louis-Claude Brunel, Arnold L. Rheingold, George Christou, and David N. Hendrickson
pp 5329 - 5340; DOI:
10.1021/ic990613g
PDF
Synthesis and Characterization of [RuCl3(P-P)(H2O)] Complexes; P-P = Achiral or Chiral, Chelating Ditertiary Phosphine Ligands
Luis R. Dinelli, Alzir A. Batista, Karen Wohnrath, Marcio P. de Araujo, Salete L. Queiroz, Marcos R. Bonfadini, Glaucius Oliva, Otaciro R. Nascimento, Paul W. Cyr, Kenneth S. MacFarlane, and Brian R. James
pp 5341 - 5345; DOI:
10.1021/ic990130c
PDF
Syntheses and Structural Characterizations of the Three-dimensional Polymers [(R2Sn)3{Co(CN)6}2·X] (R = Vinyl, Propyl, Butyl; X = Solvent)
Tianyan Niu and Allan J. Jacobson
pp 5346 - 5350; DOI:
10.1021/ic990648g
PDF
Factors Influencing the pKa of Ligated Amines and the Syn/Anti Isomerization in Cysteine-Based Re(V)=O(N2S2) Radiopharmaceutical Analogues As Revealed by a Novel Dominant Tautomer in the Solid State
Lory Hansen, Malgorzata Lipowska, Enrique Meléndez, Xiaolong Xu, Shun Hirota, Andrew T. Taylor, and Luigi G. Marzilli
pp 5351 - 5358; DOI:
10.1021/ic9906398
PDF
Mechanistic, Structural, and Spectroscopic Studies on the Catecholase Activity of a Dinuclear Copper Complex by Dioxygen
Enrico Monzani, Giuseppe Battaini, Angelo Perotti, Luigi Casella, Michele Gullotti, Laura Santagostini, Giorgio Nardin, Lucio Randaccio, Silvano Geremia, Piero Zanello, and Giuliana Opromolla
pp 5359 - 5369; DOI:
10.1021/ic990397b
PDF
Hybrid Open Frameworks. 8. Hydrothermal Synthesis, Crystal Structure, and Thermal Behavior of the First Three-Dimensional Titanium(IV) Diphosphonate with an Open Structure: Ti3O2(H2O)2(O3P-(CH2)-PO3)2·(H2O)2, or MIL-22
Christian Serre and Gérard Férey
pp 5370 - 5373; DOI:
10.1021/ic990345m
PDF
Kinetics and Mechanisms of the Oxidation of Hydrazinium Ion (N2H5+) by ICl and IBr; Determination of the Protonation Constant of N2H5+
Zhongjiang Jia and Dale W. Margerum
pp 5374 - 5378; DOI:
10.1021/ic990674e
PDF
Reactivity of the Verdoheme Analogues. Opening of the Planar Macrocycle by Amide and Thiolate Nucleophiles To Form Helical Complexes
James A. Johnson, Marilyn M. Olmstead, and Alan L. Balch
pp 5379 - 5383; DOI:
10.1021/ic9904283
PDF
An EPR Study of Some Highly Distorted Tetrahedral Manganese(II) Complexes at High Magnetic Fields
Richard M. Wood, Debra M. Stucker, Laura M. Jones, W. Bryan Lynch, Sushil K. Misra, and Jack H. Freed
pp 5384 - 5388; DOI:
10.1021/ic990377+
PDF
Synthesis and Reactivity Aspects of the Bis(dithiolene) Chalcogenide Series [WIVQ(S2C2R2)2]2- (Q = O, S, Se)
Christine A. Goddard and R. H. Holm
pp 5389 - 5398; DOI:
10.1021/ic9903329
PDF
Bis(2,2'-bipyridine)(1,2-diimino-9,10-anthraquinone)ruthenium(II) Derivatives: A ZINDO Analysis of a Redox Series Involving Coupled Proton and Electron Transfers
Carlos Jorge da Cunha, Elaine S. Dodsworth, Mario Artur Monteiro, and A. B. P. Lever
pp 5399 - 5409; DOI:
10.1021/ic9905594
PDF
Two-Dimensional Coordination Polymers with One-Dimensional Magnetic Chains: Hydrothermal Synthesis, Crystal Structure, and Magnetic and Thermal Properties of %@mt;sys@% %@mh;-%pxwidth@%%@sx@%%@be@%2%@sxx@%%@mx@% [MCl2(4,4'-bipyridine)] (M = Fe, Co, Ni, Co/Ni)
Michael A. Lawandy, Xiaoying Huang, Ru-Ji Wang, Jing Li, Jack Y. Lu, Tan Yuen, and C. L. Lin
pp 5410 - 5414; DOI:
10.1021/ic990286c
PDF
Degradation and Modification of Metallaboranes: Reactions of the Hexaborane(10) Analogue nido-(PPh3)2(CO)OsB5H9 with Phosphines and the Crystal and Molecular Structure of [2,2,2-(PPh3)2(CO)-nido-2-OsB4H7-3-BH2·PPh2Me]
Paul McQuade, Kevin Hupp, Jonathan Bould, Hong Fang, Nigam P. Rath, Rhodri Ll. Thomas, and Lawrence Barton
pp 5415 - 5424; DOI:
10.1021/ic990688k
PDF
Synthesis and Electrochemical and Structural Chemistry of Rhenium in High Oxidation States with Sterically Hindered Polypyridine Ligands
Md. Athar Masood, B. P. Sullivan, and Derek J. Hodgson
pp 5425 - 5430; DOI:
10.1021/ic9814672
PDF
Synthesis and Reactions of tert-Butylimidotellurium Dihalides: X-ray Structures of [Cl2Te(-NtBu)2TeCl2]3 and (tBuO)2Te(-NtBu)2Te(OtBu)2
Tristram Chivers, Gary D. Enright, Nicole Sandblom, Gabriele Schatte, and Masood Parvez
pp 5431 - 5436; DOI:
10.1021/ic990849k
PDF
The First Systematic Synthesis of Heterobimetallic Dithiolene-Bridged Complexes. Synthesis and Characterization of Metal Complexes of 4-(1',2'-Ethylenedithiolate)-1,3-dithiole-2-one and Dimeric Metal Complexes of 1,2,3,4-Butadienetetrathiolate
Christopher E. Keefer, Suzanne T. Purrington, Robert D. Bereman, and Paul D. Boyle
pp 5437 - 5442; DOI:
10.1021/ic990841a
PDF
DFT Study of the Role of Bridging Diphosphine Ligands in the Structure and the Internal Rotation in Quadruply Bonded Metal Dimers of the Mo2Cl4(P-P)2 Type
Isabelle Demachy, Agusti Lledos, and Yves Jean
pp 5443 - 5448; DOI:
10.1021/ic990541t
PDF
Ionizable Calixarene-Crown Ethers with High Selectivity for Radium over Light Alkaline Earth Metal Ions
Xiaoyuan Chen, Min Ji, Darrell R. Fisher, and Chien M. Wai
pp 5449 - 5452; DOI:
10.1021/ic990135+
PDF
Palladium(II)-Induced Activation of Carbon-Nitrogen Single Bond of Coordinated N4S Ligand. Characterization of Product with Modified Ligand Structure: Kinetics versus Thermodynamic Considerations
Sudeep Bhattacharyya, Timothy J. R. Weakley, and Muktimoy Chaudhury
pp 5453 - 5456; DOI:
10.1021/ic9813720
PDF
Trinucleating Bipyridyl Ligands; Synthesis and Structure of Cobalt-Benzoquinone Complex of Cyclotriphosphazenes Bearing Dioxybipyridine Groups
Ok-Sang Jung, Yong Tae Kim, Young-A Lee, Yun Ju Kim, and Hee K. Chae
pp 5457 - 5460; DOI:
10.1021/ic990215d
PDF
Unusual Sandwiching of the Cyclopentadienyl Anion in [K4(C5H5)2M2(OBut)6(CH3OCH2CH2OCH3)2]n (M = Ge, Sn)
Michael Veith, Charu Mathur, Sanjay Mathur, and Volker Huch
pp 5461 - 5463; DOI:
10.1021/ic9814120
PDF
Synthesis and Molecular Structure of Bis(pyrazolyl)hydroborato Thallium {[Bp]Tl}2: A [BpRR']Tl Complex with an Unbridged Close TlI···TlI Contact
Prasenjit Ghosh, Arnold L. Rheingold, and Gerard Parkin
pp 5464 - 5467; DOI:
10.1021/ic990647o
PDF
[BH3·PPh2CH2C6H4CH2PPh2·Ru(p-cym)Cl2]: A New Bifunctional Compound and Prototype of a Linked Borane/Metal Cluster Species
Paul McQuade, Nigam P. Rath, and Lawrence Barton
pp 5468 - 5470; DOI:
10.1021/ic990687s
PDF

Issue 24


Unprecedented Antiferromagnetic Metal-Ligand Interactions in Gadolinium-Nitroxide Derivatives
Christophe Lescop, Dominique Luneau, Elie Belorizky, Pascal Fries, Maurice Guillot, and Paul Rey
pp 5472 - 5473; DOI:
10.1021/ic990996i
PDF
Carboxylate-Shift-like Dynamic Equilibrium in Bromomagnesium Diethylcarbamate
M. Tyler Caudle and Jeff W. Kampf
pp 5474 - 5475; DOI:
10.1021/ic990765b
PDF
The [Cu8Br15]6- Ion, A Crystal-Stabilized High-Symmetry Mixed-Valence Copper Complex with a Linear Halogen Bridge
Graham A. Bowmaker, Peter D. W. Boyd, Clifton E. F. Rickard, Marcia L. Scudder, and Ian G. Dance
pp 5476 - 5477; DOI:
10.1021/ic990754i
PDF
Bis(cyclopentadienyl)yttrium Complexes of the Ligand [N(QPPh2)2]- (Q = S, Se): Synthesis, Structure, and NMR Properties of Cp2Y[3-N(QPPh2)2]
Christopher G. Pernin and James A. Ibers
pp 5478 - 5483; DOI:
10.1021/ic990602n
PDF
Ligand Influences on Copper Cyanide Solid-State Architecture: Flattened and Fused "Slinky", Corrugated Sheet, and Ribbon Motifs in the Copper-Cyanide-Triazolate-Organoamine Family
Douglas J. Chesnut, Anakarin Kusnetzow, Robert Birge, and Jon Zubieta
pp 5484 - 5494; DOI:
10.1021/ic990385q
PDF
Four-Coordinate, Low-Spin (S = 0) and Six-Coordinate, High-Spin (S = 1) Nickel(II) Complexes of Tetraphenylporphyrins with -Pyrrole Electron-Withdrawing Substituents: Porphyrin-Core Expansion and Conformation
Hugues Duval, Véronique Bulach, Jean Fischer, and Raymond Weiss
pp 5495 - 5501; DOI:
10.1021/ic990231a
PDF
Binding of the - and -Enantiomers of [Ru(dmphen)2dpq]2+ to the Hexanucleotide d(GTCGAC)2
J. Grant Collins, Janice R. Aldrich-Wright, Ivan D. Greguric, and Paul A. Pellegrini
pp 5502 - 5509; DOI:
10.1021/ic990092x
PDF
Metal-Metal Bonding in M2Cl6(H2PCH2PH2)2, M2Cl6(PH3)4, and M2Cl104- (M = Cr, Mo, W) Edge-Shared Dimer Systems
Robert Stranger, Timothy Lovell, and John E. McGrady
pp 5510 - 5518; DOI:
10.1021/ic9905042
PDF
Spectrophotometric Study of the Equilibria between Nickel(II) Schiff-Base Complexes and Alkaline Earth or Nickel(II) Cations in Acetonitrile Solution
Laura Carbonaro, Mauro Isola, Piero La Pegna, Lucio Senatore, and Fabio Marchetti
pp 5519 - 5525; DOI:
10.1021/ic990189j
PDF
Effect of DNA Scaffolding on Intramolecular Electron Transfer Quenching of a Photoexcited Ruthenium(II) Polypyridine Naphthalene Diimide
Dabney W. Dixon, Nancy B. Thornton, Vera Steullet, and Thomas Netzel
pp 5526 - 5534; DOI:
10.1021/ic971446s
PDF
Azidophosphazenes as Functionalized Intermediates
Harry R. Allcock, Michael B. McIntosh, and Thomas J. Hartle
pp 5535 - 5544; DOI:
10.1021/ic9904541
PDF
Metal Complexes with Cis Topology from Stereoselective Quadridentate Ligands with Amine, Pyridine, and Quinoline Donor Groups
Christina Ng, Michal Sabat, and Cassandra L. Fraser
pp 5545 - 5556; DOI:
10.1021/ic990475v
PDF
Synthesis, Structures, and Redox Properties of Octa(3-sulfido)hexarhenium(III) Complexes Having Terminal Pyridine Ligands
Takashi Yoshimura, Keisuke Umakoshi, Yoichi Sasaki, and A. Geoffrey Sykes
pp 5557 - 5564; DOI:
10.1021/ic9907922
PDF
Steric and Solvation Effects on the Aggregation of Lithium Thioamidates: Single-Strand Polymers with (LiS)n and (LiNCS)n Backbones
Tristram Chivers, Andrew Downard, and Masood Parvez
pp 5565 - 5570; DOI:
10.1021/ic990759f
PDF
Synthesis and Characterization of Functionalized N,N'-Diphenylformamidinate Silver(I) Dimers: Solid-State Structures and Solution Properties
Stephen J. Archibald, Nathaniel W. Alcock, Daryle H. Busch, and David R. Whitcomb
pp 5571 - 5578; DOI:
10.1021/ic981270+
PDF
Stoichiometric O2 Oxidation of Bis(Thioether)(Octaethylporphyrinato)ruthenium(II) Complexes to the Corresponding Sulfoxide Species in Acidic Media. Structural Confirmation of S-Bonded Sulfoxides
Andrew Pacheco, Brian R. James, and Steven J. Rettig
pp 5579 - 5587; DOI:
10.1021/ic9908219
PDF
Template Effects of Lithium Salts on the Crystallization of Diazasulfates: X-ray Structures of {THF·Li2[O2S(NtBu)2]}8·2LiOH·2LiCl and {(THF·Li)2[O2S(NtBu)2]·(THF)LiCl}2
Justin K. Brask, Tristram Chivers, and Glenn P. A. Yap
pp 5588 - 5592; DOI:
10.1021/ic990632q
PDF
Exchange Interactions Derived from Electron-Transfer Processes in [Cr2(OH)3(tmtame)2](NO3)3
Ralph Schenker, Hgni Weihe, and Hans U. Güdel
pp 5593 - 5601; DOI:
10.1021/ic9904081
PDF
High-Dimensional Manganese(II) Compounds with Noncovalent and/or Covalent Bonds Derived from Flexible Ligands: Self-Assembly and Structural Transformation
Chang Seop Hong, Sang-Kil Son, Yoon Sup Lee, Moo-Jin Jun, and Youngkyu Do
pp 5602 - 5610; DOI:
10.1021/ic990611w
PDF
Multiple Bonding Involving Late Transition Metals. The Case of a Silver-Oxo Complex
Thomas R. Cundari, Jeremy N. Harvey, Thomas R. Klinckman, and Wentao Fu
pp 5611 - 5615; DOI:
10.1021/ic9904642
PDF
Displacement of Inner-Sphere Water Molecules from Eu3+ Analogues of Gd3+ MRI Contrast Agents by Carbonate and Phosphate Anions: Dissociation Constants from Luminescence Data in the Rapid-Exchange Limit
Ronald M. Supkowski and William DeW. Horrocks, Jr.
pp 5616 - 5619; DOI:
10.1021/ic990597n
PDF
Ruthenium(II) Complexes of 2-Aryl-1,10-phenanthrolines: Synthesis, Structure, and Photophysical Properties
Feiyue Wu, Elvira Riesgo, Anna Pavalova, Rachael A. Kipp, Russell H. Schmehl, and Randolph P. Thummel
pp 5620 - 5628; DOI:
10.1021/ic990706y
PDF
Bridged Aminotroponiminate Complexes of the Lanthanides
Peter W. Roesky and Markus R. Bürgstein
pp 5629 - 5632; DOI:
10.1021/ic990533c
PDF
Dimanganese(II) Accordion Porphyrin as a Functional Model for Catalases
Nikolay N. Gerasimchuk, Aida Gerges, Thomas Clifford, Andrew Danby, and Kristin Bowman-James
pp 5633 - 5636; DOI:
10.1021/ic990576t
PDF

Issue 25


Gold Compounds as Ionic Liquids. Synthesis, Structures, and Thermal Properties of N,N'-Dialkylimidazolium Tetrachloroaurate Salts
Masihul Hasan, Ivan V. Kozhevnikov, M. Rafiq H. Siddiqui, Alexander Steiner, and Neil Winterton
pp 5637 - 5641; DOI:
10.1021/ic990657p
PDF
1H NMR Studies on Strongly Antiferromagnetically Coupled Dicopper(II) Systems
Anbanandam Asokan and Periakaruppan T. Manoharan
pp 5642 - 5654; DOI:
10.1021/ic9803356
PDF
Reactions of Electrophilic Reagents That Target the Thiolate Groups of Metallothionein Clusters: Preferential Reaction of the -Domain with 5,5'-Dithio-bis(2-nitrobenzoate) (DTNB) and Aurothiomalate (AuSTm)
Amalia Muñoz, David H. Petering, and C. Frank Shaw, III
pp 5655 - 5659; DOI:
10.1021/ic9901822
PDF
Water -Donation in trans-Tetraammineruthenium(II): Effect on Coordinated-Water Properties Induced by a Trans NO Ligand
Cícero W. B. Bezerra, Sebastião C. da Silva, Maria T. P. Gambardella, Regina H. A. Santos, Lidia M. A. Plicas, Elia Tfouni, and Douglas W. Franco
pp 5660 - 5667; DOI:
10.1021/ic990210g
PDF
Mobility of Silver(I) Ions around the Propeller Ligand, Hexaphenylbenzene (HPB), in Silver(I) -Complexes
Gui Ling Ning, Megumu Munakata, Liang Ping Wu, Masahiko Maekawa, Yusaku Suenaga, Takayoshi Kuroda-Sowa, and Kunihisa Sugimoto
pp 5668 - 5673; DOI:
10.1021/ic990143q
PDF
Silver(I) Complex Assemblies with Nonplanar Aromatic Compounds
Megumu Munakata, Liang Ping Wu, Kunihisa Sugimoto, Takayoshi Kuroda-Sowa, Masahiko Maekawa, Yusaku Suenaga, Naoto Maeno, and Motoshi Fujita
pp 5674 - 5680; DOI:
10.1021/ic990391m
PDF
Magnetostructural Characterization of 4-Oxohexa-2-chlorotetrakis(imidazole)copper(II)
Ana María Atria, Andrés Vega, Martín Contreras, Jorge Valenzuela, and Evgenia Spodine
pp 5681 - 5685; DOI:
10.1021/ic990389v
PDF
Cyanide-Bridged Iron-Copper Molecular Squares with Doublet and Quintet Spin Ground States
Hiroki Oshio, Osamu Tamada, Hironori Onodera, Tasuku Ito, Tadaaki Ikoma, and Shozo Tero-Kubota
pp 5686 - 5689; DOI:
10.1021/ic990617l
PDF
Characteristics of Five-Coordinate Nickel-Cysteine Centers
Patrick J. Desrochers, Russell W. Cutts, Phillip K. Rice, Melissa L. Golden, James B. Graham, Tosha M. Barclay, and A. W. Cordes
pp 5690 - 5694; DOI:
10.1021/ic990059a
PDF
Identification of Gaseous Cobalt Tetrafluoride: MS and FTIR Spectroscopic Studies
Juliet V. Rau, Stella Nunziante Cesaro, Norbert S. Chilingarov, and Giovanni Balducci
pp 5695 - 5697; DOI:
10.1021/ic990294t
PDF
Syntheses, Crystal Structures, and CD Spectra of Simple Heterobimetallic Transition Metal Binaphtholates
Ronald J. Cross, Louis J. Farrugia, Duncan R. McArthur, Robert D. Peacock, and Douglas S. C. Taylor
pp 5698 - 5702; DOI:
10.1021/ic990414x
PDF
Determination of Iron-Ligand Bond Lengths in Ferric and Ferrous Horse Heart Cytochrome c Using Multiple-Scattering Analyses of XAFS Data
Ming-Chu Cheng, Anne M. Rich, Robert S. Armstrong, Paul J. Ellis, and Peter A. Lay
pp 5703 - 5708; DOI:
10.1021/ic990395r
PDF
Vanadium Oxide Complexes in Room-Temperature Chloroaluminate Molten Salts
R. C. Bell, A. W. Castleman, Jr., and D. L. Thorn
pp 5709 - 5715; DOI:
10.1021/ic990693o
PDF
Synthesis, Structural Characterization, Magnetic Behavior, and Single Crystal EPR Spectra of Three New One-Dimensional Manganese Azido Systems with FM, Alternating FM-AF, and AF Coupling
Morsy A. M. Abu-Youssef, Albert Escuer, Dante Gatteschi, Mohamed A. S. Goher, Franz A. Mautner, and Ramon Vicente
pp 5716 - 5723; DOI:
10.1021/ic990656x
PDF
Synthesis and Characterization of Diiron(III)-Substituted Silicotungstate, [(1,2)-SiW10{Fe(OH2)}2O38]6-
Chika Nozaki, Ikuro Kiyoto, Yoshitaka Minai, Makoto Misono, and Noritaka Mizuno
pp 5724 - 5729; DOI:
10.1021/ic9902065
PDF
Aquation of the Chloro Pentaammine Complexes of Cobalt(III) and Chromium(III): Do the Almost Equal Activation Parameters Arise from a Common Mechanism?
François P. Rotzinger
pp 5730 - 5733; DOI:
10.1021/ic990748m
PDF
Dithiophosphinate Complexes of Trivalent Lanthanide Cations: Consequences of Counterions and Coordination Number for Binding Energies and Selectivity. A Theoretical Study
Christian Boehme and Georges Wipff
pp 5734 - 5741; DOI:
10.1021/ic990951h
PDF
Polarized Specular Reflectance Spectra of Fe(-dtpy)2·4THF: A D2h Model of Porphyrins
Christopher B. Hoffman, Vincenzo Fares, Alberto Flamini, and Ronald L. Musselman
pp 5742 - 5748; DOI:
10.1021/ic980990d
PDF
Effects of Some Charged Amino Acid Mutations on the Electron Self-Exchange Kinetics of Cytochrome b5
Dejian Ma, Yibing Wu, Chengmin Qian, Wenxia Tang, Yun-Hua Wang, Wen-Hu Wang, Jun-Xia Lu, Yi Xie, and Zhong-Xian Huang
pp 5749 - 5754; DOI:
10.1021/ic990607k
PDF
Synthesis, Structure, and Reactivity of Copper Dioxygen Complexes Derived from Molecular Receptor Ligands
Robertus J. M. Klein Gebbink, Constantinus F. Martens, Paulus J. A. Kenis, Rob J. Jansen, Hans-Friedrich Nolting, V. Armando Solé, Martinus C. Feiters, Kenneth D. Karlin, and Roeland J. M. Nolte
pp 5755 - 5768; DOI:
10.1021/ic990108j
PDF
Structural and Photophysical Properties of Mononuclear and Dinuclear Lanthanide(III) Complexes of Multidentate Podand Ligands Based on Poly(pyrazolyl)borates
Nicola Armaroli, Gianluca Accorsi, Francesco Barigelletti, Samantha M. Couchman, James S. Fleming, Nicholas C. Harden, John C. Jeffery, Karen L. V. Mann, Jon A. McCleverty, Leigh H. Rees, Sarah R. Starling, and Michael D. Ward
pp 5769 - 5776; DOI:
10.1021/ic990708i
PDF
Synthesis, Spectroscopic, and X-ray Diffraction Structural Studies of Tin(IV) Derivatives with Tris(pyrazol-1-yl)methanes
C. Pettinari, M. Pellei, A. Cingolani, D. Martini, A. Drozdov, S. Troyanov, W. Panzeri, and A. Mele
pp 5777 - 5787; DOI:
10.1021/ic9906252
PDF
N-Substituted Guanidinate Anions as Ancillary Ligands in Group 4 Chemistry. Syntheses and Characterization of M{RNC[N(SiMe3)2]NR}2Cl2, [M{CyNC[N(SiMe3)2]NCy}Cl3]- (M = Zr, Hf; R = iPr, Cy), and Zr{CyNC[N(SiMe3)2]NCy}(CH2Ph)3
Dayna Wood, Glenn P. A. Yap, and Darrin S. Richeson
pp 5788 - 5794; DOI:
10.1021/ic990668i
PDF
Intramolecular Spin Interactions in Bis(phenoxyl)metal Complexes of Zinc(II) and Copper(II)
Eckhard Bill, Jochen Müller, Thomas Weyhermüller, and Karl Wieghardt
pp 5795 - 5802; DOI:
10.1021/ic990396j
PDF
Addition of {M2S2O2}2+, M = Mo, W, to A--[PW9O34]9-. Synthesis and Structural Characterizations in the Solid State and in Solution
Virginie Béreau, Emmanuel Cadot, H. Bögge, A. Müller, and F. Sécheresse
pp 5803 - 5808; DOI:
10.1021/ic990666y
PDF
Syntheses and Characterization of Novel Three-Dimensional Tellurites, Na2MTe4O12 (M = W, Mo), with Intersecting Tunnels
Vidyavathy Balraj and K. Vidyasagar
pp 5809 - 5813; DOI:
10.1021/ic990547i
PDF
Ring Opening of Dilithio Bis(amido)cyclodiphosphazanes As a Route to 1,3-Diaza-22-phosphaallyl Gallium Complexes
Ingo Schranz, Daniel F. Moser, Lothar Stahl, and Richard J. Staples
pp 5814 - 5819; DOI:
10.1021/ic990553e
PDF
Spatial Extensions of Excited States of Metal Complexes. Tunability by Chemical Variation
Hartmut Yersin and Werner Humbs
pp 5820 - 5831; DOI:
10.1021/ic990582p
PDF
The Influence of Bulky Ligands in the Synthesis of Aluminosiloxanes: X-ray Crystal Structures of a Sterically Hindered Silanetriol RSi(OH)3 and the Aluminosiloxanes [RSiO3Al·THF]4 and [RSiO(OH)2]2AlC(SiMe3)3·3THF (R = (2,6-i-Pr2C6H3)N(SiMe2-i-Pr))
Andreas Klemp, Hagen Hatop, Herbert W. Roesky, Hans-Georg Schmidt, and Mathias Noltemeyer
pp 5832 - 5836; DOI:
10.1021/ic990861c
PDF
Luminescent Lanthanide Coordination Polymers
Ling Ma, Owen R. Evans, Bruce M. Foxman, and Wenbin Lin
pp 5837 - 5840; DOI:
10.1021/ic990429v
PDF
Structures, Magnetic Properties, and Reactivity Studies of Salts Containing the Dinuclear Anion [M2Cl6]2- (M = Mn, Fe, Co)
Jui-Sui Sun, Hanhua Zhao, Xiang Ouyang, Rodolphe Clérac, Jennifer A. Smith, Juan M. Clemente-Juan, Carlos Gómez-Garcia, Eugenio Coronado, and Kim R. Dunbar
pp 5841 - 5855; DOI:
10.1021/ic990525w
PDF
The Effect of Axial Ligand Plane Orientation on the Isotropic Shifts of the Dichelated Protohemin Cyanide Complexes of Traylor and Berzinis
Amy B. Minniear, Tatjana Kh. Shokhireva, and F. Ann Walker
pp 5856 - 5859; DOI:
10.1021/ic990785d
PDF
Structure and Small Molecule Binding of a Tetranuclear Iron(II) Resorc[4]arene-Based Cage Complex
O. Danny Fox, N. Kent Dalley, and Roger G. Harrison
pp 5860 - 5863; DOI:
10.1021/ic990834m
PDF
Synthesis and Characterization of Platinum(II) Complexes of L-Ascorbic Acid. Crystal Structure of Ascorbato-C2,O5-ethylenediamineplatinum(II) Dihydrate
Malcolm J. Arendse, Gordon K. Anderson, and Nigam P. Rath
pp 5864 - 5869; DOI:
10.1021/ic990152z
PDF
Isomerism of Aurated Phosphine Sulfides, Thiophosphinates, Thiophosphonates, and Thiophosphates: Structural and Quantum Chemical Studies
Max Preisenberger, Pekka Pyykkö, Annette Schier, and Hubert Schmidbaur
pp 5870 - 5875; DOI:
10.1021/ic990965n
PDF
B-H Bond Protonation in Mono- and Diprotonated Borane Complexes H3BX (X = N2H4, NH2OH, and H2O2) Involving Hypercoordinate Boron
Golam Rasul, G. K. Surya Prakash, and George A. Olah
pp 5876 - 5878; DOI:
10.1021/ic990939p
PDF
Magnetic Anisotropy of Two Cyclic Hexanuclear Fe(III) Clusters Entrapping Alkaline Ions
O. Waldmann, J. Schülein, R. Koch, P. Müller, I. Bernt, R. W. Saalfrank, H. P. Andres, H. U. Güdel, and P. Allenspach
pp 5879 - 5886; DOI:
10.1021/ic9906510
PDF
Synthesis of Schiff Bases Derived from the Ammoniaundecahydro-closo-dodecaborate(1-) Anion, [B12H11NH=CHR]-, and Their Reduction into Monosubstituted Amines [B12H11NH2CH2R]-: A New Route to Water Soluble Agents for BNCT
Igor B. Sivaev, Alexandr B. Bruskin, Vladimir V. Nesterov, Mikhail Yu. Antipin, Vladimir I. Bregadze, and Stefan Sjöberg
pp 5887 - 5893; DOI:
10.1021/ic990013h
PDF
Experimental and Theoretical Studies of Bis(perfluorovinyl)mercury, Hg(CF=CF2)2: Synthesis, Characterization, and Structure in the Gaseous and Crystalline Phases
Kulbinder K. Banger, Alan K. Brisdon, Paul T. Brain, Simon Parsons, David W. H. Rankin, Heather E. Robertson, Bruce A. Smart, and Michael Bühl
pp 5894 - 5900; DOI:
10.1021/ic991018h
PDF
Tetrakis(pyridine)ruthenium Trans Complexes of Phenylcyanamide Ligands: Crystallography, Electronic Absorption Spectroscopy, and Cyclic Voltammetry
Pierre Desjardins, Glenn P. A. Yap, and Robert J. Crutchley
pp 5901 - 5905; DOI:
10.1021/ic990717r
PDF
Unusually High Selectivity of Polythiaethers for Copper(II) over Nickel(II)
Chandrika P. Kulatilleke, Scott N. Goldie, L. A. Ochrymowycz, and D. B. Rorabacher
pp 5906 - 5909; DOI:
10.1021/ic9907213
PDF
Synthesis and Characterization of {Re(CO)3}4-n{PtMe3}n(OH)4, (n = 1-3). A Set of Heterobimetallic Hydroxy Cubane Complexes
Udo Brand, Chris A. Wright, and John R. Shapley
pp 5910 - 5912; DOI:
10.1021/ic9906914
PDF
C-S Bond Cleavage in CpRu(PPh3)2SCH2CH=CH2 To Give the Trimer (CpRu)3(3-S)2(-SCH2CH=CH2)
Alan Shaver, Mohammad El-Khateeb, and Anne-Marie Lebuis
pp 5913 - 5915; DOI:
10.1021/ic981433u
PDF
Partial Degradation of the New exo-Heterodisubstituted Carborane Derivatives with d10 Transition Metal Ions (Cu, Au)
Francesc Teixidor, Rajae Benakki, Clara Viñas, Raikko Kivekäs, and Reijo Sillanpää
pp 5916 - 5919; DOI:
10.1021/ic9805574
PDF
Polybis(1-methyl-2-thioimidazolate)iron(II): Crystal Structure and Magnetic Properties of a One-Dimensional Material Exhibiting Ferromagnetic Ordering below 8 K
Steven J. Rettig, Victor Sánchez, Alan Storr, Robert C. Thompson, and James Trotter
pp 5920 - 5923; DOI:
10.1021/ic990774k
PDF
Uranyl Photochemistry with Alkenes: Distinguishing between H-Atom Abstraction and Electron Transfer
T. Mark McCleskey, Carol J. Burns, and William Tumas
pp 5924 - 5925; DOI:
10.1021/ic9909126
PDF
Synthesis, Magnetic Properties, and Electronic Spectra of Octahedral Mixed-Ligand (-Diketonato)nickel(II) Complexes with a Chelated Nitronyl Nitroxide Radical.
Takafumi Yoshida, Takayoshi Suzuki, Kan Kanamori, and Sumio Kaizaki:
pp 5926 - 5926; DOI:
10.1021/ic9907415
PDF
Flash Photolysis Studies of Roussin's Black Salt Anion: Fe4S3(NO)7-.
James Bourassa, Brian Lee, Stefan Bernhard, JonSchoonover, and Peter C. Ford:
pp 5926 - 5926; DOI:
10.1021/ic991193y
PDF

Issue 26


High-Field, Multifrequency EPR Study of the Vanadium(III) Hexaaqua Cation
Philip L. W. Tregenna-Piggott, Hgni Weihe, Jesper Bendix, Anne-Laure Barra, and Hans-Ueli Güdel
pp 5928 - 5929; DOI:
10.1021/ic990399w
PDF
Gold Complexes of Trithiocyanuric Acid: A Two-Dimensional Polymer Assembled through Gold(I)···Gold(I) Interactions
William J. Hunks, Michael C. Jennings, and Richard J. Puddephatt
pp 5930 - 5931; DOI:
10.1021/ic991085b
PDF
Highly Emissive Hexanuclear Rhenium(III) Clusters Containing the Cubic Cores [Re6S8]2+ and [Re6Se8]2+
Thomas G. Gray, Christina M. Rudzinski, Daniel G. Nocera, and R. H. Holm
pp 5932 - 5933; DOI:
10.1021/ic991195i
PDF
Playing the Keyboard of Fluorine Chemistry
Herbert W. Roesky
pp 5934 - 5943; DOI:
10.1021/ic990624+
PDF
Hydrothermal Synthesis and Structure of Fe(NH3)2PO4: A Novel Monophosphate
Miguel A. Salvadó, Pilar Pertierra, Santiago García-Granda, Aránzazu Espina, Camino Trobajo, and José R. García
pp 5944 - 5947; DOI:
10.1021/ic990879n
PDF
Intervalence Transfer at the Localized-to-Delocalized, Mixed-Valence Transition in Osmium Polypyridyl Complexes
Konstantinos D. Demadis, Gregory A. Neyhart, Edward M. Kober, Peter S. White, and Thomas J. Meyer
pp 5948 - 5959; DOI:
10.1021/ic9907765
PDF
Undecafluorodiarsenate Anion: Synthesis and Crystal Structure of (MeS)2CSH+As2F11-
Rolf Minkwitz and Frank Neikes
pp 5960 - 5963; DOI:
10.1021/ic9902673
PDF
Five- and Six-Coordinate Group 4 Compounds Stabilized by -Ketiminate and Diketiminate Ligands: Syntheses and Comparisons between Solid-State and Solution Structures
Lena Kakaliou, William J. Scanlon, IV, Baixin Qian, Sung W. Baek, Milton R. Smith, III, and Douglas H. Motry
pp 5964 - 5977; DOI:
10.1021/ic981364j
PDF
Syntheses, Structures, and Theoretical Study of LaCuSTe and SmCuSTe
Fu Qiang Huang and James A. Ibers
pp 5978 - 5983; DOI:
10.1021/ic990835e
PDF
Regiospecific Oximato Coordination at the Oxygen Site: Ligand Design and Low-Spin MnII and FeII/III Species
Sanjib Ganguly, Soma Karmakar, Chandan Kumar Pal, and Animesh Chakravorty
pp 5984 - 5987; DOI:
10.1021/ic9907011
PDF
Comparison of the Manganese Cluster in Oxygen-Evolving Photosystem II with Distorted Cubane Manganese Compounds through X-ray Absorption Spectroscopy
Roehl M. Cinco, Annette Rompel, Hendrik Visser, Guillem Aromí, George Christou, Kenneth Sauer, Melvin P. Klein, and Vittal K. Yachandra
pp 5988 - 5998; DOI:
10.1021/ic991003j
PDF
Solid-Phase Synthesis and Photophysical Properties of DNA Labeled at the Nucleobase with Ru(bpy)2(4-m-4'-pa-bpy)2+
Shoeb I. Khan, Amy E. Beilstein, Mark T. Tierney, Milan Sykora, and Mark W. Grinstaff
pp 5999 - 6002; DOI:
10.1021/ic990810f
PDF
Molecular Recognition of Activated and Unactivated Phosphate Diesters
Paul E. Jurek and Arthur E. Martell
pp 6003 - 6007; DOI:
10.1021/ic990578d
PDF
Synthesis, Structure, and Spectroscopy of Rare Earth Hypophosphites. 1. Anhydrous and Monohydrated Lanthanide Hypophosphites
Peter A. Tanner, Michele D. Faucher, and Thomas C. W. Mak
pp 6008 - 6023; DOI:
10.1021/ic990187z
PDF
Synthesis, Structure, and Spectroscopy of Rare Earth Hypophosphites. 2. Uranyl Hypophosphite Monohydrate and Uranyl Hypophosphite-Hypophosphorous Acid (1/1)
Peter A. Tanner and Thomas C. W. Mak
pp 6024 - 6031; DOI:
10.1021/ic990188r
PDF
Synthesis, Crystal Structure, NMR Studies, and Thermal Stability of Mixed Iron-Indium Phosphates with Quasi-One-Dimensional Frameworks
X. Tang, A. Jones, A. Lachgar, B. J. Gross, and J. L. Yarger
pp 6032 - 6038; DOI:
10.1021/ic9905906
PDF
o-, m-, and p-Carboranes and Their Anions: Ab Initio Calculations of Structures, Electron Affinities, and Acidities
Kersti Hermansson, Mark Wójcik, and Stefan Sjöberg
pp 6039 - 6048; DOI:
10.1021/ic990381l
PDF
A G2 Ab Initio Investigation of Ligand-Exchange Reactions Involving Mono- and Bis-Adducts of the Phosphenium Ion
Theis I. Slling, S. Bruce Wild, and Leo Radom
pp 6049 - 6054; DOI:
10.1021/ic991080e
PDF
Reactions of Iodoperfluoro-3-oxaundecylsulfonyl Fluoride with Halohydrocarbons through Organometallic Intermediates
Bamidele A. Omotowa, Robert L. Kirchmeier, and Jean'ne M. Shreeve
pp 6055 - 6059; DOI:
10.1021/ic990928w
PDF
Acidic Dicationic Iron(II) Dihydrogen Complexes and Compounds Related by H2 Substitution
Shaun E. Landau, Robert H. Morris, and Alan J. Lough
pp 6060 - 6068; DOI:
10.1021/ic990876a
PDF
Cisplatin (cis-Pt(NH3)2Cl2) and cis-[Pt(NH3)2(H2O)2]2+ Intrastrand Cross-Linking Reactions at the Telomere GGGT DNA Sequence Embedded in a Duplex, a Hairpin, and a Bulged Duplex: Use of Mg2+ and Zn2+ to Convert a Hairpin to a Bulged Duplex
Julie M. Villanueva, Xin Jia, Paulos G. Yohannes, Paul W. Doetsch, and Luigi G. Marzilli
pp 6069 - 6080; DOI:
10.1021/ic990603f
PDF
High-Nuclearity Magnetic Clusters: Generalized Spin Hamiltonian and Its Use for the Calculation of the Energy Levels, Bulk Magnetic Properties, and Inelastic Neutron Scattering Spectra
J. J. Borrás-Almenar, J. M. Clemente-Juan, E. Coronado, and B. S. Tsukerblat
pp 6081 - 6088; DOI:
10.1021/ic990915i
PDF
Ab Initio Calculations of the Magnetic Coupling between a Ni(II) Ion and Two Nitroxide Radicals in cis and trans Positions
Nicolas Suaud, Hélène Bolvin, and Jean-Pierre Daudey
pp 6089 - 6095; DOI:
10.1021/ic990014+
PDF
Electroregulated Metal-Binding with a Crown Ether Tetrathiafulvalene Derivative: Toward Electrochemically Addressed Metal Cation Sponges
Franck Le Derf, Miloud Mazari, Nicolas Mercier, Eric Levillain, Pascal Richomme, Jan Becher, Javier Garín, Jesus Orduna, Alain Gorgues, and Marc Sallé
pp 6096 - 6100; DOI:
10.1021/ic9907617
PDF
The d0, d1 and d2 Configurations in Known and Unknown Tetrathiometal Compounds MS4n- (M = Mo, Tc, Ru; W, Re, Os). A Quantum Chemical Study
Stanislav Záli, Hermann Stoll, Evert Jan Baerends, and Wolfgang Kaim
pp 6101 - 6105; DOI:
10.1021/ic990891f
PDF
Double-Aging Method for Preparation of Stabilized Na-Buserite and Transformations to Todorokites Incorporated with Various Metals
Jian Luo, Qiuhua Zhang, Aimin Huang, Oscar Giraldo, and Steven L. Suib
pp 6106 - 6113; DOI:
10.1021/ic980675r
PDF
Tetrakis(thiadiazole)porphyrazines. 2. Metal Complexes with Mn(II), Fe(II), Co(II), Ni(II), and Zn(II)
Elvira M. Bauer, Demetria Cardarilli, Claudio Ercolani, Pavel A. Stuzhin, and U. Russo
pp 6114 - 6120; DOI:
10.1021/ic990855g
PDF
High-Frequency and -Field Electron Paramagnetic Resonance of High-Spin Manganese(III) in Porphyrinic Complexes
J. Krzystek, Joshua Telser, Luca A. Pardi, David P. Goldberg, Brian M. Hoffman, and Louis-Claude Brunel
pp 6121 - 6129; DOI:
10.1021/ic9901970
PDF
Mechanistic Study of the Reaction of Cr(CO)3C5Me5 with H2S Yielding HCr(CO)3C5Me5, HSCr(CO)3C5Me5, and C5Me5(CO)2Cr=S=Cr(CO)2C5Me5. Kinetic Evidence for Formation of the Substituted Radical Complex Cr(CO)2(H2S)C5Me5
Kenneth B. Capps, Andreas Bauer, Telvin D. Ju, and Carl D. Hoff
pp 6130 - 6135; DOI:
10.1021/ic990571w
PDF
Hydrolysis of a Model for the 5'-Cap of mRNA by Dinuclear Copper(II) and Zinc(II) Complexes. Rapid Hydrolysis by Four Copper(II) Ions
Kevin P. McCue and Janet R. Morrow
pp 6136 - 6142; DOI:
10.1021/ic990380t
PDF
Super-Charged Porphyrazines: Synthesis and Physical Properties of Octacationic Tetraazaporphyrins
Máirín E. Anderson, Anthony G. M. Barrett, and Brian M. Hoffman
pp 6143 - 6151; DOI:
10.1021/ic990410s
PDF
Organic-Inorganic Hybrids Based on Polyoxometalates. 5.1 Synthesis and Structural Characterization of Bis(organophosphoryl)decatungstosilicates [-SiW10O36((RPO)2]4-
Cédric R. Mayer, Patrick Herson, and René Thouvenot
pp 6152 - 6158; DOI:
10.1021/ic990724f
PDF
CaB2C2: Reinvestigation of a Semiconducting Boride Carbide with a Layered Structure and an Interesting Boron/Carbon Ordering Scheme
Barbara Albert and Konny Schmitt
pp 6159 - 6163; DOI:
10.1021/ic9907821
PDF
Trinuclear Zinc(II) Complexes and Polymeric Cadmium(II) Complexes with the Ligand 2,5-Bis(2-pyridyl)pyrazine: Synthesis, Spectral Analysis, and Single-Crystal and Powder X-ray Analyses
Antonia Neels and Helen Stoeckli-Evans
pp 6164 - 6170; DOI:
10.1021/ic990843v
PDF
X-ray Absorption Spectroscopic Studies of the Copper(I) Complexes of Crown Ether Appended Bis{(2-pyridyl)ethyl}amines and Their Dioxygen Adducts
Martinus C. Feiters, Robertus J. M. Klein Gebbink, V. Armando Solé, Hans-Friedrich Nolting, Kenneth D. Karlin, and Roeland J. M. Nolte
pp 6171 - 6180; DOI:
10.1021/ic990056y
PDF
Osmium(VI) Nitrido and Osmium(IV) Phosphoraniminato Complexes Containing Schiff Base Ligands
Tsz-Wing Wong, Tai-Chu Lau, and Wing-Tak Wong
pp 6181 - 6186; DOI:
10.1021/ic9814571
PDF
Ground-State Properties and Excited-State Reactivity of 8-Quinolate Complexes of Ruthenium(II)
Jeremy T. Warren, Wei Chen, Dean H. Johnston, and Claudia Turro
pp 6187 - 6192; DOI:
10.1021/ic991001z
PDF
Medium Effects on Reactivity Profiles for Platination of Phosphorothioate-Containing Oligonucleotides
Johan Kjellström and Sofi K. C. Elmroth
pp 6193 - 6199; DOI:
10.1021/ic990622p
PDF
Benzene-Copper(I) Coordination in a Bimetallic Chain Complex
Andrew M. Dattelbaum and James D. Martin
pp 6200 - 6205; DOI:
10.1021/ic991064h
PDF
Kinetic and Thermodynamic Studies of Reaction of Cr(CO)3C5Me5, HCr(CO)3C5Me5, and PhSCr(CO)3C5Me5 with NO. Reductive Elimination of Thermodynamically Unstable Molecules HNO and RSNO Driven by Formation of the Strong Cr-NO Bond
Kenneth B. Capps, Andreas Bauer, Kengkaj Sukcharoenphon, and Carl D. Hoff
pp 6206 - 6211; DOI:
10.1021/ic990829i
PDF
Reaction of NO Thiolate and Thiol Complexes: Elimination of PhSNO from W(phen)(CO)2(SPh)2, CO from W(phen)(CO)2((-S)2Arene), and HNO from W(phen)(CO)3(RSH)
Kenneth B. Capps, Andreas Bauer, Khalil A. Abboud, and Carl D. Hoff
pp 6212 - 6217; DOI:
10.1021/ic990830h
PDF
Spectral and Structural Characterization of 5,6-Chrysenequinone Diimine Complexes of Rhodium(III): Evidence for a pH-Dependent Ligand Conformational Switch
Brian A. Jackson, Lawrence M. Henling, and Jacqueline K. Barton
pp 6218 - 6224; DOI:
10.1021/ic990824l
PDF
Synthetic and Structural Studies of Titanium Aminotroponiminate Complexes
Dietrich P. Steinhuebel and Stephen J. Lippard
pp 6225 - 6233; DOI:
10.1021/ic9909072
PDF
One-Dimensional Copper(I) Coordination Polymers Based on a Tridentate Thioether Ligand
Hing W. Yim, Linh M. Tran, Eric E. Pullen, Daniel Rabinovich, Louise M. Liable-Sands, Thomas E. Concolino, and Arnold L. Rheingold
pp 6234 - 6239; DOI:
10.1021/ic990642r
PDF
Cyclopentadienyl Behavior of Pyrrolyl Anions within the meso-Octaethylporphyrinogen-Binding Lanthanides: Carbon-Hydrogen and Metal-Carbon Bond Rearrangements
Elisa Campazzi, Euro Solari, Rosario Scopelliti, and Carlo Floriani
pp 6240 - 6245; DOI:
10.1021/ic990742x
PDF
Design, Structure, and Optical Properties of Organic-Inorganic Perovskites Containing an Oligothiophene Chromophore
David B. Mitzi, Konstantinos Chondroudis, and Cherie R. Kagan
pp 6246 - 6256; DOI:
10.1021/ic991048k
PDF
Theoretical Bonding Description of Alkylidene Chalcogen (O, S, Se) Difluorides (H2C=XF2): Planar versus Bent Conformations
J. A. Dobado, Henar Martínez-García, and José Molina Molina
pp 6257 - 6260; DOI:
10.1021/ic990733o
PDF
Electronic Structure of Metallacyclophosphazene and Metallacyclothiazene Complexes
Andreas Sundermann and Wolfgang W. Schoeller
pp 6261 - 6270; DOI:
10.1021/ic990956e
PDF
Examination of the Stabilities of Group 14 (C, Si, Ge, Sn, Pb) Congeners of Dihydroxycarbene and Dioxirane. Comparison to Formic Acid and Hydroperoxycarbene Congeners
Nancy A. Richardson, Jonathan C. Rienstra-Kiracofe, and Henry F. Schaefer, III
pp 6271 - 6277; DOI:
10.1021/ic9910099
PDF
Comparative Study of the Luminescence Properties of the Europium(III) Complexes of the Squarate, Phenylsquarate, and (Diphenylamino)squarate Ligands
Bert D. Alleyne, Lincoln A. Hall, Ishenkumba A. Kahwa, Andrew J. P. White, and David J. Williams
pp 6278 - 6284; DOI:
10.1021/ic9907664
PDF
Probing the Molecular Geometry of Five-Coordinate Vanadyl Complexes with Pulsed ENDOR
Christopher V. Grant, Katherine M. Geiser-Bush, Charles R. Cornman, and R. David Britt
pp 6285 - 6288; DOI:
10.1021/ic9909173
PDF
Formation of Separated versus Contact Ion Triplets in Magnesium Thiolates. Synthesis and Characterization of [Mg(15-crown-5)(SCPh3)2] and [Mg(15-crown-5)(THF)2][S-2,4,6-tBu3C6H2)]2
Scott Chadwick, Ulrich Englich, and Karin Ruhlandt-Senge
pp 6289 - 6293; DOI:
10.1021/ic990814k
PDF
Linear Tricobalt Compounds with Di-(2-pyridyl)amide (dpa) Ligands: Studies of the Paramagnetic Compound Co3(dpa)4Cl2 in Solution
F. Albert Cotton, Carlos A. Murillo, and Xiaoping Wang
pp 6294 - 6297; DOI:
10.1021/ic990944t
PDF
Acid-Base Equilibria of (2,2'-Bipyridyl-4,4'-dicarboxylic acid)ruthenium(II) Complexes and the Effect of Protonation on Charge-Transfer Sensitization of Nanocrystalline Titania
Md. K. Nazeeruddin, S. M. Zakeeruddin, R. Humphry-Baker, M. Jirousek, P. Liska, N. Vlachopoulos, V. Shklover, Christian-H. Fischer, and M. Grätzel
pp 6298 - 6305; DOI:
10.1021/ic990916a
PDF
N,O-Polydentate Scorpionate Ligands
Arnold L. Rheingold, Brian S. Haggerty, Louise M. Liable-Sands, and Swiatoslaw Trofimenko
pp 6306 - 6308; DOI:
10.1021/ic990881e
PDF
Synthesis, Crystal Structure, and Properties of a 3-D Network Assembled by Nickel(II) Macrocyclic Complex and Terephthalato Bridge
Hye Jin Choi and Myunghyun Paik Suh
pp 6309 - 6312; DOI:
10.1021/ic990664d
PDF
Self-Assembly of the First Copper(II) Infinite 2D Network with Large Cavities Formed between the Two Adjacent Layers
Hong-Ke Liu, Wei-Yin Sun, Wen-Xia Tang, Tetsuo Yamamoto, and Norikazu Ueyama
pp 6313 - 6316; DOI:
10.1021/ic9907563
PDF
Progress in the Intercalation of Pyridine and Other Organic Bases into Crystalline Bismuth Molybdenum Oxide Hydrate, BiMo2O7OH·2H2O
N. Barnes, S. J. Kitchin, and J. A. Hriljac
pp 6317 - 6319; DOI:
10.1021/ic9905502
PDF
Influence of the Attaching Group and Substituted Position in the Photosensitization Behavior of Ruthenium Polypyridyl Complexes
Yuan-jun Hou, Pu-hui Xie, Bao-wen Zhang, Yi Cao, Xu-rui Xiao, and Wei-bo Wang
pp 6320 - 6322; DOI:
10.1021/ic990001w
PDF
Carboxy and Diphosphate Ester Hydrolysis Promoted by Dinuclear Zinc(II) Macrocyclic Complexes. Role of Zn(II)-Bound Hydroxide as the Nucleophilic Function
Andrea Bencini, Emanuela Berni, Antonio Bianchi, Valentina Fedi, Claudia Giorgi, Piero Paoletti, and Barbara Valtancoli
pp 6323 - 6325; DOI:
10.1021/ic990820g
PDF
[Mn(bpm)(N3)2]n: A One-Dimensional Coordination Polymer Exhibiting Strong Ferromagnetic-Antiferromagnetic Alternating Interactions
Liang-Fu Tang, Lei Zhang, Li-Chun Li, Peng Cheng, Zhi-Hong Wang, and Ji-Tao Wang
pp 6326 - 6328; DOI:
10.1021/ic990878v
PDF